Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei
Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is lim...
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| Published in | Solid state nuclear magnetic resonance Vol. 84; pp. 89 - 102 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Netherlands
Elsevier Inc
01.07.2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0926-2040 1527-3326 1527-3326 |
| DOI | 10.1016/j.ssnmr.2017.01.001 |
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| Abstract | Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is limited. A number of methods have been introduced in the literature to attempt to address this problem. Recently, we have introduced an alternative, automated approach, based on numerical simulations, for generating amplitude-modulated pulses (termed FAM-N pulses) to enhance the efficiency of the triple- to single-quantum conversion step within MQMAS. This results in efficient pulses that can be used without experimental reoptimisation, ensuring that this method is particularly suitable for challenging nuclei and systems. In this work, we investigate the applicability of FAM-N pulses to a wider variety of systems, and their robustness under more challenging experimental conditions. These include experiments performed under fast MAS, nuclei with higher spin quantum numbers, samples with multiple distinct sites, low-γ nuclei and nuclei subject to large quadrupolar interactions.
[Display omitted]
•High-throughput optimisation of FAM-N pulses for MQMAS NMR of quadrupolar nuclei.•Applicability of FAM-N pulses to higher spin systems and efficiency under fast MAS.•Application of FAM-N to more challenging systems without experimental re-optimisation.•Investigation into the differences between experimental and theoretical enhancements. |
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| AbstractList | Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is limited. A number of methods have been introduced in the literature to attempt to address this problem. Recently, we have introduced an alternative, automated approach, based on numerical simulations, for generating amplitude-modulated pulses (termed FAM-N pulses) to enhance the efficiency of the triple- to single-quantum conversion step within MQMAS. This results in efficient pulses that can be used without experimental reoptimisation, ensuring that this method is particularly suitable for challenging nuclei and systems. In this work, we investigate the applicability of FAM-N pulses to a wider variety of systems, and their robustness under more challenging experimental conditions. These include experiments performed under fast MAS, nuclei with higher spin quantum numbers, samples with multiple distinct sites, low-γ nuclei and nuclei subject to large quadrupolar interactions.Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is limited. A number of methods have been introduced in the literature to attempt to address this problem. Recently, we have introduced an alternative, automated approach, based on numerical simulations, for generating amplitude-modulated pulses (termed FAM-N pulses) to enhance the efficiency of the triple- to single-quantum conversion step within MQMAS. This results in efficient pulses that can be used without experimental reoptimisation, ensuring that this method is particularly suitable for challenging nuclei and systems. In this work, we investigate the applicability of FAM-N pulses to a wider variety of systems, and their robustness under more challenging experimental conditions. These include experiments performed under fast MAS, nuclei with higher spin quantum numbers, samples with multiple distinct sites, low-γ nuclei and nuclei subject to large quadrupolar interactions. Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is limited. A number of methods have been introduced in the literature to attempt to address this problem. Recently, we have introduced an alternative, automated approach, based on numerical simulations, for generating amplitude-modulated pulses (termed FAM-N pulses) to enhance the efficiency of the triple- to single-quantum conversion step within MQMAS. This results in efficient pulses that can be used without experimental reoptimisation, ensuring that this method is particularly suitable for challenging nuclei and systems. In this work, we investigate the applicability of FAM-N pulses to a wider variety of systems, and their robustness under more challenging experimental conditions. These include experiments performed under fast MAS, nuclei with higher spin quantum numbers, samples with multiple distinct sites, low-γ nuclei and nuclei subject to large quadrupolar interactions. Although a popular choice for obtaining high-resolution solid-state NMR spectra of quadrupolar nuclei, the inherently low sensitivity of the multiple-quantum magic-angle spinning (MQMAS) experiment has limited its application for nuclei with low receptivity or when the available sample volume is limited. A number of methods have been introduced in the literature to attempt to address this problem. Recently, we have introduced an alternative, automated approach, based on numerical simulations, for generating amplitude-modulated pulses (termed FAM-N pulses) to enhance the efficiency of the triple- to single-quantum conversion step within MQMAS. This results in efficient pulses that can be used without experimental reoptimisation, ensuring that this method is particularly suitable for challenging nuclei and systems. In this work, we investigate the applicability of FAM-N pulses to a wider variety of systems, and their robustness under more challenging experimental conditions. These include experiments performed under fast MAS, nuclei with higher spin quantum numbers, samples with multiple distinct sites, low-γ nuclei and nuclei subject to large quadrupolar interactions. [Display omitted] •High-throughput optimisation of FAM-N pulses for MQMAS NMR of quadrupolar nuclei.•Applicability of FAM-N pulses to higher spin systems and efficiency under fast MAS.•Application of FAM-N to more challenging systems without experimental re-optimisation.•Investigation into the differences between experimental and theoretical enhancements. |
