Hierarchical Tubular Structures Composed of Mn-Based Mixed Metal Oxide Nanoflakes with Enhanced Electrochemical Properties
In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn‐based (Co‐Mn, Ni‐Mn, Cu‐Mn, Zn‐Mn) mixed metal oxides. The first step in the synthesis involves redox reaction mediated growth of nanoflakes on carbon nanofibers under hydrothermal conditions. Afte...
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| Published in | Advanced functional materials Vol. 25; no. 32; pp. 5184 - 5189 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Blackwell Publishing Ltd
01.08.2015
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1616-301X 1616-3028 |
| DOI | 10.1002/adfm.201501974 |
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| Abstract | In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn‐based (Co‐Mn, Ni‐Mn, Cu‐Mn, Zn‐Mn) mixed metal oxides. The first step in the synthesis involves redox reaction mediated growth of nanoflakes on carbon nanofibers under hydrothermal conditions. After calcination in air, carbon nanofibers are removed and HTS of mixed metal oxides can be obtained with little structural deterioration. The resultant HTS are advantageous as electrodes for electrochemical energy storage. As an example, it is shown that the Co‐Mn‐HTS sample exhibits outstanding electrochemical performance as electrode materials for hybrid supercapacitors and lithium ion batteries.
A general strategy is developed for the synthesis of hierarchical tubular structures of Mn‐based mixed metal oxides. The derived Co‐Mn mixed oxide hierarchical tubular structures manifest enhanced electrochemical properties as electrodes for both hybrid supercapacitors and lithium ion batteries. |
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| AbstractList | In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn‐based (Co‐Mn, Ni‐Mn, Cu‐Mn, Zn‐Mn) mixed metal oxides. The first step in the synthesis involves redox reaction mediated growth of nanoflakes on carbon nanofibers under hydrothermal conditions. After calcination in air, carbon nanofibers are removed and HTS of mixed metal oxides can be obtained with little structural deterioration. The resultant HTS are advantageous as electrodes for electrochemical energy storage. As an example, it is shown that the Co‐Mn‐HTS sample exhibits outstanding electrochemical performance as electrode materials for hybrid supercapacitors and lithium ion batteries.
A general strategy is developed for the synthesis of hierarchical tubular structures of Mn‐based mixed metal oxides. The derived Co‐Mn mixed oxide hierarchical tubular structures manifest enhanced electrochemical properties as electrodes for both hybrid supercapacitors and lithium ion batteries. In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn-based (Co-Mn, Ni-Mn, Cu-Mn, Zn-Mn) mixed metal oxides. The first step in the synthesis involves redox reaction mediated growth of nanoflakes on carbon nanofibers under hydrothermal conditions. After calcination in air, carbon nanofibers are removed and HTS of mixed metal oxides can be obtained with little structural deterioration. The resultant HTS are advantageous as electrodes for electrochemical energy storage. As an example, it is shown that the Co-Mn-HTS sample exhibits outstanding electrochemical performance as electrode materials for hybrid supercapacitors and lithium ion batteries. A general strategy is developed for the synthesis of hierarchical tubular structures of Mn-based mixed metal oxides. The derived Co-Mn mixed oxide hierarchical tubular structures manifest enhanced electrochemical properties as electrodes for both hybrid supercapacitors and lithium ion batteries. In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn‐based (Co‐Mn, Ni‐Mn, Cu‐Mn, Zn‐Mn) mixed metal oxides. The first step in the synthesis involves redox reaction mediated growth of nanoflakes on carbon nanofibers under hydrothermal conditions. After calcination in air, carbon nanofibers are removed and HTS of mixed metal oxides can be obtained with little structural deterioration. The resultant HTS are advantageous as electrodes for electrochemical energy storage. As an example, it is shown that the Co‐Mn‐HTS sample exhibits outstanding electrochemical performance as electrode materials for hybrid supercapacitors and lithium ion batteries. |
| Author | Lou, Xiong Wen (David) Guo, Yan Lin, Zhan Wang, Cheng-Yang Yu, Le |
| Author_xml | – sequence: 1 givenname: Yan surname: Guo fullname: Guo, Yan organization: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, 637459, Singapore, Singapore – sequence: 2 givenname: Le surname: Yu fullname: Yu, Le organization: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, 637459, Singapore, Singapore – sequence: 3 givenname: Cheng-Yang surname: Wang fullname: Wang, Cheng-Yang organization: Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, 300072, Tianjin, P. R. China – sequence: 4 givenname: Zhan surname: Lin fullname: Lin, Zhan email: xwlou@ntu.edu.sg organization: Institute of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Zhejiang, 310027, Hangzhou, P. R. China – sequence: 5 givenname: Xiong Wen (David) surname: Lou fullname: Lou, Xiong Wen (David) email: xwlou@ntu.edu.sg organization: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, 637459, Singapore, Singapore |
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| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Snippet | In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn‐based (Co‐Mn, Ni‐Mn, Cu‐Mn, Zn‐Mn) mixed metal oxides.... In this work, a simple strategy is developed to synthesize hierarchical tubular structures (HTS) of Mn-based (Co-Mn, Ni-Mn, Cu-Mn, Zn-Mn) mixed metal oxides.... |
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| SubjectTerms | Carbon fibers Electrochemical analysis Electrodes hierarchical tubular structures hybrid supercapacitors Lithium batteries lithium ion batteries Manganese Metal oxides mixed metal oxides Nanostructure Strategy |
| Title | Hierarchical Tubular Structures Composed of Mn-Based Mixed Metal Oxide Nanoflakes with Enhanced Electrochemical Properties |
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