Enriching Structural Diversity of Alkynyl‐Protected Gold Nanoclusters with Chlorides
The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as‐synthesized cluster mixture to give the clusters Na[Au25L18] (Au25), [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12]...
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| Published in | Angewandte Chemie International Edition Vol. 60; no. 12; pp. 6699 - 6703 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Germany
Wiley Subscription Services, Inc
15.03.2021
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| Edition | International ed. in English |
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| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 1521-3773 |
| DOI | 10.1002/anie.202014154 |
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| Abstract | The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as‐synthesized cluster mixture to give the clusters Na[Au25L18] (Au25), [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12] (Au106), L=3,5‐bis(trifluoromethyl)‐phenylacetylide. Au67 and Au106 are new clusters; the structures were determined by X‐ray single‐crystal diffraction. Au67 contains a distorted Au18 Marks decahedron shelled by an irregular Au32 and further protected with two V‐shaped Au2L3, 13 linear AuL2 staples and 4 chlorides. Au67 is the first structurally determined 34e superatomic gold nanocluster. Au106 is composed of 106 Au atoms co‐protected by alkynyls and chlorides. It has a Au79 kernel, like in Au102(p‐MBA)44. The surface structure of Au106 includes 20 linear Au‐alkynyl staples, 5 Cl‐Au‐Cl and 2 Cl‐Au motifs. These three gold nanoclusters show size‐dependent electrochemical properties.
The combination of chloride and alkynyl as protecting agents leads to the formation of large gold nanoclusters. Silica gel column chromatography results in the successful isolation and crystallization of atomically precise gold nanoclusters [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12] (Au106), where L=3,5‐bis(trifluoromethyl)‐phenylacetylide. They are all superatomic clusters, and show size‐dependent electrochemical properties. |
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| AbstractList | The synthesis and isolation of alkynyl/chloride-protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as-synthesized cluster mixture to give the clusters Na[Au25 L18 ] (Au25 ), [HNEt3 ]3 [Au67 L32 Cl4 ] (Au67 ), [HNEt3 ]4 [Au106 L40 Cl12 ] (Au106 ), L=3,5-bis(trifluoromethyl)-phenylacetylide. Au67 and Au106 are new clusters; the structures were determined by X-ray single-crystal diffraction. Au67 contains a distorted Au18 Marks decahedron shelled by an irregular Au32 and further protected with two V-shaped Au2 L3 , 13 linear AuL2 staples and 4 chlorides. Au67 is the first structurally determined 34e superatomic gold nanocluster. Au106 is composed of 106 Au atoms co-protected by alkynyls and chlorides. It has a Au79 kernel, like in Au102 (p-MBA)44 . The surface structure of Au106 includes 20 linear Au-alkynyl staples, 5 Cl-Au-Cl and 2 Cl-Au motifs. These three gold nanoclusters show size-dependent electrochemical properties.The synthesis and isolation of alkynyl/chloride-protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as-synthesized cluster mixture to give the clusters Na[Au25 L18 ] (Au25 ), [HNEt3 ]3 [Au67 L32 Cl4 ] (Au67 ), [HNEt3 ]4 [Au106 L40 Cl12 ] (Au106 ), L=3,5-bis(trifluoromethyl)-phenylacetylide. Au67 and Au106 are new clusters; the structures were determined by X-ray single-crystal diffraction. Au67 contains a distorted Au18 Marks decahedron shelled by an irregular Au32 and further protected with two V-shaped Au2 L3 , 13 linear AuL2 staples and 4 chlorides. Au67 is the first structurally determined 34e superatomic gold nanocluster. Au106 is composed of 106 Au atoms co-protected by alkynyls and chlorides. It has a Au79 kernel, like in Au102 (p-MBA)44 . The surface structure of Au106 includes 20 linear Au-alkynyl staples, 5 Cl-Au-Cl and 2 Cl-Au motifs. These three gold nanoclusters show size-dependent electrochemical properties. The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as‐synthesized cluster mixture to give the clusters Na[Au25L18] (Au25), [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12] (Au106), L=3,5‐bis(trifluoromethyl)‐phenylacetylide. Au67 and Au106 are new clusters; the structures were determined by X‐ray single‐crystal diffraction. Au67 contains a distorted Au18 Marks decahedron shelled by an irregular Au32 and further protected with two V‐shaped Au2L3, 13 linear AuL2 staples and 4 chlorides. Au67 is the first structurally determined 34e superatomic gold nanocluster. Au106 is composed of 106 Au atoms co‐protected by alkynyls and chlorides. It has a Au79 kernel, like in Au102(p‐MBA)44. The surface structure of Au106 includes 20 linear Au‐alkynyl staples, 5 Cl‐Au‐Cl and 2 Cl‐Au