Extraction of rubidium by t-BAMBP in cyclohexane
4-Tert-butyl-2-（α-methylbenzyl） phenol （t-BAMBP） was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied, t-BAMBP/cyclohexane was efficient and...
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| Published in | Chinese journal of chemical engineering Vol. 23; no. 7; pp. 1110 - 1113 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.07.2015
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1004-9541 2210-321X |
| DOI | 10.1016/j.cjche.2015.04.005 |
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| Abstract | 4-Tert-butyl-2-（α-methylbenzyl） phenol （t-BAMBP） was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied, t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol.L-1. The stoichiometry of the complex of α-BAMBP with rubidium is 4：1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data. |
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| AbstractList | 4-Tert-butyl-2-（α-methylbenzyl） phenol （t-BAMBP） was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied, t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol.L-1. The stoichiometry of the complex of α-BAMBP with rubidium is 4：1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data. 4-Tert-butyl-2-(α-methylbenzyl) phenol (t-BAMBP) was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied. t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0mol·L−1. The stoichiometry of the complex of t-BAMBP with rubidium is 4:1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data. |
| Author | Jiawei wang Dehua Che Wei Qin |
| AuthorAffiliation | State Key Laboratory of Chemical Engineering, Department of Chemical Engineering Tsinghua University, Beijing 100084, China |
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| Cites_doi | 10.1021/ac60239a051 10.1021/ja00822a007 10.1016/0022-1902(73)80416-6 10.1016/0039-9140(71)80028-0 10.1021/ic50029a030 10.13182/NSE63-A28885 10.1021/ac60216a035 10.1021/i260015a002 |
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| Keywords | Selectivity Solvent extraction Rubidium t-BAMBP Cyclohexane |
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| Notes | Solvent extractionSelectivityRubidiumc-BAMBPCydohexane 11-3270/TQ 4-Tert-butyl-2-（α-methylbenzyl） phenol （t-BAMBP） was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied, t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol.L-1. The stoichiometry of the complex of α-BAMBP with rubidium is 4：1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data. |
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| Snippet | 4-Tert-butyl-2-（α-methylbenzyl） phenol （t-BAMBP） was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of... 4-Tert-butyl-2-(α-methylbenzyl) phenol (t-BAMBP) was used in cyclohexane in the extraction of rubidium from brine sources containing lithium. The effect of... |
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| SubjectTerms | bambp Cyclohexane Rubidium Selectivity Solvent extraction t-BAMBP 初始浓度 提取 最佳操作条件 环己烷 甲基苄基 表观萃取平衡常数 铷 |
| Title | Extraction of rubidium by t-BAMBP in cyclohexane |
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