| Author | Ashbrook, Sharon E. Dawson, Daniel M. Colaux, Henri |
| Author_xml | – sequence: 1 givenname: Henri surname: Colaux fullname: Colaux, Henri – sequence: 2 givenname: Daniel M. surname: Dawson fullname: Dawson, Daniel M. – sequence: 3 givenname: Sharon E. surname: Ashbrook fullname: Ashbrook, Sharon E. email: sema@st-andrews.ac.uk |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28131696$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1002_mrc_5116 crossref_primary_10_1146_annurev_anchem_061417_125852 crossref_primary_10_1016_j_jmro_2024_100177 crossref_primary_10_1002_chem_202101421 crossref_primary_10_1016_j_jmr_2020_106873 crossref_primary_10_1021_acs_jpclett_4c00563 crossref_primary_10_1016_j_ssnmr_2019_03_002 crossref_primary_10_1063_1_5038547 crossref_primary_10_1515_psr_2019_0086 |
| Cites_doi | 10.1021/jp047868m 10.1016/j.ssnmr.2006.09.002 10.1039/c39880001483 10.1021/ja9614676 10.1016/j.jmr.2004.03.021 10.1021/jp049603d 10.1016/0009-2614(96)00809-3 10.1006/jmre.2000.2174 10.1016/S0926-2040(99)00053-3 10.1039/c3ce40875b 10.1039/c1cp20258h 10.1016/S0009-2614(98)01402-X 10.1080/00268978800101571 10.1021/ja9939791 10.1016/j.jmr.2007.05.020 10.1016/S0066-4103(04)54003-6 10.1021/ja036777k 10.1016/0375-9601(78)90023-3 10.1007/b98650 10.1021/ja057682g 10.1016/j.ssnmr.2007.09.003 10.1006/jmre.1997.1275 10.1103/PhysRev.94.630 10.1006/jmre.2000.2190 10.1039/ft9918702453 10.1021/ja00124a023 10.1016/0009-2614(88)87362-7 10.1063/1.1716296 10.1021/jp992798i 10.1021/jp111531e 10.1021/jp505752c 10.1063/1.480804 10.2138/am.2010.3403 10.1016/S0926-2040(97)00027-1 10.1006/jmre.1996.1059 10.1016/j.ssnmr.2005.09.003 10.1021/ja0203869 10.1063/1.3263904 10.1016/S0926-2040(00)00081-3 10.1016/j.cplett.2005.01.023 10.1006/jmre.2000.2179 10.1021/cm060590l 10.2138/am-1996-5-602 10.1006/jmre.1997.1217 10.1002/mrc.1238 10.1016/0926-2040(95)01210-9 10.1016/S0009-2614(02)01681-0 10.1021/ja054035g 10.1016/j.jmr.2004.11.001 10.1016/S0926-2040(99)00054-5 10.1016/S1090-7807(03)00016-8 10.1246/cl.1984.293 10.1016/S0009-2614(99)00446-7 10.1016/j.pnmrs.2004.04.002 10.1063/1.1333407 10.1021/jp304868w 10.1021/ja101860r 10.1021/jp310878b 10.1016/S0009-2614(00)00298-0 10.1016/S0926-2040(96)01284-2 10.1016/S0926-2040(99)00011-9 |
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| Keywords | MQMAS Quadrupolar nuclei Fast-amplitude modulation Challenging systems Solid-state MAS NMR spectroscopy FAM-N pulses |
| Language | English |
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| References | Colaux, Dawson, Ashbrook (bib37) 2014; 118 Ashbrook, Wimperis (bib61) 2003; 162 Derighetti, Hafner, Marxer, Rager (bib65) 1978; 66 Larsen, Farnan (bib53) 2004; 108 Morais, Lopes, Fernandez, Rocha (bib38) 2003; 41 Davis, Brouwer, Lipton, Gan, Mueller (bib67) 2001; 95 Antonijevic, Ashbrook, Biedesek, Walton, Wimperis, Yang (bib17) 2006; 128 Kim, Hsieh, Stebbins (bib54) 2006; 18 Bak, Rasmussen, Nielsen (bib40) 2000; 147 Ashbrook, Wimperis (bib49) 2009; 131 Vosegaard, Florian, Massiot, Grandinetti (bib29) 2001; 114 Johnston, Griffin, Walton, Dawson, Lightfoot, Ashbrook (bib55) 2011; 13 Tabeta, Saito (bib43) 1984; 13 Ashbrook, Wimperis (bib36) 2000; 147 Amoureux, Fernandez (bib12) 1998; 10 Pruski, Wiench, Amoureux (bib26) 2000; 147 Massiot, Touzo, Trumeau, Virlet, Florian, Grandinetti (bib39) 1996; 6 Gan, Kwak (bib19) 2004; 168 Carr, Purcell (bib32) 1954; 94 Lapina, Khabibulin, Romanenko, Gan, Zuev, Krasil’nikov, Fedorov (bib47) 2005; 28 Ashbrook, Griffin (bib64) 2013; 79 Rocha, Morais, Fernandez (bib9) 2005; 246 Trebosc, Amoureux, Gan (bib18) 2007; 31 Siegel, Nakashima, Wasylishen (bib25) 2005; 403 MATLAB Release 2011b, The MathWorks, Inc., Natick, Massachusetts, United States. Pruski, Lang, Fernandez, Amoureux (bib35) 1997; 7 Ashbrook, Dawson, Griffin (bib2) 2014 Brown, Wimperis (bib7) 1997; 128 Engelhardt, Kentgens, Koller, Samoson (bib50) 1999; 15 Llor, Virlet (bib4) 1988; 152 Amoureux, Delevoye, Steuernagel, Gan, Ganapathy, Montagne (bib20) 2005; 172 Vosegaard, Kehlet, Khaneja, Glaser, Nielsen (bib31) 2005; 127 Brown, Wimperis (bib42) 1997; 124 Pike, Malde, Ashbrook, McManus, Wimperis (bib48) 2000; 16 Barrie (bib45) 1998; 102 Samoson, Lippmaa, Pines (bib5) 1988; 65 Massiot, Vosegaard, Magneron, Trumeau, Montouillout, Berthet, Loiseau, Bujoli (bib58) 1999; 15 Alemany, Steuernagel, Amoureux, Callender, Barron (bib59) 1999; 14 Meiboom, Gill (bib33) 1958; 29 O’Dell, Ratcliffe (bib69) 2011; 115 Madhu, Goldbourt, Frydman, Vega (bib23) 2000; 112 Kentgens, Verhagen (bib21) 1999; 300 Kanellopoulos, Freude, Kentgens (bib10) 2007; 32 Ashbrook, Wimperis (bib52) 2002; 124 Goldburt, Madhu, Vega (bib24) 2000; 320 Goldburt, Madhu (bib8) 2005; 54 Johnston, Mitchell, Blanc, Lightfoot, Ashbrook (bib46) 2013; 117 Koczor, Rohonczy (bib30) 2016; 75 Amoureux, Pruski, Lang, Fernandez (bib13) 1998; 131 MacKenzie, Smith (bib1) 2002 Ashbrook, Berry, Hibberson, Steuernagel, Wimperis (bib16) 2003; 125 Gan (bib14) 2000; 122 Gan, Srinivasan, Quine, Steuernagel, Knott (bib60) 2003; 367 Dupree, Smith (bib44) 1988 Ball, Wimperis (bib27) 2007; 187 Johnston, Tang, Parker, Knight, Lightfoot, Ashbrook (bib56) 2010; 132 Madhu, Goldbourt, Frydman, Vega (bib22) 1999; 307 Larsen, Nielsen (bib34) 