LiOH-embedded zeolite for carbon dioxide capture under ambient conditions

•Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions. In the present work,...

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Published inJournal of industrial and engineering chemistry (Seoul, Korea) Vol. 22; pp. 350 - 356
Main Authors Cho, Youngmin, Lee, Ji-Yun, Bokare, Alok D., Kwon, Soon-Bark, Park, Duck-Shin, Jung, Woo-Sung, Choi, Jin-Sik, Yang, Young-Min, Lee, Ju-Yeol, Choi, Wonyong
Format Journal Article
LanguageEnglish
Published Elsevier B.V 25.02.2015
한국공업화학회
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Online AccessGet full text
ISSN1226-086X
1876-794X
DOI10.1016/j.jiec.2014.07.030

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Abstract •Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions. In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) to remove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents was much smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. The requirement of optimum moisture content for maximum CO2 adsorption was established by correlating the relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even in presence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoor environments at ambient conditions.
AbstractList In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) toremove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents wasmuch smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. Therequirement of optimummoisture content for maximum CO2 adsorption was established by correlatingthe relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even inpresence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoorenvironments at ambient conditions. KCI Citation Count: 22
•Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+ and CO2 is the reason of strong CO2 adsorption.•Efficient adsorption was achieved even in humid atmospheric conditions. In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) to remove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents was much smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. The requirement of optimum moisture content for maximum CO2 adsorption was established by correlating the relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even in presence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoor environments at ambient conditions.
Author Choi, Jin-Sik
Jung, Woo-Sung
Choi, Wonyong
Cho, Youngmin
Park, Duck-Shin
Yang, Young-Min
Lee, Ji-Yun
Lee, Ju-Yeol
Kwon, Soon-Bark
Bokare, Alok D.
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Keywords Relative humidity
Zeolite 5A
Lithium hydroxide
Zeolite 13X
CO2 adsorption
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한국공업화학회
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Snippet •Ambient CO2 capturing was achieved using LiOH-embedded zeolites.•LiOH-zeolite composite adsorbed more CO2 than unmodified zeolites.•Chemical bond between Li+...
In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) toremove CO2 under simulated indoor conditions. Although the...
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SubjectTerms CO2 adsorption
Lithium hydroxide
Relative humidity
Zeolite 13X
Zeolite 5A
화학공학
Title LiOH-embedded zeolite for carbon dioxide capture under ambient conditions
URI https://dx.doi.org/10.1016/j.jiec.2014.07.030
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