Biological Durability of Wood–Polymer Composites—The Role of Moisture and Aging
Knowledge about the resistance of wood–polymer composites (WPCs) to biological attack is of high importance for purpose-oriented use in outdoor applications. To gain this knowledge, uniform test methods are essential. EN 15534-1 (2018) provides a general framework, including the recommendation of ap...
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          | Published in | Materials Vol. 15; no. 23; p. 8556 | 
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| Main Authors | , , , , | 
| Format | Journal Article | 
| Language | English | 
| Published | 
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        01.12.2022
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| Online Access | Get full text | 
| ISSN | 1996-1944 1996-1944  | 
| DOI | 10.3390/ma15238556 | 
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| Abstract | Knowledge about the resistance of wood–polymer composites (WPCs) to biological attack is of high importance for purpose-oriented use in outdoor applications. To gain this knowledge, uniform test methods are essential. EN 15534-1 (2018) provides a general framework, including the recommendation of applying a pre-weathering procedure before the biological laboratory tests. However, the procedure’s manner is not specified, and its necessity assumes that a durability test without such pre-weathering will not produce the structural changes that occur during outdoor use. To verify this assumption, this study examined the influence of natural, ground-level pre-weathering on the material properties of different WPC variants, which were tested at intervals of six months in four durability tests under laboratory conditions in accordance with EN 15534-1 (2018). Weathering factors were calculated from determined characteristic values such as mass loss, and loss in moduli of elasticity (MOE) and rupture (MOR). The weathering factors based on mechanical properties tended to decrease with increasing weathering duration. The expected negative influence of pre-weathering on these material properties was thus not confirmed. The weathering factors based on mass loss were subject to high variation. No significant effect of pre-weathering on mass loss due to fungal attack became evident. Overall, the necessity of a pre-weathering step in biological durability tests shall be questioned based on the presented results. | 
    
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| AbstractList | Knowledge about the resistance of wood–polymer composites (WPCs) to biological attack is of high importance for purpose-oriented use in outdoor applications. To gain this knowledge, uniform test methods are essential. EN 15534-1 (2018) provides a general framework, including the recommendation of applying a pre-weathering procedure before the biological laboratory tests. However, the procedure’s manner is not specified, and its necessity assumes that a durability test without such pre-weathering will not produce the structural changes that occur during outdoor use. To verify this assumption, this study examined the influence of natural, ground-level pre-weathering on the material properties of different WPC variants, which were tested at intervals of six months in four durability tests under laboratory conditions in accordance with EN 15534-1 (2018). Weathering factors were calculated from determined characteristic values such as mass loss, and loss in moduli of elasticity (MOE) and rupture (MOR). The weathering factors based on mechanical properties tended to decrease with increasing weathering duration. The expected negative influence of pre-weathering on these material properties was thus not confirmed. The weathering factors based on mass loss were subject to high variation. No significant effect of pre-weathering on mass loss due to fungal attack became evident. Overall, the necessity of a pre-weathering step in biological durability tests shall be questioned based on the presented results. Knowledge about the resistance of wood-polymer composites (WPCs) to biological attack is of high importance for purpose-oriented use in outdoor applications. To gain this knowledge, uniform test methods are essential. EN 15534-1 (2018) provides a general framework, including the recommendation of applying a pre-weathering procedure before the biological laboratory tests. However, the procedure's manner is not specified, and its necessity assumes that a durability test without such pre-weathering will not produce the structural changes that occur during outdoor use. To verify this assumption, this study examined the influence of natural, ground-level pre-weathering on the material properties of different WPC variants, which were tested at intervals of six months in four durability tests under laboratory conditions in accordance with EN 15534-1 (2018). Weathering factors were calculated from determined characteristic values such as mass loss, and loss in moduli of elasticity (MOE) and rupture (MOR). The weathering factors based on mechanical properties tended to decrease with increasing weathering duration. The expected negative influence of pre-weathering on these material properties was thus not confirmed. The weathering factors based on mass loss were subject to high variation. No significant effect of pre-weathering on mass loss due to fungal attack became evident. Overall, the necessity of a pre-weathering step in biological durability tests shall be questioned based on the presented results.Knowledge about the resistance of wood-polymer composites (WPCs) to biological attack is of high importance for purpose-oriented use in outdoor applications. To gain this knowledge, uniform test methods are essential. EN 15534-1 (2018) provides a general framework, including the recommendation of applying a pre-weathering procedure before the biological laboratory tests. However, the procedure's manner is not specified, and its necessity assumes that a durability test without such pre-weathering will not produce the structural changes that occur during outdoor use. To verify this assumption, this study examined the influence of natural, ground-level pre-weathering on the material properties of different WPC variants, which were tested at intervals of six months in four durability tests under laboratory conditions in accordance with EN 15534-1 (2018). Weathering factors were calculated from determined characteristic values such as mass loss, and loss in moduli of elasticity (MOE) and rupture (MOR). The weathering factors based on mechanical properties tended to decrease with increasing weathering duration. The expected negative influence of pre-weathering on these material properties was thus not confirmed. The weathering factors based on mass loss were subject to high variation. No significant effect of pre-weathering on mass loss due to fungal attack became evident. Overall, the necessity of a pre-weathering step in biological durability tests shall be questioned based on the presented results.  | 
    
| Audience | Academic | 
    
| Author | Kilian, Thomas Klein, Kim Christian Brischke, Christian Buschalsky, Andreas Militz, Holger  | 
    
| AuthorAffiliation | 2 Fagus-GreCon Greten GmbH & Co. KG, Hannoversche Straße 58, 31061 Alfeld, Germany 3 SKZ-KFE gGmbH, Friedrich-Bergius-Ring 22, 97076 Wuerzburg, Germany 1 Wood Biology and Wood Products, Faculty of Forest Sciences and Forest Ecology, University of Goettingen, Buesgenweg 4, 37077 Goettingen, Germany  | 
    