1999; 103 Winkler, Blaha, Schwarz (bib66) 1996; 81 Pontryagin, Boltyanskii, Gamkreldze, Mishchenko (bib68) 1962 Dowell, Ashbrook, Wimperis (bib62) 2004; 108 Perras, Korobkov, Bryce (bib51) 2013; 15 Ashbrook, Wimperis (bib15) 2004; 45 Amoureux, Fernandez, Frydman (bib11) 1996; 259 (bib3) 2012 Wu, Rovnyak, Griffin (bib28) 1996; 118 Bastow (bib63) 1991; 87 Frydman, Harwood (bib6) 1995; 117 Amri, Ashbrook, Dawson, Griffin, Walton, Wimperis (bib57) 2012; 116 Barrie (10.1016/j.ssnmr.2017.01.001_bib45) 1998; 102 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib64) 2013; 79 Larsen (10.1016/j.ssnmr.2017.01.001_bib53) 2004; 108 Kanellopoulos (10.1016/j.ssnmr.2017.01.001_bib10) 2007; 32 Engelhardt (10.1016/j.ssnmr.2017.01.001_bib50) 1999; 15 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib49) 2009; 131 Goldburt (10.1016/j.ssnmr.2017.01.001_bib24) 2000; 320 Massiot (10.1016/j.ssnmr.2017.01.001_bib39) 1996; 6 Pruski (10.1016/j.ssnmr.2017.01.001_bib26) 2000; 147 Koczor (10.1016/j.ssnmr.2017.01.001_bib30) 2016; 75 Vosegaard (10.1016/j.ssnmr.2017.01.001_bib29) 2001; 114 Vosegaard (10.1016/j.ssnmr.2017.01.001_bib31) 2005; 127 Pontryagin (10.1016/j.ssnmr.2017.01.001_bib68) 1962 Kim (10.1016/j.ssnmr.2017.01.001_bib54) 2006; 18 MacKenzie (10.1016/j.ssnmr.2017.01.001_bib1) 2002 Gan (10.1016/j.ssnmr.2017.01.001_bib14) 2000; 122 Wu (10.1016/j.ssnmr.2017.01.001_bib28) 1996; 118 Morais (10.1016/j.ssnmr.2017.01.001_bib38) 2003; 41 Winkler (10.1016/j.ssnmr.2017.01.001_bib66) 1996; 81 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib15) 2004; 45 Dowell (10.1016/j.ssnmr.2017.01.001_bib62) 2004; 108 Amoureux (10.1016/j.ssnmr.2017.01.001_bib11) 1996; 259 Amri (10.1016/j.ssnmr.2017.01.001_bib57) 2012; 116 Siegel (10.1016/j.ssnmr.2017.01.001_bib25) 2005; 403 Amoureux (10.1016/j.ssnmr.2017.01.001_bib12) 1998; 10 Perras (10.1016/j.ssnmr.2017.01.001_bib51) 2013; 15 Gan (10.1016/j.ssnmr.2017.01.001_bib19) 2004; 168 Bastow (10.1016/j.ssnmr.2017.01.001_bib63) 1991; 87 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib16) 2003; 125 Ball (10.1016/j.ssnmr.2017.01.001_bib27) 2007; 187 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib2) 2014 Johnston (10.1016/j.ssnmr.2017.01.001_bib55) 2011; 13 Johnston (10.1016/j.ssnmr.2017.01.001_bib46) 2013; 117 Kentgens (10.1016/j.ssnmr.2017.01.001_bib21) 1999; 300 Bak (10.1016/j.ssnmr.2017.01.001_bib40) 2000; 147 Johnston (10.1016/j.ssnmr.2017.01.001_bib56) 2010; 132 Madhu (10.1016/j.ssnmr.2017.01.001_bib23) 2000; 112 Meiboom (10.1016/j.ssnmr.2017.01.001_bib33) 1958; 29 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib52) 2002; 124 (10.1016/j.ssnmr.2017.01.001_bib3) 2012 Tabeta (10.1016/j.ssnmr.2017.01.001_bib43) 1984; 13 Antonijevic (10.1016/j.ssnmr.2017.01.001_bib17) 2006; 128 Lapina (10.1016/j.ssnmr.2017.01.001_bib47) 2005; 28 Goldburt (10.1016/j.ssnmr.2017.01.001_bib8) 2005; 54 Trebosc (10.1016/j.ssnmr.2017.01.001_bib18) 2007; 31 Davis (10.1016/j.ssnmr.2017.01.001_bib67) 2001; 95 Pruski (10.1016/j.ssnmr.2017.01.001_bib35) 1997; 7 Dupree (10.1016/j.ssnmr.2017.01.001_bib44) 1988 Gan (10.1016/j.ssnmr.2017.01.001_bib60) 2003; 367 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib36) 2000; 147 Larsen (10.1016/j.ssnmr.2017.01.001_bib34) 1999; 103 Llor (10.1016/j.ssnmr.2017.01.001_bib4) 1988; 152 O’Dell (10.1016/j.ssnmr.2017.01.001_bib69) 2011; 115 Samoson (10.1016/j.ssnmr.2017.01.001_bib5) 1988; 65 Brown (10.1016/j.ssnmr.2017.01.001_bib42) 1997; 124 Colaux (10.1016/j.ssnmr.2017.01.001_bib37) 2014; 118 Frydman (10.1016/j.ssnmr.2017.01.001_bib6) 1995; 117 Alemany (10.1016/j.ssnmr.2017.01.001_bib59) 1999; 14 Carr (10.1016/j.ssnmr.2017.01.001_bib32) 1954; 94 Massiot (10.1016/j.ssnmr.2017.01.001_bib58) 1999; 15 Brown (10.1016/j.ssnmr.2017.01.001_bib7) 1997; 128 10.1016/j.ssnmr.2017.01.001_bib41 Derighetti (10.1016/j.ssnmr.2017.01.001_bib65) 1978; 66 Amoureux (10.1016/j.ssnmr.2017.01.001_bib20) 2005; 172 Ashbrook (10.1016/j.ssnmr.2017.01.001_bib61) 2003; 162 Amoureux (10.1016/j.ssnmr.2017.01.001_bib13) 1998; 131 Rocha (10.1016/j.ssnmr.2017.01.001_bib9) 2005; 246 Madhu (10.1016/j.ssnmr.2017.01.001_bib22) 1999; 307 Pike (10.1016/j.ssnmr.2017.01.001_bib48) 2000; 16 |
| References_xml | – volume: 168 start-page: 346 year: 2004 end-page: 351 ident: bib19 article-title: Enhancing MQMAS sensitivity using signals from multiple coherence transfer pathways publication-title: J. Magn. Reson. – volume: 115 start-page: 747 year: 2011 end-page: 752 ident: bib69 article-title: Crystal structure based design of signal enhancement schemes for solid-state NMR of insensitive half-integer quadrupolar nuclei publication-title: J. Phys. Chem. A – volume: 10 start-page: 211 year: 1998 end-page: 223 ident: bib12 article-title: Triple, quintuple and higher order multiple quantum MAS NMR of quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. – volume: 31 start-page: 1 year: 2007 end-page: 9 ident: bib18 article-title: Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. – volume: 45 start-page: 53 year: 2004 end-page: 108 ident: bib15 article-title: High-resolution NMR of quadrupolar nuclei in solids: the satellite-transition magic angle spinning (STMAS) experiment publication-title: Prog. Nucl. Magn. Reson. Spectrosc. – volume: 15 start-page: 8727 year: 2013 end-page: 8738 ident: bib51 article-title: NMR crystallography of sodium diphosphates: combining dipolar, shielding, quadrupolar, diffraction, and computational information publication-title: CrystEngComm – volume: 66 start-page: 150 year: 1978 end-page: 152 ident: bib65 article-title: NMR of publication-title: Phys. Lett. A – volume: 81 start-page: 545 year: 1996 end-page: 549 ident: bib66 article-title: calculation of electric-field-gradient tensors of forsterite publication-title: