Prevulcanization of isoprene rubber latex
Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state 13 C-NMR spectroscopy to understand its mechanism in latex stage. The prevulcanization was carried out at 50 to 90 °C with sulfur (S) and zinc-dibutyldithiocarbamate (ZDBC) as vulcanizing agents. The prevulcanized IR late...
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| Published in | Colloid and polymer science Vol. 293; no. 5; pp. 1457 - 1464 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Berlin/Heidelberg
Springer Berlin Heidelberg
01.05.2015
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0303-402X 1435-1536 |
| DOI | 10.1007/s00396-015-3513-z |
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| Abstract | Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state
13
C-NMR spectroscopy to understand its mechanism in latex stage. The prevulcanization was carried out at 50 to 90 °C with sulfur (S) and zinc-dibutyldithiocarbamate (ZDBC) as vulcanizing agents. The prevulcanized IR latex was subjected to latex-state
13
C-NMR spectroscopy. The signal at 44 ppm was assigned to secondary carbons adjacent to carbons linking to S atoms, whereas the signal at 58 ppm was assigned to tertiary and quaternary carbons linking to S atoms. The time evolution of the small signals at 44 and 58 ppm was investigated at various temperatures, and kinetic constants were determined at each temperature. The activation energy of the prevulcanization of IR latex was estimated from the kinetic constants to be about 80 kJ/mol. |
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| AbstractList | Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state
13
C-NMR spectroscopy to understand its mechanism in latex stage. The prevulcanization was carried out at 50 to 90 °C with sulfur (S) and zinc-dibutyldithiocarbamate (ZDBC) as vulcanizing agents. The prevulcanized IR latex was subjected to latex-state
13
C-NMR spectroscopy. The signal at 44 ppm was assigned to secondary carbons adjacent to carbons linking to S atoms, whereas the signal at 58 ppm was assigned to tertiary and quaternary carbons linking to S atoms. The time evolution of the small signals at 44 and 58 ppm was investigated at various temperatures, and kinetic constants were determined at each temperature. The activation energy of the prevulcanization of IR latex was estimated from the kinetic constants to be about 80 kJ/mol. Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state super(13)C-NMR spectroscopy to understand its mechanism in latex stage. The prevulcanization was carried out at 50 to 90 degree C with sulfur (S) and zinc-dibutyldithiocarbamate (ZDBC) as vulcanizing agents. The prevulcanized IR latex was subjected to latex-state super(13)C-NMR spectroscopy. The signal at 44 ppm was assigned to secondary carbons adjacent to carbons linking to S atoms, whereas the signal at 58 ppm was assigned to tertiary and quaternary carbons linking to S atoms. The time evolution of the small signals at 44 and 58 ppm was investigated at various temperatures, and kinetic constants were determined at each temperature. The activation energy of the prevulcanization of IR latex was estimated from the kinetic constants to be about 80 kJ/mol. Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state ^sup 13^C-NMR spectroscopy to understand its mechanism in latex stage. The prevulcanization was carried out at 50 to 90 °C with sulfur (S) and zinc-dibutyldithiocarbamate (ZDBC) as vulcanizing agents. The prevulcanized IR latex was subjected to latex-state ^sup 13^C-NMR spectroscopy. The signal at 44 ppm was assigned to secondary carbons adjacent to carbons linking to S atoms, whereas the signal at 58 ppm was assigned to tertiary and quaternary carbons linking to S atoms. The time evolution of the small signals at 44 and 58 ppm was investigated at various temperatures, and kinetic constants were determined at each temperature. The activation energy of the prevulcanization of IR latex was estimated from the kinetic constants to be about 80 kJ/mol. |
| Author | Kawahara, Seiichi Sae-heng, Kewwarin Iso, Noriaki Kosugi, Kenichiro |
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| CitedBy_id | crossref_primary_10_1016_j_polymer_2024_127272 crossref_primary_10_1021_acs_biomac_2c00141 crossref_primary_10_1016_j_polymer_2021_124271 crossref_primary_10_1080_10298436_2024_2404705 |
| Cites_doi | 10.1021/la981601v 10.5254/1.3538453 10.1016/j.polymer.2009.01.062 10.1002/(SICI)1097-4628(19970906)65:10<1913::AID-APP8>3.0.CO;2-I 10.1002/(SICI)1097-4628(19981114)70:7<1371::AID-APP12>3.0.CO;2-3 10.1002/polb.21076 10.1016/0021-9797(79)90225-X 10.1063/1.1723792 10.1351/pac196715010081 10.5254/1.3539414 10.1038/pj.2012.112 10.5254/1.3547801 10.1002/app.21918 10.5254/1.3538836 10.5254/1.3544951 |
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| Keywords | Isoprene rubber NMR Prevulcanization Kinetics Activation energy |
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| References_xml | – volume: 15 start-page: 6208 year: 1999 end-page: 6219 ident: CR6 article-title: Surface morphology of prevulcanized natural rubber latex films by atomic force microscopy: new insight into the prevulcanization mechanism publication-title: Langmuir doi: 10.1021/la981601v – volume: 70 start-page: 671 year: 1997 end-page: 680 ident: CR13 article-title: Solid-state C-13 NMR studies of vulcanized elastomers XVII. 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| Snippet | Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state
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C-NMR spectroscopy to understand its mechanism in latex stage. The... Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state ^sup 13^C-NMR spectroscopy to understand its mechanism in latex stage. The... Prevulcanization of isoprene rubber (IR) latex was investigated by latex-state super(13)C-NMR spectroscopy to understand its mechanism in latex stage. The... |
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| SubjectTerms | Carbon Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Constants Food Science Infrared radiation Isoprene rubber Joining Latex Linking Nanotechnology and Microengineering Original Contribution Physical Chemistry Polymer Sciences Soft and Granular Matter Spectroscopy |
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| Title | Prevulcanization of isoprene rubber latex |
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