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| Cites_doi | 10.1016/j.ibiod.2009.07.010 10.3390/fib7100092 10.1002/pc.20212 10.1080/17480272.2014.916347 10.1002/app.25037 10.1080/17480270903261339 10.1016/j.polymdegradstab.2007.06.017 10.1533/9781845694579.142  | 
    
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| Keywords | EN 15534-1 basidiomycetes wood–moisture interaction biological durability WPC soft rot durability test wood–polymer composites  | 
    
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| References | Clemons (ref_6) 2002; 52 Mankowski (ref_7) 2000; 32 Rowell (ref_5) 2009; 4 Schirp (ref_20) 2005; 37 Stark (ref_1) 2007; 92 ref_14 ref_13 ref_12 ref_11 ref_10 Steckel (ref_2) 2007; 103 Krause (ref_19) 2014; 9 Defoirdt (ref_21) 2010; 64 ref_18 ref_17 ref_16 ref_15 Morris (ref_8) 1998; 48 ref_9 Witt (ref_3) 2006; 27 Ahmad (ref_4) 2011; 2011  | 
    
| References_xml | – volume: 64 start-page: 65 year: 2010 ident: ref_21 article-title: Moisture Dynamics of WPC and the Impact on Fungal Testing publication-title: Int. Biodeterior. Biodegrad. doi: 10.1016/j.ibiod.2009.07.010 – ident: ref_15 doi: 10.3390/fib7100092 – volume: 27 start-page: 323 year: 2006 ident: ref_3 article-title: Effects of Soaking and Freezing on Composites Made from Wood-Based Fillers and Biodegradable Plastics publication-title: Polym. Compos. doi: 10.1002/pc.20212 – ident: ref_12 – ident: ref_10 – ident: ref_11 – volume: 37 start-page: 643 year: 2005 ident: ref_20 article-title: Influence of Fungal Decay and Moisture Absorption on Mechanical Properties of Extruded Wood-Plastic Composites publication-title: Wood Fiber Sci. – ident: ref_16 – volume: 48 start-page: 86 year: 1998 ident: ref_8 article-title: Recycled Plastic/Wood Composite Lumber Attacked by Fungi publication-title: For. Prod. J. – volume: 2011 start-page: 406284 year: 2011 ident: ref_4 article-title: The Comparison of Water Absorption Analysis between Counterrotating and Corotating Twin-Screw Extruders with Different Antioxidants Content in Wood Plastic Composites publication-title: Adv. Mater. Sci. Eng. – ident: ref_13 – ident: ref_14 – volume: 9 start-page: 179 year: 2014 ident: ref_19 article-title: Evaluating Durability of Thermoplastic Wood Composites against Basidiomycetes and Development of a Suitable Test Design publication-title: Wood Mater. Sci. Eng. doi: 10.1080/17480272.2014.916347 – volume: 32 start-page: 340 year: 2000 ident: ref_7 article-title: Patterns of Fungal Attack in Wood-Plastic Composites Following Exposure in a Soil Block Test publication-title: Wood Fiber Sci. – ident: ref_17 – ident: ref_18 – volume: 103 start-page: 752 year: 2007 ident: ref_2 article-title: Effects of Material Parameters on the Diffusion and Sorption Properties of Wood-Flour/Polypropylene Composites publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.25037 – volume: 4 start-page: 14 year: 2009 ident: ref_5 article-title: Understanding Decay Resistance, Dimensional Stability and Strength Changes in Heat-Treated and Acetylated Wood publication-title: Wood Mater. Sci. Eng. doi: 10.1080/17480270903261339 – volume: 52 start-page: 10 year: 2002 ident: ref_6 article-title: Wood-Plastic Composites in the United States: The Interfacing of Two Industries publication-title: For. Prod. J. – volume: 92 start-page: 1883 year: 2007 ident: ref_1 article-title: Characterization of Weathered Wood–Plastic Composite Surfaces Using FTIR Spectroscopy, Contact Angle, and XPS publication-title: Polym. Degrad. Stab. doi: 10.1016/j.polymdegradstab.2007.06.017 – ident: ref_9 doi: 10.1533/9781845694579.142  | 
    
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| SubjectTerms | Aging Aging (natural) Air conditioning Building materials Durability Fungi Laboratories Laboratory tests Material properties Mathematical analysis Mechanical properties Microorganisms Moisture content Moisture effects Moisture resistance Polymer matrix composites Polymers Service life Test methods Weathering  | 
    
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| Title | Biological Durability of Wood–Polymer Composites—The Role of Moisture and Aging | 
    
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