Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here...
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| Published in | Science (American Association for the Advancement of Science) Vol. 365; no. 6451; pp. 360 - 366 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Association for the Advancement of Science
26.07.2019
The American Association for the Advancement of Science |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0036-8075 1095-9203 1095-9203 |
| DOI | 10.1126/science.aaw3254 |
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| Abstract | Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity. |
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| AbstractList | Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity. Two-for-one approach to photoredoxIn photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it. Ghosh et al. used a semiconductor catalyst to activate two reactants at once by quenching both an excited electron and the residual positive hole (see the Perspective by Swift). As such, two different reactive carbon or halide fragments could be appended to separate sites on an aryl ring. The catalyst also tolerated strong nucleophiles such as cyanide and could be recovered easily and reused.Science, this issue p. 360; see also p. 320Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity. Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon-hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity.Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon-hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity. In photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it. Ghosh et al. used a semiconductor catalyst to activate two reactants at once by quenching both an excited electron and the residual positive hole (see the Perspective by Swift). As such, two different reactive carbon or halide fragments could be appended to separate sites on an aryl ring. The catalyst also tolerated strong nucleophiles such as cyanide and could be recovered easily and reused. Science , this issue p. 360 ; see also p. 320 Formation of oxidizing and reducing sites on a semiconductor photocatalyst promotes double radical addition reactions. Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity. |
| Author | Khamrai, Jagadish König, Burkhard Shlapakov, Nikita Antonietti, Markus Ghosh, Indrajit Savateev, Aleksandr |
| Author_xml | – sequence: 1 givenname: Indrajit surname: Ghosh fullname: Ghosh, Indrajit – sequence: 2 givenname: Jagadish surname: Khamrai fullname: Khamrai, Jagadish – sequence: 3 givenname: Aleksandr surname: Savateev fullname: Savateev, Aleksandr – sequence: 4 givenname: Nikita surname: Shlapakov fullname: Shlapakov, Nikita – sequence: 5 givenname: Markus surname: Antonietti fullname: Antonietti, Markus – sequence: 6 givenname: Burkhard surname: König fullname: König, Burkhard |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31346061$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/ol201437g 10.1016/j.electacta.2010.02.099 10.1002/cctc.201800886 10.1021/jp4009338 10.1002/cctc.201601165 10.1021/ja211422g 10.1016/j.apcata.2008.03.009 10.1021/jo3018473 