LiOH-embedded zeolite for carbon dioxide capture under ambient conditions
•Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions. In the present work,...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 22; pp. 350 - 356 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.02.2015
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1226-086X 1876-794X |
| DOI | 10.1016/j.jiec.2014.07.030 |
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| Abstract | •Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions.
In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) to remove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents was much smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. The requirement of optimum moisture content for maximum CO2 adsorption was established by correlating the relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even in presence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoor environments at ambient conditions. |
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| AbstractList | In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) toremove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents wasmuch smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. Therequirement of optimummoisture content for maximum CO2 adsorption was established by correlatingthe relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even inpresence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoorenvironments at ambient conditions. KCI Citation Count: 22 •Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions. In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) to remove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents was much smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. The requirement of optimum moisture content for maximum CO2 adsorption was established by correlating the relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even in presence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoor environments at ambient conditions. |
| Author | Choi, Jin-Sik Jung, Woo-Sung Choi, Wonyong Cho, Youngmin Park, Duck-Shin Yang, Young-Min Lee, Ji-Yun Lee, Ju-Yeol Kwon, Soon-Bark Bokare, Alok D. |
| Author_xml | – sequence: 1 givenname: Youngmin surname: Cho fullname: Cho, Youngmin email: ymcho@krri.re.kr organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 2 givenname: Ji-Yun surname: Lee fullname: Lee, Ji-Yun organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 3 givenname: Alok D. surname: Bokare fullname: Bokare, Alok D. organization: School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Republic of Korea – sequence: 4 givenname: Soon-Bark surname: Kwon fullname: Kwon, Soon-Bark organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 5 givenname: Duck-Shin surname: Park fullname: Park, Duck-Shin organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 6 givenname: Woo-Sung surname: Jung fullname: Jung, Woo-Sung organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 7 givenname: Jin-Sik surname: Choi fullname: Choi, Jin-Sik organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 8 givenname: Young-Min surname: Yang fullname: Yang, Young-Min organization: Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea – sequence: 9 givenname: Ju-Yeol surname: Lee fullname: Lee, Ju-Yeol organization: Technical Institute, Anytech Inc., Suwon, Republic of Korea – sequence: 10 givenname: Wonyong surname: Choi fullname: Choi, Wonyong organization: School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Republic of Korea |
| BackLink | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART001996753$$DAccess content in National Research Foundation of Korea (NRF) |
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| Snippet | •Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+... In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) toremove CO2 under simulated indoor conditions. Although the... |
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| SubjectTerms | CO2 adsorption Lithium hydroxide Relative humidity Zeolite 13X Zeolite 5A 화학공학 |
| Title | LiOH-embedded zeolite for carbon dioxide capture under ambient conditions |
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