Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane
Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of me...
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Published in | Chinese journal of chemical engineering Vol. 21; no. 8; pp. 827 - 834 |
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Main Author | |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.08.2013
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Online Access | Get full text |
ISSN | 1004-9541 2210-321X |
DOI | 10.1016/S1004-9541(13)60547-9 |
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Abstract | Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and ef- fective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency. |
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AbstractList | Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and effective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency. Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and ef- fective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency. |
Author | 郑辉东 陈晶晶 王碧玉 赵素英 |
AuthorAffiliation | College of Chemistry and Chemical Engineering, Fuzhou University |
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Cites_doi | 10.1016/S0021-9797(03)00480-6 10.1016/S1006-1266(08)60040-1 10.1016/j.memsci.2007.02.010 10.1016/j.ultsonch.2009.09.001 10.1016/S0043-1354(03)00072-1 10.1016/S0376-7388(98)00321-4 10.1002/aic.690391115 10.1016/S0958-2118(01)80411-0 10.1016/S0376-7388(98)00351-2 10.1016/j.colsurfa.2009.09.028 10.1016/0376-7388(95)00174-3 10.1016/j.memsci.2010.01.021 10.1016/j.cej.2009.12.032 10.1002/aic.690440308 10.1016/j.memsci.2007.03.036 |
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Notes | copper ion, supported emulsion liquid membrane, extraction rate, hollow fiber College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China 11-3270/TQ Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and ef- fective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 ObjectType-Article-1 ObjectType-Feature-2 |
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Snippet | Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as... Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as... |
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SubjectTerms | copper ion Emulsions Extraction extraction rate Fibers Flow rate hollow fiber Liquid phases LIX984N Stripping supported emulsion liquid membrane Surfactants Waste water 中空纤维 乳状液膜 废水回收 硫酸溶液 表面活性剂 载流子浓度 铜离子 |
Title | Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane |
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