Electrochemical characterization of supercapacitors based on carbons derived from coffee shells
Carbons derived by pyrolysis of coffee shells treated with ZnCl 2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning electron microscopy showed that the carbon from the porogen-free shells show a flake-like structure, while those from the ZnCl 2-treated coffee sh...
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Published in | Materials chemistry and physics Vol. 115; no. 1; pp. 33 - 39 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.05.2009
|
Subjects | |
Online Access | Get full text |
ISSN | 0254-0584 1879-3312 |
DOI | 10.1016/j.matchemphys.2008.11.010 |
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Abstract | Carbons derived by pyrolysis of coffee shells treated with ZnCl
2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning electron microscopy showed that the carbon from the porogen-free shells show a flake-like structure, while those from the ZnCl
2-treated coffee shells have a loose, disjointed structure with no definite shape. X-ray diffraction studies indicated the presence of small domains of coherent and parallel stacking of the graphene sheets. The average surface area of the carbon was 842
m
2
g
−1, with an average micropore area of 400
m
2
g
−1. Cyclic voltammetric studies suggested a specific capacitance of about 150
F
g
−1. Self-discharge studies on the devices showed a large retention time. |
---|---|
AbstractList | Carbons derived by pyrolysis of coffee shells treated with ZnCl
2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning electron microscopy showed that the carbon from the porogen-free shells show a flake-like structure, while those from the ZnCl
2-treated coffee shells have a loose, disjointed structure with no definite shape. X-ray diffraction studies indicated the presence of small domains of coherent and parallel stacking of the graphene sheets. The average surface area of the carbon was 842
m
2
g
−1, with an average micropore area of 400
m
2
g
−1. Cyclic voltammetric studies suggested a specific capacitance of about 150
F
g
−1. Self-discharge studies on the devices showed a large retention time. Carbons derived by pyrolysis of coffee shells treated with ZnCl2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning electron microscopy showed that the carbon from the porogen-free shells show a flake-like structure, while those from the ZnCl2-treated coffee shells have a loose, disjointed structure with no definite shape. X-ray diffraction studies indicated the presence of small domains of coherent and parallel stacking of the graphene sheets. The average surface area of the carbon was 842 m2 g-1, with an average micropore area of 400 m2 g-1. Cyclic voltammetric studies suggested a specific capacitance of about 150 F g-1. Self-discharge studies on the devices showed a large retention time. |
Author | Shin, Jae Sun Hwang, Yun Ju Jisha, M.R. Nahm, Kee Suk Prem Kumar, T. Dhanikaivelu, N. Stephan, A. Manuel Karthikeyan, K. Kalpana, D. Renganathan, N.G. |
Author_xml | – sequence: 1 givenname: M.R. surname: Jisha fullname: Jisha, M.R. organization: Department of Hydrogen and Fuel cells Engineering, Chonbuk National University, Jeonju 561-756, Republic of Korea – sequence: 2 givenname: Yun Ju surname: Hwang fullname: Hwang, Yun Ju organization: Department of Hydrogen and Fuel cells Engineering, Chonbuk National University, Jeonju 561-756, Republic of Korea – sequence: 3 givenname: Jae Sun surname: Shin fullname: Shin, Jae Sun organization: School of Nanosemiconductor display, Chonbuk National University, Jeonju 561-756, Republic of Korea – sequence: 4 givenname: Kee Suk surname: Nahm fullname: Nahm, Kee Suk email: nahmks@chonbuk.ac.kr organization: Department of Hydrogen and Fuel cells Engineering, Chonbuk National University and School of Chemical Engineering and Technology, Jeonju 561-756, Republic of Korea – sequence: 5 givenname: T. surname: Prem Kumar fullname: Prem Kumar, T. organization: Central Electro Chemical Research Institute, Karaikudi 630006, India – sequence: 6 givenname: K. surname: Karthikeyan fullname: Karthikeyan, K. organization: Central Electro Chemical Research Institute, Karaikudi 630006, India – sequence: 7 givenname: N. surname: Dhanikaivelu fullname: Dhanikaivelu, N. organization: Central Electro Chemical Research Institute, Karaikudi 630006, India – sequence: 8 givenname: D. surname: Kalpana fullname: Kalpana, D. organization: Central Electro Chemical Research Institute, Karaikudi 630006, India – sequence: 9 givenname: N.G. surname: Renganathan fullname: Renganathan, N.G. organization: Central Electro Chemical Research Institute, Karaikudi 630006, India – sequence: 10 givenname: A. Manuel surname: Stephan fullname: Stephan, A. Manuel organization: Central Electro Chemical Research Institute, Karaikudi 630006, India |
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Keywords | Supercapacitors Porogen Chemical activations Carbon Coffee shells |
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Snippet | Carbons derived by pyrolysis of coffee shells treated with ZnCl
2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning... Carbons derived by pyrolysis of coffee shells treated with ZnCl2 were used as electrode materials in symmetric electrochemical supercapacitors. Scanning... |
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SubjectTerms | Carbon Chemical activations Coffee shells Porogen Supercapacitors |
Title | Electrochemical characterization of supercapacitors based on carbons derived from coffee shells |
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