motifs. These three gold nanoclusters show size‐dependent electrochemical properties. The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as‐synthesized cluster mixture to give the clusters Na[Au25L18] (Au25), [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12] (Au106), L=3,5‐bis(trifluoromethyl)‐phenylacetylide. Au67 and Au106 are new clusters; the structures were determined by X‐ray single‐crystal diffraction. Au67 contains a distorted Au18 Marks decahedron shelled by an irregular Au32 and further protected with two V‐shaped Au2L3, 13 linear AuL2 staples and 4 chlorides. Au67 is the first structurally determined 34e superatomic gold nanocluster. Au106 is composed of 106 Au atoms co‐protected by alkynyls and chlorides. It has a Au79 kernel, like in Au102(p‐MBA)44. The surface structure of Au106 includes 20 linear Au‐alkynyl staples, 5 Cl‐Au‐Cl and 2 Cl‐Au motifs. These three gold nanoclusters show size‐dependent electrochemical properties. The combination of chloride and alkynyl as protecting agents leads to the formation of large gold nanoclusters. Silica gel column chromatography results in the successful isolation and crystallization of atomically precise gold nanoclusters [HNEt3]3[Au67L32Cl4] (Au67), [HNEt3]4[Au106L40Cl12] (Au106), where L=3,5‐bis(trifluoromethyl)‐phenylacetylide. They are all superatomic clusters, and show size‐dependent electrochemical properties. The synthesis and isolation of alkynyl/chloride-protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as-synthesized cluster mixture to give the clusters Na[Au L ] (Au ), [HNEt ] [Au L Cl ] (Au ), [HNEt ] [Au L Cl ] (Au ), L=3,5-bis(trifluoromethyl)-phenylacetylide. Au and Au are new clusters; the structures were determined by X-ray single-crystal diffraction. Au contains a distorted Au Marks decahedron shelled by an irregular Au and further protected with two V-shaped Au L , 13 linear AuL staples and 4 chlorides. Au is the first structurally determined 34e superatomic gold nanocluster. Au is composed of 106 Au atoms co-protected by alkynyls and chlorides. It has a Au kernel, like in Au (p-MBA) . The surface structure of Au includes 20 linear Au-alkynyl staples, 5 Cl-Au-Cl and 2 Cl-Au motifs. These three gold nanoclusters show size-dependent electrochemical properties. The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold nanoclusters from the as‐synthesized cluster mixture to give the clusters Na[Au 25 L 18 ] ( Au 25 ), [HNEt 3 ] 3 [Au 67 L 32 Cl 4 ] ( Au 67 ), [HNEt 3 ] 4 [Au 106 L 40 Cl 12 ] ( Au 106 ), L=3,5‐bis(trifluoromethyl)‐phenylacetylide. Au 67 and Au 106 are new clusters; the structures were determined by X‐ray single‐crystal diffraction. Au 67 contains a distorted Au 18 Marks decahedron shelled by an irregular Au 32 and further protected with two V‐shaped Au 2 L 3 , 13 linear AuL 2 staples and 4 chlorides. Au 67 is the first structurally determined 34e superatomic gold nanocluster. Au 106 is composed of 106 Au atoms co‐protected by alkynyls and chlorides. It has a Au 79 kernel, like in Au 102 ( p ‐MBA) 44 . The surface structure of Au 106 includes 20 linear Au‐alkynyl staples, 5 Cl‐Au‐Cl and 2 Cl‐Au motifs. These three gold nanoclusters show size‐dependent electrochemical properties. |
| Author | Li, Jiao‐Jiao Guan, Zong‐Jie Wang, Quan‐Ming Yuan, Shang‐Fu Hu, Feng |
| Author_xml | – sequence: 1 givenname: Jiao‐Jiao surname: Li fullname: Li, Jiao‐Jiao organization: Tsinghua University – sequence: 2 givenname: Zong‐Jie orcidid: 0000-0001-8977-0850 surname: Guan fullname: Guan, Zong‐Jie organization: Tsinghua University – sequence: 3 givenname: Shang‐Fu surname: Yuan fullname: Yuan, Shang‐Fu organization: Tsinghua University – sequence: 4 givenname: Feng surname: Hu fullname: Hu, Feng organization: Tsinghua University – sequence: 5 givenname: Quan‐Ming orcidid: 0000-0002-3764-6409 surname: Wang fullname: Wang, Quan‐Ming email: qmwang@tsinghua.edu.cn organization: Tsinghua University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/33336534$$D View this record in MEDLINE/PubMed |
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| Keywords | gold silica gel column chromatography chloride cluster compounds alkynes |
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| Snippet | The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold... The synthesis and isolation of alkynyl/chloride-protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold... |
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| SubjectTerms | alkynes chloride Chlorides cluster compounds Clusters Column chromatography Crystal structure Electrochemical analysis Electrochemistry Gold Nanoclusters Silica Silica gel silica gel column chromatography Silicon dioxide Staples Surface structure |
| Title | Enriching Structural Diversity of Alkynyl‐Protected Gold Nanoclusters with Chlorides |
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