10.1016/j.tet.2010.01.007 10.1016/j.tet.2011.01.049 10.3762/bjoc.10.97 10.1021/acs.joc.6b01449 10.1126/science.aac9895 10.1021/acssuschemeng.8b05487 10.1002/anie.201511131 10.1007/s11244-010-9513-9 10.1021/ja501906x 10.1021/jo702219f 10.1021/acs.accounts.6b00229 10.1021/jacs.6b02782 10.1021/jo200443u 10.1021/ol3021836 10.1002/anie.201709690 10.1016/j.bmcl.2009.02.091 10.1021/acs.joc.8b01146 10.1021/jo0266285 10.1021/jacs.5b12081 10.1021/cr300503r 10.1021/ol301912a 10.1039/c0sc00535e 10.3762/bjoc.9.245 10.1038/s41570-017-0052 10.1038/nature11680 10.1039/B913880N 10.1002/chem.201601000 10.1002/anie.201800699 10.1002/chem.201503915 10.1021/jo048297x 10.1039/C6GC01582D 10.1016/j.tetlet.2009.11.016 10.1038/s41467-017-02527-8 10.1002/adma.201501939 10.1126/science.1161976 10.1002/anie.201707517 10.1021/ja501879c 10.1021/ol100437j 10.1016/j.tet.2016.07.032 10.1021/ja301553c 10.1002/anie.201707906 10.1002/ejoc.201600770 10.1002/anie.201201200 10.1126/science.1258232 10.1021/jo00125a047 10.1038/nmat2317 10.1021/ol101146f 10.1021/acscatal.5b02410 10.1039/C5SC02913A 10.1002/anie.201802472 10.1038/nchem.2888 10.1002/chem.201002547 10.1002/anie.201101182 10.1021/ja410823e 10.1039/C6GC02000C 10.1021/jo00061a041 10.1007/s40820-016-0121-5 10.1021/ja952600h 10.1021/acs.chemmater.7b02899 10.1021/acscatal.8b03199 10.1021/jacs.5b13450 10.1021/jo101589h 10.1039/C4SC03064H 10.1016/S1010-6030(96)04556-X 10.6028/jres.114.006 10.1021/jacs.6b12708 10.1021/jacs.8b03302 10.1002/anie.200903838 10.1002/anie.201103224 10.1021/ja00206a061 10.1002/adsc.201300199 10.1021/jo102063s 10.1073/pnas.1109059108 10.1038/s41586-018-0413-7 10.1126/science.1253647 10.1021/ol201713b 10.1021/ol4023084 10.1002/adsc.201200588 10.1126/science.aag0209 10.1002/anie.201407948 10.1038/nature10647 10.1021/jacs.8b01561 10.1021/acs.chemrev.6b00057 10.1021/jo8025884 10.1021/acs.accounts.7b00023 10.1016/S0022-328X(03)00503-5 10.1039/b800274f 10.1039/C5RA22167F 10.1039/C4RA05625F 10.1002/chem.201300229 10.1002/chem.201405505 |
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| References | e_1_3_2_20_2 e_1_3_2_43_2 e_1_3_2_62_2 e_1_3_2_85_2 Wang Y. B. (e_1_3_2_104_2) 2015 e_1_3_2_24_2 e_1_3_2_47_2 e_1_3_2_66_2 e_1_3_2_89_2 e_1_3_2_100_2 e_1_3_2_81_2 e_1_3_2_16_2 e_1_3_2_7_2 e_1_3_2_39_2 e_1_3_2_54_2 e_1_3_2_31_2 e_1_3_2_73_2 e_1_3_2_12_2 e_1_3_2_58_2 e_1_3_2_96_2 e_1_3_2_3_2 e_1_3_2_35_2 e_1_3_2_77_2 e_1_3_2_92_2 e_1_3_2_50_2 e_1_3_2_48_2 e_1_3_2_29_2 e_1_3_2_40_2 e_1_3_2_86_2 e_1_3_2_63_2 e_1_3_2_44_2 e_1_3_2_67_2 e_1_3_2_82_2 e_1_3_2_103_2 e_1_3_2_17_2 e_1_3_2_59_2 e_1_3_2_6_2 e_1_3_2_32_2 e_1_3_2_51_2 e_1_3_2_74_2 e_1_3_2_13_2 e_1_3_2_36_2 e_1_3_2_55_2 e_1_3_2_78_2 e_1_3_2_97_2 e_1_3_2_2_2 e_1_3_2_93_2 e_1_3_2_70_2 e_1_3_2_26_2 e_1_3_2_49_2 e_1_3_2_41_2 e_1_3_2_64_2 e_1_3_2_87_2 e_1_3_2_45_2 e_1_3_2_68_2 e_1_3_2_60_2 e_1_3_2_83_2 e_1_3_2_102_2 e_1_3_2_106_2 e_1_3_2_9_2 e_1_3_2_37_2 e_1_3_2_18_2 Roth H. G. (e_1_3_2_56_2) 2016; 27 e_1_3_2_75_2 e_1_3_2_10_2 e_1_3_2_52_2 e_1_3_2_5_2 e_1_3_2_33_2 e_1_3_2_79_2 e_1_3_2_14_2 e_1_3_2_98_2 e_1_3_2_94_2 e_1_3_2_71_2 e_1_3_2_90_2 Liebig J. B. (e_1_3_2_21_2) 1834; 10 e_1_3_2_27_2 e_1_3_2_65_2 e_1_3_2_42_2 e_1_3_2_84_2 e_1_3_2_23_2 e_1_3_2_69_2 e_1_3_2_46_2 e_1_3_2_88_2 e_1_3_2_61_2 e_1_3_2_80_2 e_1_3_2_101_2 e_1_3_2_105_2 e_1_3_2_15_2 e_1_3_2_38_2 e_1_3_2_8_2 e_1_3_2_19_2 e_1_3_2_30_2 e_1_3_2_53_2 e_1_3_2_76_2 e_1_3_2_99_2 e_1_3_2_11_2 e_1_3_2_34_2 e_1_3_2_57_2 e_1_3_2_95_2 e_1_3_2_4_2 e_1_3_2_91_2 e_1_3_2_72_2 31346053 - Science. 2019 Jul 26;365(6451):320-321 |