Am. Mineral. – volume: 41 start-page: 679 year: 2003 end-page: 688 ident: bib38 article-title: Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei publication-title: Magn. Reson. Chem. – volume: 65 start-page: 1013 year: 1988 end-page: 1018 ident: bib5 article-title: High resolution solid-state NMR publication-title: Mol. Phys. – volume: 18 start-page: 3855 year: 2006 end-page: 3859 ident: bib54 article-title: Scandium coordination in solid oxides and stabilized zirconia: publication-title: Chem. Mater. – volume: 94 start-page: 630 year: 1954 end-page: 638 ident: bib32 article-title: Effects of diffusion on free precession in nuclear magnetic resonance experiments publication-title: Phys. Rev. – volume: 132 start-page: 8732 year: 2010 end-page: 8746 ident: bib56 article-title: The polar phase of NaNbO publication-title: J. Am. Chem. Soc. – volume: 172 start-page: 268 year: 2005 end-page: 278 ident: bib20 article-title: Increasing the sensitivity of 2D high-resolution NMR methods applied to quadrupolar nuclei publication-title: J. Magn. Reson. – volume: 103 start-page: 10825 year: 1999 end-page: 11083 ident: bib34 article-title: Effects of finite Rf pulses and sample spinning speed in multiple-quantum magic-angle spinning (MQ-MAS) and multiple-quantum quadrupolar carr-purcell-meiboom-gill magic-angle spinning (MQ-QCPMG-MAS) nuclear magnetic resonance of half-integer quadrupolar nuclei publication-title: J. Phys. Chem. A – volume: 79 start-page: 242 year: 2013 end-page: 332 ident: bib64 article-title: Solid-state NMR of high-pressure silicates in the Earth's mantle publication-title: Ann. Rep. NMR Spectrosc. – volume: 114 start-page: 4618 year: 2001 end-page: 4624 ident: bib29 article-title: Multiple quantum magic-angle spinning using rotary resonance excitation publication-title: J. Chem. Phys. – volume: 13 start-page: 7565 year: 2011 end-page: 7576 ident: bib55 article-title: Nb NMR and DFT investigation of the polymorphs of NaNbO publication-title: Phys. Chem. Chem. Phys. – volume: 128 start-page: 42 year: 1997 end-page: 61 ident: bib7 article-title: Two-dimensional multiple-quantum MAS NMR of quadrupolar nuclei: a comparison of methods publication-title: J. Magn. Reson. – volume: 54 start-page: 81 year: 2005 end-page: 153 ident: bib8 article-title: Multiple-quantum magic-angle spinning: high-resolution solid-state NMR of half-integer spin quadrupolar nuclei publication-title: Ann. Rep. NMR Spectrosc. – volume: 6 start-page: 73 year: 1996 end-page: 83 ident: bib39 article-title: Two-dimensional magic-angle spinning isotropic reconstruction sequences for quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. – volume: 124 start-page: 279 year: 1997 end-page: 285 ident: bib42 article-title: Two-dimensional multiple-quantum MAS NMR of quadrupolar nuclei. acquisition of the whole echo publication-title: J. Magn. Reson. – volume: 95 start-page: 1601 year: 2001 end-page: 1607 ident: bib67 article-title: Characterization of cation environments in polycrystalline forsterite by publication-title: Am. Mineral. – volume: 7 start-page: 327 year: 1997 end-page: 331 ident: bib35 article-title: Multiple-quantum magic-angle spinning NMR with cross-polarization: spectral editing of high-resolution spectra of quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson – volume: 147 start-page: 238 year: 2000 end-page: 249 ident: bib36 article-title: Multiple-quantum cross-polarization and two-dimensional MQMAS NMR of quadrupolar nuclei publication-title: J. Magn. Reson. – volume: 162 start-page: 402 year: 2003 end-page: 416 ident: bib61 article-title: SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset publication-title: J. Magn. Reson. – volume: 152 start-page: 248 year: 1988 end-page: 253 ident: bib4 article-title: Towards high-resolution NMR of more nuclei in solids – sample spinning with time-dependent spinner axis angle publication-title: J. Chem. Phys. Lett. – volume: 118 start-page: 6018 year: 2014 end-page: 6025 ident: bib37 article-title: Efficient amplitude-modulated pulses for triple-to single-quantum coherence conversion in MQMAS NMR publication-title: J. Phys. Chem. A – volume: 87 start-page: 2453 year: 1991 end-page: 2455 ident: bib63 article-title: Powder determination of publication-title: J. Chem. Soc. Faraday Trans. – volume: 112 start-page: 2377 year: 2000 end-page: 2391 ident: bib23 article-title: Fast radio-frequency amplitude modulation in multiple-quantum magic-angle-spinning nuclear magnetic resonance: theory and experiments publication-title: J. Chem. Phys. – reference: MATLAB Release 2011b, The MathWorks, Inc., Natick, Massachusetts, United States. – volume: 367 start-page: 163 year: 2003 end-page: 169 ident: bib60 article-title: Third-order effect in solid-state NMR of quadrupolar nuclei publication-title: Chem. Phys. Lett. – volume: 108 start-page: 13292 year: 2004 end-page: 13299 ident: bib62 article-title: Satellite-transition MAS NMR of low-γ nuclei at natural abundance: sensitivity, practical implementation, and application to publication-title: J. Phys. Chem. B – year: 2002 ident: bib1 article-title: Multinuclear Solid-State NMR of Inorganic Materials – volume: 29 start-page: 688 year: 1958 end-page: 691 ident: bib33 article-title: Modified spin-echo method for measuring nuclear relaxation times publication-title: Rev. Sci. Instrum. – volume: 15 start-page: 159 year: 1999 end-page: 169 ident: bib58 article-title: Ga NMR of reference Ga publication-title: Solid State Nucl. Magn. Reson. – volume: 147 start-page: 296 year: 2000 end-page: 330 ident: bib40 article-title: SIMPSON: a general simulation program for solid-state NMR spectroscopy publication-title: J. Magn. Reson. – volume: 124 start-page: 11602 year: 2002 