Electrochemical Performance of LiMn2O4/LiFePO4 Blend Cathodes for Lithium Ion Batteries

• Published in: Chemical research in Chinese universities Vol. 31; no. 2; pp. 270 - 275
• Main Authors: Qiu, Chengguang, Liu, Lina, Du, Fei, Yang, Xu, Wang, Chunzhong, Chen, Gang, Wei, Yingjin
• Format: Journal Article
• Language: English
• Published: Heidelberg Jilin University and The Editorial Department of Chemical Research in Chinese Universities 01.04.2015; State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P.R.China; Key Laboratory of Physics and Technology for Advanced Batteries(Ministry of Education), College of Physics,Jilin University, Changchun 130012, P.R.China%School of Materials Science and Engineering, Changchun University of Science and Technology,Changchun 130022, P.R.China%Key Laboratory of Physics and Technology for Advanced Batteries(Ministry of Education), College of Physics,Jilin University, Changchun 130012, P.R.China
• Subjects: Analytical Chemistry; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Inorganic Chemistry; LiFePO4; LiMn2O4; Organic Chemistry; Physical Chemistry; 扫描电子显微镜; 电化学性能; 磷酸铁锂; 锂离子电池; 锰酸锂; 阴极; Lithium ion battery; Blend cathode; LiFePO; LiMn; O; LiFePO4; LiMn2O4
• ISSN: 1005-9040; 2210-3171
• DOI: 10.1007/s40242-015-4367-0

A series of LiMn2O4/LiFePO4 blend cathodes was prepared by hand milling and ball milling in order to compensate the disadvantage of spinel LiMnaO4 and olivine LiFePO4. The morphologies of the blends were studied by scanning electron microscopy, and their electrochemical properties were studied by charge-discharge cycling, cyclic voltarnmetry and electrochemical impedance spectroscopy. It is easy to obtain uniform LiMn2Oa/LiFePO4 blends by the hand milling technique, while significant particle agglomeration is caused by the ball milling technique. When the LiMn2O4：LiFePO4 mass ratio is 1：1, the nano-sized LiFePO4 powders not only uniformly cover the micron-sized LiMn2O4 particles but also effectively fill in the cavities of the LiMn2O4 space. Such morphology offers a good electrical contact and a high tap density, which leads to a high discharge capacity and good cycle stability.