Effect of relative humidity on SOA formation from isoprene/NO photooxidation: enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions
The effect of relative humidity (RH) on secondary organic aerosol (SOA) formation from the photooxidation of isoprene under initially high nitric oxide (NO) conditions (i.e., isoprene/NO ~3) was investigated in a dual outdoor smog chamber. Based upon particle volume concentration measurements and th...
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| Published in | Atmospheric chemistry and physics Vol. 11; no. 13; pp. 6411 - 6424 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Katlenburg-Lindau
Copernicus GmbH
06.07.2011
Copernicus Publications |
| Online Access | Get full text |
| ISSN | 1680-7324 1680-7316 1680-7324 |
| DOI | 10.5194/acp-11-6411-2011 |
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| Abstract | The effect of relative humidity (RH) on secondary organic aerosol (SOA) formation from the photooxidation of isoprene under initially high nitric oxide (NO) conditions (i.e., isoprene/NO ~3) was investigated in a dual outdoor smog chamber. Based upon particle volume concentration measurements and the detailed chemical characterization of isoprene SOA using gas chromatography/mass spectrometry (GC/MS) and ultra performance liquid chromatography/electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-Q-TOFMS), enhanced SOA formation was observed under lower RH conditions (15–40 %) compared to higher RH conditions (40–90 %). 2-methylglyceric acid (2-MG) and its corresponding oligoesters, which have been previously shown to form from further oxidation of methacryloylperoxynitrate (MPAN), were enhanced in the particle-phase under lower RH conditions. In addition, an abundant unknown SOA tracer likely derived from the further oxidation of MPAN was detected and enhanced under lower RH conditions. In contrast, the 2-methyltetrols, which are known to mainly form from the reactive uptake of isoprene epoxydiols (IEPOX) under low-NO conditions in the presence of acidified aerosol, did not substantially vary under different RH conditions; however, isoprene-derived organosulfates were found to be enhanced under high-RH conditions, indicating the likely importance of the aqueous aerosol phase in their formation. Based upon the detailed chemical characterization results, particle-phase organic esterification is tentatively proposed to explain the observed enhancements of isoprene SOA mass under lower RH conditions. Alternative mechanisms explaining the enhancement of 2-MG and its corresponding oligoesters cannot be completely ruled out. This is one of only a few chamber studies that have examined the effect of RH on isoprene SOA formation. In comparison to our recent results obtained from aromatic SOA formation, the effect of RH on isoprene SOA formation is reversed. The results of this study highlight the importance of elucidating the key reactive intermediates that lead to SOA formation, especially since RH likely affects their ability in forming SOA. Furthermore, ignoring the effects of RH may significantly affect the accuracy of both regional and global SOA models. |