end-page: 11603 ident: bib52 article-title: High-resolution NMR spectroscopy of quadrupolar nuclei in solids: satellite-transition MAS with self-compensation for magic-angle misset publication-title: J. Am. Chem. Soc. – volume: 14 start-page: 1 year: 1999 end-page: 18 ident: bib59 article-title: Very fast MAS and MQMAS NMR studies of the spectroscopically challenging minerals kyanite and andalusite on 400, 500, and 800 MHz spectrometers publication-title: Solid State Nucl. Magn. Reson. – volume: 102 start-page: 9750 year: 1998 end-page: 9760 ident: bib45 article-title: Distorted powder lineshapes in publication-title: J. Phys. Chem. A – volume: 300 start-page: 435 year: 1999 end-page: 443 ident: bib21 article-title: Advantages of double frequency sweeps in static, MAS and MQMAS NMR of Spin I=3/2 nuclei publication-title: Chem. Phys. Lett. – volume: 147 start-page: 286 year: 2000 end-page: 295 ident: bib26 article-title: On the conversion of triple- to single-quantum coherences in MQMAS NMR publication-title: J. Magn. Reson. – volume: 13 start-page: 293 year: 1984 end-page: 296 ident: bib43 article-title: Na chemical shifts of some inorganic and organic compounds in the solid state as determined by the magic angle spinning and high power NMR methods publication-title: Chem. Lett. – volume: 117 start-page: 5367 year: 1995 end-page: 5368 ident: bib6 article-title: Isotropic spectra of half-integer quadrupolar spins from bidimensional magic-angle-spinning NMR publication-title: J. Am. Chem. Soc. – volume: 320 start-page: 448 year: 2000 end-page: 456 ident: bib24 article-title: Enhanced conversion of triple to single-quantum coherence in the triple-quantum MAS NMR spectrosocopy of Spin-5/2 nuclei publication-title: Chem. Phys. Lett. – volume: 117 start-page: 2252 year: 2013 end-page: 2265 ident: bib46 article-title: Structural study of La publication-title: J. Phys. Chem. C – volume: 75 start-page: 1 year: 2016 end-page: 9 ident: bib30 article-title: A novel pulse scheme for multiple quantum excitation, SFAM to enhance the sensitivity of MQMAS experiments publication-title: Solid State Nucl. Magn. Reson. 74 – volume: 15 start-page: 171 year: 1999 end-page: 180 ident: bib50 article-title: Strategies for extracting NMR parameters from publication-title: Solid State Nucl. Magn. Reson. – volume: 307 start-page: 41 year: 1999 end-page: 47 ident: bib22 article-title: Sensitivity enhancement of the MQMAS NMR experiment by fast amplitude modulation of the pulses publication-title: Chem. Phys. Lett. – volume: 108 start-page: 9764 year: 2004 end-page: 9771 ident: bib53 article-title: Site populations and short range order in aluminosilicates investigated by publication-title: J. Phys. Chem. B – start-page: 1483 year: 1988 end-page: 1485 ident: bib44 article-title: Solid-state magnesium-25 NMR spectroscopy publication-title: J. Chem. Soc. Chem. Commun. – volume: 16 start-page: 203 year: 2000 end-page: 215 ident: bib48 article-title: Multiple-quantum MAS NMR of quadrupolar nuclei. Do five-, seven- and nine-quantum experiments yield higher resolution than the three-quantum experiment? publication-title: Solid State Nucl. Magn. Reson. – volume: 118 start-page: 9326 year: 1996 end-page: 9332 ident: bib28 article-title: Quantitative multiple-quantum magic-angle-spinning NMR spectroscopy of quadrupolar nuclei in solids publication-title: J. Am. Chem. Soc. – volume: 131 start-page: 194509 year: 2009 ident: bib49 article-title: Spin-locking of half-integer quadrupolar nuclei in nuclear magnetic resonance of solids: second-order quadrupolar and resonance offset effects publication-title: J. Chem. Phys. – year: 2014 ident: bib2 article-title: Solid-state NMR spectroscopy publication-title: Local Structural Characterisation – year: 2012 ident: bib3 publication-title: NMR of Quadrupolar Nuclei in Solid Materials – volume: 403 start-page: 353 year: 2005 end-page: 358 ident: bib25 article-title: Sensitivity enhancement of MQMAS NMR spectra of Spin 3/2 nuclei using hyperbolic secant pulses publication-title: Chem. Phys. Lett. – volume: 128 start-page: 8054 year: 2006 end-page: 8062 ident: bib17 article-title: Dynamics on the microsecond timescale in microporous aluminophosphate AlPO-14 as evidenced by publication-title: J. Am. Chem. Soc. – volume: 246 start-page: 141 year: 2005 end-page: 194 ident: bib9 article-title: Progress in multiple-quantum magic-angle spinning NMR spectroscopy publication-title: Top. Curr. Chem. – volume: 259 start-page: 347 year: 1996 end-page: 355 ident: bib11 article-title: Optimized multiple-quantum magic-angle spinning NMR experiments on half-integer quadrupoles publication-title: Chem. Phys. Lett. – volume: 187 start-page: 343 year: 2007 end-page: 351 ident: bib27 article-title: Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei publication-title: J. Magn. Reson. – volume: 116 start-page: 15048 year: 2012 end-page: 15057 ident: bib57 article-title: A multinuclear solid-state NMR study of templated and calcined chabazite-type GaPO-34 publication-title: J. Phys. Chem. C – year: 1962 ident: bib68 article-title: The Mathematical Theory of Optimal Processes – volume: 131 start-page: 170 year: 1998 end-page: 175 ident: bib13 article-title: The effect of RF power and spinning speed on MQMAS NMR publication-title: J. Magn. Reson. – volume: 125 start-page: 11824 year: 2003 end-page: 11825 ident: bib16 article-title: High-resolution publication-title: J. Am. Chem. Soc. – volume: 28 start-page: 204 year: 2005 end-page: 224 ident: bib47 article-title: Nb NMR chemical shift scale for Niobia systems publication-title: Solid State Nucl. Magn. Reson. – volume: 122 start-page: 3242 year: 2000 end-page: 3243 ident: bib14 article-title: Isotropic NMR spectra