Oxidative degradation of bisphenol A and 17α-ethinyl estradiol by Fenton-like activity of silver nanoparticles in aqueous solution

Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endoc...

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Published in	Chemosphere (Oxford) Vol. 168; pp. 617 - 622
Main Authors	Park, Chang Min, Heo, Jiyong, Yoon, Yeomin
Format	Journal Article
Language	English
Published	England Elsevier Ltd 01.02.2017
Subjects	17α-ethinyl estradiol antibacterial properties aqueous solutions Benzhydryl Compounds - analysis Bisphenol A Catalysis cations cytotoxicity Degradation Endocrine Disruptors - analysis endocrine-disrupting chemicals equations estradiol Ethinyl Estradiol - analysis hydrogen peroxide Hydrogen Peroxide - chemistry Hydroxyl radicals Metal Nanoparticles - chemistry nanosilver oxidation Oxidation-Reduction Phenols - analysis polyvinylpyrrolidone Povidone - chemistry silver Silver - chemistry Silver nanoparticle Water Pollutants, Chemical - analysis Degradation Hydroxyl radicals Bisphenol A 17α-ethinyl estradiol Silver nanoparticle
Online Access	Get full text
ISSN	0045-6535 1879-1298 1879-1298
DOI	10.1016/j.chemosphere.2016.11.016

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Abstract	Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H2O2, assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H2O2 exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6–7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment. [Display omitted] •AgNPs-catalyzed degradation of BPA and EE2 was investigated.•BPA and EE2 were effectively removed with the proposed Fenton-like mechanism.•Solution pH and H2O2 had a significant effect on the degradation performance.
AbstractList	Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H2O2, assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H2O2 exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6–7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment. [Display omitted] •AgNPs-catalyzed degradation of BPA and EE2 was investigated.•BPA and EE2 were effectively removed with the proposed Fenton-like mechanism.•Solution pH and H2O2 had a significant effect on the degradation performance. Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H2O2, assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H2O2 exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6-7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment.Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H2O2, assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H2O2 exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6-7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment. Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag ) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H O , assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H O exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6-7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment. Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its soluble complexes. However, to our knowledge, little has been reported about their potential use in degrading organic contaminants such as endocrine-disrupting compounds in aqueous solution. In this first report on the subject, we examined the effectiveness of the oxidative degradation of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) in water by reactive oxygen species formed during the decomposition of H2O2, assisted by polyvinylpyrrolidone (PVP)-stabilized AgNPs. The dissolution of AgNPs accompanied generation of OH at low pH. The fully dispersed PVP-AgNPs in the presence of H2O2 exhibited fast degradation kinetics for EE2 at a typical aquatic condition of pH (6–7). The oxidation kinetics of BPA and EE2 by PVP-AgNPs can be interpreted using three different modeling approaches: an initial pseudo-first-order, a retarded first-order rate, and Behnajady-Modirshahla-Ghanbery kinetic equation. The findings showed that AgNPs may have potential to facilitate the in situ oxidation for emerging contaminants in the aqueous environment.
Author	Yoon, Yeomin Park, Chang Min Heo, Jiyong
Author_xml	– sequence: 1 givenname: Chang Min surname: Park fullname: Park, Chang Min organization: Department of Civil and Environmental Engineering, University of South Carolina, 300 Main Street, Columbia, SC 29208, USA – sequence: 2 givenname: Jiyong surname: Heo fullname: Heo, Jiyong organization: Department of Civil and Environmental Engineering, Korea Army Academy at Young-Cheon, 495 Hogook-ro, Kokyungmeon, Young-Cheon, Gyeongbuk 38900, South Korea – sequence: 3 givenname: Yeomin surname: Yoon fullname: Yoon, Yeomin email: yoony@cec.sc.edu organization: Department of Civil and Environmental Engineering, University of South Carolina, 300 Main Street, Columbia, SC 29208, USA
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Keywords	Degradation Hydroxyl radicals Bisphenol A 17α-ethinyl estradiol Silver nanoparticle
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Snippet	Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag+) and its... Silver nanoparticles (AgNPs) have been reported to have antibacterial activities and cytotoxicity, resulting from the dissolved silver cation (Ag ) and its...
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SubjectTerms	17α-ethinyl estradiol antibacterial properties aqueous solutions Benzhydryl Compounds - analysis Bisphenol A Catalysis cations cytotoxicity Degradation Endocrine Disruptors - analysis endocrine-disrupting chemicals equations estradiol Ethinyl Estradiol - analysis hydrogen peroxide Hydrogen Peroxide - chemistry Hydroxyl radicals Metal Nanoparticles - chemistry nanosilver oxidation Oxidation-Reduction Phenols - analysis polyvinylpyrrolidone Povidone - chemistry silver Silver - chemistry Silver nanoparticle Water Pollutants, Chemical - analysis
Title	Oxidative degradation of bisphenol A and 17α-ethinyl estradiol by Fenton-like activity of silver nanoparticles in aqueous solution
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