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| AbstractList | The effect of relative humidity (RH) on secondary organic aerosol (SOA) formation from the photooxidation of isoprene under initially high nitric oxide (NO) conditions (i.e., isoprene/NO ~3) was investigated in a dual outdoor smog chamber. Based upon particle volume concentration measurements and the detailed chemical characterization of isoprene SOA using gas chromatography/mass spectrometry (GC/MS) and ultra performance liquid chromatography/electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-Q-TOFMS), enhanced SOA formation was observed under lower RH conditions (15-40 %) compared to higher RH conditions (40-90 %). 2-methylglyceric acid (2-MG) and its corresponding oligoesters, which have been previously shown to form from further oxidation of methacryloylperoxynitrate (MPAN), were enhanced in the particle-phase under lower RH conditions. In addition, an abundant unknown SOA tracer likely derived from the further oxidation of MPAN was detected and enhanced under lower RH conditions. In contrast, the 2-methyltetrols, which are known to mainly form from the reactive uptake of isoprene epoxydiols (IEPOX) under low-NO conditions in the presence of acidified aerosol, did not substantially vary under different RH conditions; however, isoprene-derived organosulfates were found to be enhanced under high-RH conditions, indicating the likely importance of the aqueous aerosol phase in their formation. Based upon the detailed chemical characterization results, particle-phase organic esterification is tentatively proposed to explain the observed enhancements of isoprene SOA mass under lower RH conditions. Alternative mechanisms explaining the enhancement of 2-MG and its corresponding oligoesters cannot be completely ruled out. This is one of only a few chamber studies that have examined the effect of RH on isoprene SOA formation. In comparison to our recent results obtained from aromatic SOA formation, the effect of RH on isoprene SOA formation is reversed. The results of this study highlight the importance of elucidating the key reactive intermediates that lead to SOA formation, especially since RH likely affects their ability in forming SOA. Furthermore, ignoring the effects of RH may significantly affect the accuracy of both regional and global SOA models. |
| Author | Bapat, J. Surratt, J. D. Zhang, H. Lin, Y. H. Kamens, R. M. |
| Author_xml | – sequence: 1 givenname: H. surname: Zhang fullname: Zhang, H. – sequence: 2 givenname: J. D. surname: Surratt fullname: Surratt, J. D. – sequence: 3 givenname: Y. H. surname: Lin fullname: Lin, Y. H. – sequence: 4 givenname: J. surname: Bapat fullname: Bapat, J. – sequence: 5 givenname: R. M. surname: Kamens fullname: Kamens, R. M. |
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| Cites_doi | 10.1029/2006GL025976 10.1002/kin.550240109 10.5194/acp-8-1423-2008 10.1021/es0704176 10.1016/j.atmosenv.2010.01.018 10.1016/j.atmosenv.2006.03.046 10.1126/science.1092805 10.1029/2009GL041683 10.1029/2006GL027485 10.1029/94JD02950 10.5194/acp-9-5155-2009 10.5194/acp-8-4117-2008 10.1021/es901538e 10.1016/j.atmosenv.2007.11.015 10.1002/jms.1329 10.1073/pnas.1012561107 10.5194/acp-11-893-2011 10.1016/j.atmosenv.2008.05.010 10.1016/j.atmosenv.2007.04.025 10.1029/2005GL023637 10.1080/10473289.2002.10470811 10.1016/j.atmosenv.2005.05.031 10.1126/science.1172910 10.1029/2006GL026523 10.1016/S1352-2310(99)00121-1 10.1016/S1352-2310(02)00090-0 10.1016/j.atmosenv.2003.12.041 10.1016/0960-1686(92)90065-S 10.5194/acp-10-7169-2010 10.5194/acp-6-4973-2006 10.1029/2007JD009505 10.1073/pnas.0911114107 10.5194/acpd-11-9217-2011 10.5194/acp-9-1907-2009 10.1021/es062044z 10.1021/jp981929x 10.1093/oso/9780195146288.001.0001 10.1016/j.atmosenv.2006.03.013 10.5194/acp-10-8219-2010 10.5194/acp-9-3331-2009 10.5194/acp-6-3181-2006 10.1021/jp802310p 10.1021/es062081q 10.5194/acp-9-4987-2009 10.1002/jms.1146 10.1016/j.atmosres.2010.02.012 10.1016/j.atmosenv.2010.12.048 10.1016/j.atmosenv.2010.11.007 10.1080/02786820902802567 10.5194/acpd-11-4313-2011 10.1016/j.atmosenv.2010.03.031 10.1021/jp061734m 10.1021/es0720412 10.1016/1352-2310(94)00276-Q 10.1021/es0524301 10.5194/acp-7-5675-2007 10.1016/j.atmosenv.2005.08.024 10.1002/kin.550240110 10.1016/j.atmosenv.2007.05.035 10.1029/91GL01852 10.5194/acp-10-5551-2010 10.1016/j.atmosenv.2004.06.001 |