of half-integer quadrupolar nuclei using satellite transitions and magic-angle spinning publication-title: J. Am. Chem. Soc. – volume: 32 start-page: 99 year: 2007 end-page: 108 ident: bib10 article-title: Practical comparison of MQMAS techniques publication-title: Solid State Nucl. Magn. Reson. – volume: 127 start-page: 13768 year: 2005 end-page: 13769 ident: bib31 article-title: Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory publication-title: J. Am. Chem. Soc. – volume: 108 start-page: 13292 year: 2004 ident: 10.1016/j.ssnmr.2017.01.001_bib62 article-title: Satellite-transition MAS NMR of low-γ nuclei at natural abundance: sensitivity, practical implementation, and application to 39K (I=3/2) and 25Mg (I=5/2) publication-title: J. Phys. Chem. B doi: 10.1021/jp047868m – volume: 31 start-page: 1 year: 2007 ident: 10.1016/j.ssnmr.2017.01.001_bib18 article-title: Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/j.ssnmr.2006.09.002 – start-page: 1483 year: 1988 ident: 10.1016/j.ssnmr.2017.01.001_bib44 article-title: Solid-state magnesium-25 NMR spectroscopy publication-title: J. Chem. Soc. Chem. Commun. doi: 10.1039/c39880001483 – year: 2002 ident: 10.1016/j.ssnmr.2017.01.001_bib1 – volume: 118 start-page: 9326 year: 1996 ident: 10.1016/j.ssnmr.2017.01.001_bib28 article-title: Quantitative multiple-quantum magic-angle-spinning NMR spectroscopy of quadrupolar nuclei in solids publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9614676 – volume: 168 start-page: 346 year: 2004 ident: 10.1016/j.ssnmr.2017.01.001_bib19 article-title: Enhancing MQMAS sensitivity using signals from multiple coherence transfer pathways publication-title: J. Magn. Reson. doi: 10.1016/j.jmr.2004.03.021 – volume: 108 start-page: 9764 year: 2004 ident: 10.1016/j.ssnmr.2017.01.001_bib53 article-title: Site populations and short range order in aluminosilicates investigated by 27Al solid-state NMR publication-title: J. Phys. Chem. B doi: 10.1021/jp049603d – volume: 259 start-page: 347 year: 1996 ident: 10.1016/j.ssnmr.2017.01.001_bib11 article-title: Optimized multiple-quantum magic-angle spinning NMR experiments on half-integer quadrupoles publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(96)00809-3 – volume: 147 start-page: 238 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib36 article-title: Multiple-quantum cross-polarization and two-dimensional MQMAS NMR of quadrupolar nuclei publication-title: J. Magn. Reson. doi: 10.1006/jmre.2000.2174 – volume: 15 start-page: 159 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib58 article-title: 71Ga NMR of reference GaIV, GaV, and GaVI compounds by MAS and QPASS, extension of gallium/aluminum NMR parameter correlation publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/S0926-2040(99)00053-3 – volume: 15 start-page: 8727 year: 2013 ident: 10.1016/j.ssnmr.2017.01.001_bib51 article-title: NMR crystallography of sodium diphosphates: combining dipolar, shielding, quadrupolar, diffraction, and computational information publication-title: CrystEngComm doi: 10.1039/c3ce40875b – volume: 13 start-page: 7565 year: 2011 ident: 10.1016/j.ssnmr.2017.01.001_bib55 article-title: 93Nb NMR and DFT investigation of the polymorphs of NaNbO3 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/c1cp20258h – volume: 300 start-page: 435 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib21 article-title: Advantages of double frequency sweeps in static, MAS and MQMAS NMR of Spin I=3/2 nuclei publication-title: Chem. Phys. Lett. doi: 10.1016/S0009-2614(98)01402-X – volume: 65 start-page: 1013 year: 1988 ident: 10.1016/j.ssnmr.2017.01.001_bib5 article-title: High resolution solid-state NMR publication-title: Mol. Phys. doi: 10.1080/00268978800101571 – volume: 122 start-page: 3242 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib14 article-title: Isotropic NMR spectra of half-integer quadrupolar nuclei using satellite transitions and magic-angle spinning publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9939791 – year: 2014 ident: 10.1016/j.ssnmr.2017.01.001_bib2 article-title: Solid-state NMR spectroscopy – volume: 187 start-page: 343 year: 2007 ident: 10.1016/j.ssnmr.2017.01.001_bib27 article-title: Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei publication-title: J. Magn. Reson. doi: 10.1016/j.jmr.2007.05.020 – volume: 54 start-page: 81 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib8 article-title: Multiple-quantum magic-angle spinning: high-resolution solid-state NMR of half-integer spin quadrupolar nuclei publication-title: Ann. Rep. NMR Spectrosc. doi: 10.1016/S0066-4103(04)54003-6 – volume: 125 start-page: 11824 year: 2003 ident: 10.1016/j.ssnmr.2017.01.001_bib16 article-title: High-resolution 17O NMR spectroscopy of Wadsleyite (β-Mg2SiO4) publication-title: J. Am. Chem. Soc. doi: 10.1021/ja036777k – volume: 66 start-page: 150 year: 1978 ident: 10.1016/j.ssnmr.2017.01.001_bib65 article-title: NMR of 29Si and 25Mg in Mg2SiO4 with dynamic polarization technique publication-title: Phys. Lett. A doi: 10.1016/0375-9601(78)90023-3 – volume: 246 start-page: 141 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib9 article-title: Progress in multiple-quantum magic-angle spinning NMR spectroscopy publication-title: Top. Curr. Chem. doi: 10.1007/b98650 – volume: 128 start-page: 8054 year: 2006 ident: 10.1016/j.ssnmr.2017.01.001_bib17 article-title: Dynamics on the microsecond timescale in microporous aluminophosphate AlPO-14 as evidenced by 27Al MQMAS and STMAS NMR spectroscopy publication-title: J. Am. Chem. Soc. doi: 10.1021/ja057682g – volume: 32 start-page: 99 year: 2007 ident: 10.1016/j.ssnmr.2017.01.001_bib10 article-title: Practical comparison of MQMAS techniques publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/j.ssnmr.2007.09.003 – volume: 131 start-page: 170 year: 1998 ident: 10.1016/j.ssnmr.2017.01.001_bib13 article-title: The effect of RF power and spinning speed on MQMAS NMR publication-title: J. Magn. Reson. doi: 10.1006/jmre.1997.1275 – volume: 94 start-page: 630 year: 1954 ident: 10.1016/j.ssnmr.2017.01.001_bib32 article-title: Effects of diffusion on free precession in nuclear magnetic resonance experiments publication-title: Phys. Rev. doi: 10.1103/PhysRev.94.630 – volume: 147 start-page: 286 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib26 article-title: On the conversion of triple- to single-quantum coherences in MQMAS NMR publication-title: J. Magn. Reson. doi: 10.1006/jmre.2000.2190 – volume: 87 start-page: 2453 year: 1991 ident: 10.1016/j.ssnmr.2017.01.001_bib63 article-title: Powder determination of 39K nuclear quadrupole coupling publication-title: J. Chem. Soc. Faraday Trans. doi: 10.1039/ft9918702453 – volume: 117 start-page: 5367 year: 1995 ident: 10.1016/j.ssnmr.2017.01.001_bib6 article-title: Isotropic spectra of half-integer quadrupolar spins from bidimensional magic-angle-spinning NMR publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00124a023 – volume: 152 start-page: 248 year: 1988 ident: 10.1016/j.ssnmr.2017.01.001_bib4 article-title: Towards high-resolution NMR of more nuclei in solids – sample spinning with time-dependent spinner axis angle publication-title: J. Chem. Phys. Lett. doi: 10.1016/0009-2614(88)87362-7 – volume: 29 start-page: 688 year: 1958 ident: 10.1016/j.ssnmr.2017.01.001_bib33 article-title: Modified spin-echo method for measuring nuclear relaxation times publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1716296 – volume: 103 start-page: 10825 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib34 publication-title: J. Phys. Chem. A doi: 10.1021/jp992798i – volume: 115 start-page: 747 year: 2011 ident: 10.1016/j.ssnmr.2017.01.001_bib69 article-title: Crystal structure based design of signal enhancement schemes for solid-state NMR of insensitive half-integer quadrupolar nuclei publication-title: J. Phys. Chem. A doi: 10.1021/jp111531e – year: 2012 ident: 10.1016/j.ssnmr.2017.01.001_bib3 – volume: 118 start-page: 6018 year: 2014 ident: 10.1016/j.ssnmr.2017.01.001_bib37 article-title: Efficient amplitude-modulated pulses for triple-to single-quantum coherence conversion in MQMAS NMR publication-title: J. Phys. Chem. A doi: 10.1021/jp505752c – volume: 112 start-page: 2377 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib23 article-title: Fast radio-frequency amplitude modulation in multiple-quantum magic-angle-spinning nuclear magnetic resonance: theory and experiments publication-title: J. Chem. Phys. doi: 10.1063/1.480804 – volume: 95 start-page: 1601 year: 2001 ident: 10.1016/j.ssnmr.2017.01.001_bib67 article-title: Characterization of cation environments in polycrystalline forsterite by 25Mg MAS, MQMAS, and QCPMG NMR publication-title: Am. Mineral. doi: 10.2138/am.2010.3403 – volume: 10 start-page: 211 year: 1998 ident: 10.1016/j.ssnmr.2017.01.001_bib12 article-title: Triple, quintuple and higher order multiple quantum MAS NMR of quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/S0926-2040(97)00027-1 – volume: 124 start-page: 279 year: 1997 ident: 10.1016/j.ssnmr.2017.01.001_bib42 article-title: Two-dimensional multiple-quantum MAS NMR of quadrupolar nuclei. acquisition of the whole echo publication-title: J. Magn. Reson. doi: 10.1006/jmre.1996.1059 – volume: 28 start-page: 204 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib47 article-title: 93Nb NMR chemical shift scale for Niobia systems publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/j.ssnmr.2005.09.003 – volume: 124 start-page: 11602 year: 2002 ident: 10.1016/j.ssnmr.2017.01.001_bib52 article-title: High-resolution NMR spectroscopy of quadrupolar nuclei in solids: satellite-transition MAS with self-compensation for magic-angle misset publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0203869 – volume: 131 start-page: 194509 year: 2009 ident: 10.1016/j.ssnmr.2017.01.001_bib49 article-title: Spin-locking of half-integer quadrupolar nuclei in nuclear magnetic resonance of solids: second-order quadrupolar and resonance offset effects publication-title: J. Chem. Phys. doi: 10.1063/1.3263904 – year: 1962 ident: 10.1016/j.ssnmr.2017.01.001_bib68 – volume: 16 start-page: 203 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib48 article-title: Multiple-quantum MAS NMR of quadrupolar nuclei. Do five-, seven- and nine-quantum experiments yield higher resolution than the three-quantum experiment? publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/S0926-2040(00)00081-3 – volume: 403 start-page: 353 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib25 article-title: Sensitivity enhancement of MQMAS NMR spectra of Spin 3/2 nuclei using hyperbolic secant pulses publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2005.01.023 – volume: 147 start-page: 296 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib40 article-title: SIMPSON: a general simulation program for solid-state NMR spectroscopy publication-title: J. Magn. Reson. doi: 10.1006/jmre.2000.2179 – volume: 18 start-page: 3855 year: 2006 ident: 10.1016/j.ssnmr.2017.01.001_bib54 article-title: Scandium coordination in solid oxides and stabilized zirconia: 45Sc NMR publication-title: Chem. Mater. doi: 10.1021/cm060590l – volume: 81 start-page: 545 year: 1996 ident: 10.1016/j.ssnmr.2017.01.001_bib66 article-title: Ab Initio calculation of electric-field-gradient tensors of forsterite publication-title: Am. Mineral. doi: 10.2138/am-1996-5-602 – volume: 128 start-page: 42 year: 1997 ident: 