Improvement of the Direct Determination Method of Linamarin in Beans and Bean Paste Products
A method for the direct determination of linamarin, a cyanogenic glycoside in beans, bean paste products and cassava flour was improved. A sample was extracted with a mixture of acetonitrile and water, cleaned up by using a solid-phase extraction cartridge, and trimethylsilylated, then linamarin was...
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| Published in | Food Hygiene and Safety Science (Shokuhin Eiseigaku Zasshi) Vol. 34; no. 1; pp. 74 - 79_1 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English Japanese |
| Published |
Japanese Society for Food Hygiene and Safety
1993
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0015-6426 1882-1006 |
| DOI | 10.3358/shokueishi.34.74 |
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| Abstract | A method for the direct determination of linamarin, a cyanogenic glycoside in beans, bean paste products and cassava flour was improved. A sample was extracted with a mixture of acetonitrile and water, cleaned up by using a solid-phase extraction cartridge, and trimethylsilylated, then linamarin was quantitated by FID-GC and confirmed by GC/MS. The detection limit of linamarin was 1μg/g in beans, 0.25μg/g in dry bean paste and 0.1μg/g in raw paste. The contents of linamarin in beans, bean paste products and cassava flour were surveyed. The contents of linamarin determined by the proposed method were in good accordance with those found by the headspace GC method. |
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| AbstractList | A method for the direct determination of linamarin, a cyanogenic glycoside in beans, bean paste products and cassava flour was improved. A sample was extracted with a mixture of acetonitrile and water, cleaned up by using a solid-phase extraction cartridge, and trimethylsilylated, then linamarin was quantitated by FID-GC and confirmed by GC/MS. The detection limit of linamarin was 1μg/g in beans, 0.25μg/g in dry bean paste and 0.1μg/g in raw paste. The contents of linamarin in beans, bean paste products and cassava flour were surveyed. The contents of linamarin determined by the proposed method were in good accordance with those found by the headspace GC method. |
| Author | KAWAMURA, Yoko HIKIDI, Siga UCHIYAMA, Sadao SAITO, Yukio MARUYAMA, Kouji |
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| References | 1) 厚生省食品保健課・乳肉衛生課・食品化学課編:“食品衛生関係法規集1”p. 1,213-1,215 (1991), 中央法規出版. 6) 近本武次, 米谷武士: 食衛誌. 25, 530-533 (1984). 4) 有賀孝成, 冠政光, 中里光男, 藤沼賢司, 西島基弘, 直井家壽太: 食衛誌. 24, 289-294 (1983). 5) 近本武次, 米谷武士: 分析化学 33, 325-327 (1984). 8) WHO ed.: “Evaluation of Certain Food Additives and Contaminants-39th Report of the Joint FAO/WHO Expert Committee on Food Additives” p. 1-2 (1992), WHO, Geneva. 2) 日本薬学会編:“衛生試験法・注解1990”p. 387-391 (1990), 金原出版. 11) 西山修, 栗田礼子, 梶本寛, 安井陽子, 金田吉男: 食衛誌. 30, 491-495 (1989 7) 中村優美子, 外海泰秀, 長谷川ゆかり, 田辺弘也, 伊藤誉志男: 衛生化学 34, 139-145 (1988). 9) Brimer, L., Dalgaard, L.: J. Chromatogr. 303, 77-88 (1984). 3) 黒田弘之, 毛利孝明, 広瀬秀雄, 多田御幸: 食衛誌. 14, 558-560 (1973). 10) Seigler, D. S.: Phytochemistry 14, 9-29 (1975). |
| References_xml | – reference: 6) 近本武次, 米谷武士: 食衛誌. 25, 530-533 (1984). – reference: 2) 日本薬学会編:“衛生試験法・注解1990”p. 387-391 (1990), 金原出版. – reference: 4) 有賀孝成, 冠政光, 中里光男, 藤沼賢司, 西島基弘, 直井家壽太: 食衛誌. 24, 289-294 (1983). – reference: 9) Brimer, L., Dalgaard, L.: J. Chromatogr. 303, 77-88 (1984). – reference: 1) 厚生省食品保健課・乳肉衛生課・食品化学課編:“食品衛生関係法規集1”p. 1,213-1,215 (1991), 中央法規出版. – reference: 5) 近本武次, 米谷武士: 分析化学 33, 325-327 (1984). – reference: 10) Seigler, D. S.: Phytochemistry 14, 9-29 (1975). – reference: 7) 中村優美子, 外海泰秀, 長谷川ゆかり, 田辺弘也, 伊藤誉志男: 衛生化学 34, 139-145 (1988). – reference: 11) 西山修, 栗田礼子, 梶本寛, 安井陽子, 金田吉男: 食衛誌. 30, 491-495 (1989) – reference: 3) 黒田弘之, 毛利孝明, 広瀬秀雄, 多田御幸: 食衛誌. 14, 558-560 (1973). – reference: 8) WHO ed.: “Evaluation of Certain Food Additives and Contaminants-39th Report of the Joint FAO/WHO Expert Committee on Food Additives” p. 1-2 (1992), WHO, Geneva. |
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| SubjectTerms | bean paste products beans cassava flour cyanogenic glycoside linamarin solid phase extraction cartridge trimethyl silylation |
| Title | Improvement of the Direct Determination Method of Linamarin in Beans and Bean Paste Products |
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