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| References | ref13 ref57 ref12 ref56 ref15 ref59 ref14 ref58 ref53 ref52 ref11 ref55 ref10 ref54 ref17 ref16 ref19 ref18 ref51 ref50 ref46 ref45 ref48 ref47 ref42 ref41 ref44 ref43 ref49 ref8 ref7 ref9 ref4 ref3 ref6 ref5 ref40 ref35 ref34 ref37 ref36 ref31 ref30 ref33 ref32 ref2 ref1 ref39 ref38 ref24 ref23 ref26 ref25 ref20 ref64 ref63 ref22 ref21 ref65 ref28 ref27 ref29 ref60 ref62 ref61 |
| References_xml | – ident: ref62 – ident: ref27 doi: 10.1029/2006GL025976 – ident: ref49 doi: 10.1002/kin.550240109 – ident: ref41 doi: 10.5194/acp-8-1423-2008 – ident: ref56 doi: 10.1021/es0704176 – ident: ref30 doi: 10.1016/j.atmosenv.2010.01.018 – ident: ref2 doi: 10.1016/j.atmosenv.2006.03.046 – ident: ref9 doi: 10.1126/science.1092805 – ident: ref44 doi: 10.1029/2009GL041683 – ident: ref33 doi: 10.1029/2006GL027485 – ident: ref22 doi: 10.1029/94JD02950 – ident: ref24 doi: 10.5194/acp-9-5155-2009 – ident: ref42 doi: 10.5194/acp-8-4117-2008 – ident: ref45 doi: 10.1021/es901538e – ident: ref1 doi: 10.1016/j.atmosenv.2007.11.015 – ident: ref21 doi: 10.1002/jms.1329 – ident: ref17 doi: 10.1073/pnas.1012561107 – ident: ref13 doi: 10.5194/acp-11-893-2011 – ident: ref52 doi: 10.1016/j.atmosenv.2008.05.010 – ident: ref29 doi: 10.1016/j.atmosenv.2007.04.025 – ident: ref34 doi: 10.1029/2005GL023637 – ident: ref5 doi: 10.1080/10473289.2002.10470811 – ident: ref36 – ident: ref15 doi: 10.1016/j.atmosenv.2005.05.031 – ident: ref48 doi: 10.1126/science.1172910 – ident: ref14 doi: 10.1029/2006GL026523 – ident: ref32 doi: 10.1016/S1352-2310(99)00121-1 – ident: ref47 doi: 10.1016/S1352-2310(02)00090-0 – ident: ref37 doi: 10.1016/j.atmosenv.2003.12.041 – ident: ref7 doi: 10.1016/0960-1686(92)90065-S – ident: ref8 doi: 10.5194/acp-10-7169-2010 – ident: ref25 doi: 10.5194/acp-6-4973-2006 – ident: ref18 doi: 10.1029/2007JD009505 – ident: ref58 doi: 10.1073/pnas.0911114107 – ident: ref43 doi: 10.5194/acpd-11-9217-2011 – ident: ref63 doi: 10.5194/acp-9-1907-2009 – ident: ref26 doi: 10.1021/es062044z – ident: ref64 doi: 10.1021/jp981929x – ident: ref6 doi: 10.1093/oso/9780195146288.001.0001 – ident: ref3 doi: 10.1016/j.atmosenv.2006.03.013 – ident: ref16 doi: 10.5194/acp-10-8219-2010 – ident: ref19 doi: 10.5194/acp-9-3331-2009 – ident: ref23 doi: 10.5194/acp-6-3181-2006 – ident: ref57 doi: 10.1021/jp802310p – ident: ref55 doi: 10.1021/es062081q – ident: ref12 doi: 10.5194/acp-9-4987-2009 – ident: ref59 doi: 10.1002/jms.1146 – ident: ref60 doi: 10.1016/j.atmosres.2010.02.012 – ident: ref65 doi: 10.1016/j.atmosenv.2010.12.048 – ident: ref31 doi: 10.1016/j.atmosenv.2010.11.007 – ident: ref40 doi: 10.1080/02786820902802567 – ident: ref53 doi: 10.5194/acpd-11-4313-2011 – ident: ref51 doi: 10.1016/j.atmosenv.2010.03.031 – ident: ref54 doi: 10.1021/jp061734m – ident: ref39 doi: 10.1021/es0720412 – ident: ref61 doi: 10.1016/1352-2310(94)00276-Q – ident: ref35 doi: 10.1021/es0524301 – ident: ref28 doi: 10.5194/acp-7-5675-2007 – ident: ref38 doi: 10.1016/j.atmosenv.2005.08.024 – ident: ref46 – ident: ref50 doi: 10.1002/kin.550240110 – ident: ref11 doi: 10.1016/j.atmosenv.2007.05.035 – ident: ref4 doi: 10.1029/91GL01852 – ident: ref20 doi: 10.5194/acp-10-5551-2010 – ident: ref10 doi: 10.1016/j.atmosenv.2004.06.001 |
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| Title | Effect of relative humidity on SOA formation from isoprene/NO photooxidation: enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions |
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