10.1016/j.ssnmr.2017.01.001_bib7 article-title: Two-dimensional multiple-quantum MAS NMR of quadrupolar nuclei: a comparison of methods publication-title: J. Magn. Reson. doi: 10.1006/jmre.1997.1217 – volume: 41 start-page: 679 year: 2003 ident: 10.1016/j.ssnmr.2017.01.001_bib38 article-title: Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei publication-title: Magn. Reson. Chem. doi: 10.1002/mrc.1238 – volume: 6 start-page: 73 year: 1996 ident: 10.1016/j.ssnmr.2017.01.001_bib39 article-title: Two-dimensional magic-angle spinning isotropic reconstruction sequences for quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/0926-2040(95)01210-9 – volume: 367 start-page: 163 year: 2003 ident: 10.1016/j.ssnmr.2017.01.001_bib60 article-title: Third-order effect in solid-state NMR of quadrupolar nuclei publication-title: Chem. Phys. Lett. doi: 10.1016/S0009-2614(02)01681-0 – volume: 127 start-page: 13768 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib31 article-title: Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory publication-title: J. Am. Chem. Soc. doi: 10.1021/ja054035g – volume: 172 start-page: 268 year: 2005 ident: 10.1016/j.ssnmr.2017.01.001_bib20 article-title: Increasing the sensitivity of 2D high-resolution NMR methods applied to quadrupolar nuclei publication-title: J. Magn. Reson. doi: 10.1016/j.jmr.2004.11.001 – volume: 15 start-page: 171 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib50 article-title: Strategies for extracting NMR parameters from 23Na MAS, DOR and MQMAS spectra. A case study for Na4P2O7 publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/S0926-2040(99)00054-5 – volume: 79 start-page: 242 year: 2013 ident: 10.1016/j.ssnmr.2017.01.001_bib64 article-title: Solid-state NMR of high-pressure silicates in the Earth's mantle publication-title: Ann. Rep. NMR Spectrosc. – volume: 162 start-page: 402 year: 2003 ident: 10.1016/j.ssnmr.2017.01.001_bib61 article-title: SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset publication-title: J. Magn. Reson. doi: 10.1016/S1090-7807(03)00016-8 – volume: 13 start-page: 293 year: 1984 ident: 10.1016/j.ssnmr.2017.01.001_bib43 article-title: 23Na chemical shifts of some inorganic and organic compounds in the solid state as determined by the magic angle spinning and high power NMR methods publication-title: Chem. Lett. doi: 10.1246/cl.1984.293 – volume: 307 start-page: 41 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib22 article-title: Sensitivity enhancement of the MQMAS NMR experiment by fast amplitude modulation of the pulses publication-title: Chem. Phys. Lett. doi: 10.1016/S0009-2614(99)00446-7 – volume: 45 start-page: 53 year: 2004 ident: 10.1016/j.ssnmr.2017.01.001_bib15 article-title: High-resolution NMR of quadrupolar nuclei in solids: the satellite-transition magic angle spinning (STMAS) experiment publication-title: Prog. Nucl. Magn. Reson. Spectrosc. doi: 10.1016/j.pnmrs.2004.04.002 – ident: 10.1016/j.ssnmr.2017.01.001_bib41 – volume: 114 start-page: 4618 year: 2001 ident: 10.1016/j.ssnmr.2017.01.001_bib29 article-title: Multiple quantum magic-angle spinning using rotary resonance excitation publication-title: J. Chem. Phys. doi: 10.1063/1.1333407 – volume: 116 start-page: 15048 year: 2012 ident: 10.1016/j.ssnmr.2017.01.001_bib57 article-title: A multinuclear solid-state NMR study of templated and calcined chabazite-type GaPO-34 publication-title: J. Phys. Chem. C doi: 10.1021/jp304868w – volume: 102 start-page: 9750 year: 1998 ident: 10.1016/j.ssnmr.2017.01.001_bib45 article-title: Distorted powder lineshapes in 27Al CP MAS NMR spectroscopy of solids publication-title: J. Phys. Chem. A – volume: 132 start-page: 8732 year: 2010 ident: 10.1016/j.ssnmr.2017.01.001_bib56 article-title: The polar phase of NaNbO3: a combined study by powder diffraction, solid-state NMR, and first-principles calculation publication-title: J. Am. Chem. Soc. doi: 10.1021/ja101860r – volume: 75 start-page: 1 year: 2016 ident: 10.1016/j.ssnmr.2017.01.001_bib30 article-title: A novel pulse scheme for multiple quantum excitation, SFAM to enhance the sensitivity of MQMAS experiments publication-title: Solid State Nucl. Magn. Reson. 74 – volume: 117 start-page: 2252 year: 2013 ident: 10.1016/j.ssnmr.2017.01.001_bib46 article-title: Structural study of La1–xYxScO3, combining neutron diffraction, solid-state NMR, and first-principles DFT calculations publication-title: J. Phys. Chem. C doi: 10.1021/jp310878b – volume: 320 start-page: 448 year: 2000 ident: 10.1016/j.ssnmr.2017.01.001_bib24 article-title: Enhanced conversion of triple to single-quantum coherence in the triple-quantum MAS NMR spectrosocopy of Spin-5/2 nuclei publication-title: Chem. Phys. Lett. doi: 10.1016/S0009-2614(00)00298-0 – volume: 7 start-page: 327 year: 1997 ident: 10.1016/j.ssnmr.2017.01.001_bib35 article-title: Multiple-quantum magic-angle spinning NMR with cross-polarization: spectral editing of high-resolution spectra of quadrupolar nuclei publication-title: Solid State Nucl. Magn. Reson doi: 10.1016/S0926-2040(96)01284-2 – volume: 14 start-page: 1 year: 1999 ident: 10.1016/j.ssnmr.2017.01.001_bib59 article-title: Very fast MAS and MQMAS NMR studies of the spectroscopically challenging minerals kyanite and andalusite on 400, 500, and 800 MHz spectrometers publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/S0926-2040(99)00011-9 |
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| SubjectTerms | Challenging systems FAM-N pulses Fast-amplitude modulation MQMAS Quadrupolar nuclei Solid-state MAS NMR spectroscopy |
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| Title | Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei |
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