| References_xml | – ident: e_1_3_2_93_2 doi: 10.1021/ol201437g – ident: e_1_3_2_63_2 doi: 10.1016/j.electacta.2010.02.099 – ident: e_1_3_2_86_2 doi: 10.1002/cctc.201800886 – start-page: 4153 year: 2015 ident: e_1_3_2_104_2 publication-title: Eur. J. Org. Chem. – ident: e_1_3_2_53_2 doi: 10.1021/jp4009338 – ident: e_1_3_2_54_2 doi: 10.1002/cctc.201601165 – ident: e_1_3_2_74_2 doi: 10.1021/ja211422g – ident: e_1_3_2_72_2 doi: 10.1016/j.apcata.2008.03.009 – ident: e_1_3_2_95_2 doi: 10.1021/jo3018473 – ident: e_1_3_2_51_2 doi: 10.1016/j.tet.2010.01.007 – ident: e_1_3_2_78_2 doi: 10.1016/j.tet.2011.01.049 – ident: e_1_3_2_8_2 doi: 10.3762/bjoc.10.97 – ident: e_1_3_2_3_2 doi: 10.1021/acs.joc.6b01449 – ident: e_1_3_2_12_2 doi: 10.1126/science.aac9895 – ident: e_1_3_2_60_2 doi: 10.1021/acssuschemeng.8b05487 – ident: e_1_3_2_69_2 doi: 10.1002/anie.201511131 – ident: e_1_3_2_49_2 doi: 10.1007/s11244-010-9513-9 – ident: e_1_3_2_89_2 doi: 10.1021/ja501906x – ident: e_1_3_2_105_2 doi: 10.1021/jo702219f – ident: e_1_3_2_7_2 doi: 10.1021/acs.accounts.6b00229 – ident: e_1_3_2_67_2 doi: 10.1021/jacs.6b02782 – ident: e_1_3_2_106_2 doi: 10.1021/jo200443u – ident: e_1_3_2_97_2 doi: 10.1021/ol3021836 – ident: e_1_3_2_62_2 doi: 10.1002/anie.201709690 – ident: e_1_3_2_88_2 doi: 10.1016/j.bmcl.2009.02.091 – ident: e_1_3_2_10_2 doi: 10.1021/acs.joc.8b01146 – ident: e_1_3_2_85_2 doi: 10.1021/jo0266285 – ident: e_1_3_2_31_2 doi: 10.1021/jacs.5b12081 – ident: e_1_3_2_2_2 doi: 10.1021/cr300503r – ident: e_1_3_2_96_2 doi: 10.1021/ol301912a – ident: e_1_3_2_29_2 doi: 10.1039/c0sc00535e – ident: e_1_3_2_43_2 doi: 10.3762/bjoc.9.245 – ident: e_1_3_2_46_2 doi: 10.1038/s41570-017-0052 – ident: e_1_3_2_71_2 doi: 10.1038/nature11680 – ident: e_1_3_2_36_2 doi: 10.1039/B913880N – ident: e_1_3_2_57_2 doi: 10.1002/chem.201601000 – ident: e_1_3_2_47_2 doi: 10.1002/anie.201800699 – ident: e_1_3_2_83_2 doi: 10.1002/chem.201503915 – ident: e_1_3_2_87_2 doi: 10.1021/jo048297x – ident: e_1_3_2_15_2 doi: 10.1039/C6GC01582D – ident: e_1_3_2_79_2 doi: 10.1016/j.tetlet.2009.11.016 – ident: e_1_3_2_26_2 doi: 10.1038/s41467-017-02527-8 – ident: e_1_3_2_59_2 doi: 10.1002/adma.201501939 – ident: e_1_3_2_4_2 doi: 10.1126/science.1161976 – ident: e_1_3_2_98_2 doi: 10.1002/anie.201707517 – ident: e_1_3_2_42_2 doi: 10.1021/ja501879c – ident: e_1_3_2_94_2 doi: 10.1021/ol100437j – ident: e_1_3_2_66_2 doi: 10.1016/j.tet.2016.07.032 – ident: e_1_3_2_37_2 doi: 10.1021/ja301553c – ident: e_1_3_2_99_2 doi: 10.1002/anie.201707906 – ident: e_1_3_2_77_2 doi: 10.1002/ejoc.201600770 – ident: e_1_3_2_16_2 doi: 10.1002/anie.201201200 – ident: e_1_3_2_6_2 doi: 10.1126/science.1258232 – ident: e_1_3_2_81_2 doi: 10.1021/jo00125a047 – ident: e_1_3_2_13_2 doi: 10.1038/nmat2317 – ident: e_1_3_2_27_2 doi: 10.1021/ol101146f – ident: e_1_3_2_58_2 doi: 10.1021/acscatal.5b02410 – ident: e_1_3_2_34_2 doi: 10.1039/C5SC02913A – ident: e_1_3_2_23_2 doi: 10.1002/anie.201802472 – ident: e_1_3_2_65_2 doi: 10.1038/nchem.2888 – ident: e_1_3_2_90_2 doi: 10.1002/chem.201002547 – ident: e_1_3_2_14_2 doi: 10.1002/anie.201101182 – ident: e_1_3_2_100_2 doi: 10.1021/ja410823e – ident: e_1_3_2_70_2 doi: 10.1039/C6GC02000C – ident: e_1_3_2_76_2 doi: 10.1021/jo00061a041 – ident: e_1_3_2_24_2 doi: 10.1007/s40820-016-0121-5 – ident: e_1_3_2_35_2 doi: 10.1021/ja952600h – ident: e_1_3_2_20_2 doi: 10.1021/acs.chemmater.7b02899 – volume: 10 start-page: 10 year: 1834 ident: e_1_3_2_21_2 publication-title: Ann. Pharm. – ident: e_1_3_2_48_2 doi: 10.1021/acscatal.8b03199 – ident: e_1_3_2_40_2 doi: 10.1021/jacs.5b13450 – ident: e_1_3_2_50_2 doi: 10.1021/jo101589h – ident: e_1_3_2_9_2 doi: 10.1039/C4SC03064H – ident: e_1_3_2_19_2 doi: 10.1016/S1010-6030(96)04556-X – ident: e_1_3_2_61_2 doi: 10.6028/jres.114.006 – ident: e_1_3_2_11_2 doi: 10.1021/jacs.6b12708 – ident: e_1_3_2_32_2 doi: 10.1021/jacs.8b03302 – ident: e_1_3_2_80_2 doi: 10.1002/anie.200903838 – ident: e_1_3_2_92_2 doi: 10.1002/anie.201103224 – ident: e_1_3_2_18_2 doi: 10.1021/ja00206a061 – ident: e_1_3_2_68_2 doi: 10.1002/adsc.201300199 – ident: e_1_3_2_103_2 doi: 10.1021/jo102063s – ident: e_1_3_2_38_2 doi: 10.1073/pnas.1109059108 – ident: e_1_3_2_30_2 doi: 10.1038/s41586-018-0413-7 – ident: e_1_3_2_44_2 doi: 10.1126/science.1253647 – ident: e_1_3_2_84_2 doi: 10.1021/ol201713b – ident: e_1_3_2_101_2 doi: 10.1021/ol4023084 – ident: e_1_3_2_64_2 doi: 10.1002/adsc.201200588 – ident: e_1_3_2_45_2 doi: 10.1126/science.aag0209 – ident: e_1_3_2_75_2 doi: 10.1002/anie.201407948 – ident: e_1_3_2_39_2 doi: 10.1038/nature10647 – ident: e_1_3_2_33_2 doi: 10.1021/jacs.8b01561 – ident: e_1_3_2_5_2 doi: 10.1021/acs.chemrev.6b00057 – ident: e_1_3_2_82_2 doi: 10.1021/jo8025884 – ident: e_1_3_2_17_2 doi: 10.1021/acs.accounts.7b00023 – ident: e_1_3_2_41_2 doi: 10.1016/S0022-328X(03)00503-5 – ident: e_1_3_2_55_2 doi: 10.1039/b800274f – ident: e_1_3_2_52_2 doi: 10.1039/C5RA22167F – ident: e_1_3_2_91_2 doi: 10.1039/C4RA05625F – ident: e_1_3_2_102_2 doi: 10.1002/chem.201300229 – volume: 27 start-page: 714 year: 2016 ident: e_1_3_2_56_2 publication-title: Synlett – ident: e_1_3_2_73_2 doi: 10.1002/chem.201405505 – reference: 31346053 - Science. 2019 Jul 26;365(6451):320-321 |
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| Snippet | Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional... In photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it. Ghosh et al. used a semiconductor... Two-for-one approach to photoredoxIn photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it.... |
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| SubjectTerms | Aromatic compounds Carbon Carbon nitride Catalysis Catalysts Centrifugation Chromophores Cyanides Electrons Holes (electron deficiencies) Intermediates Nucleophiles Oxidation Photoredox catalysis Redox reactions Semiconductor materials Substrates |
| Title | Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes |
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