Design of Hybrid Fuels Using a Modeling Study of the Miscibility of Ethanol–Biodiesel–Hydrocarbon Systems

Recently, the concept of diesel–ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability limitations entailed by the contrasted physicochemical properties of hydrated ethanol and diesel oil. Biodiesel is often used as a third solvent since...

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Published inInternational journal of thermophysics Vol. 37; no. 2; pp. 1 - 19
Main Authors Pina-Martinez, Andrés, Juntarachat, Niramol, Privat, Romain, Coniglio, Lucie, Molière, Michel, Jaubert, Jean-Noël
Format Journal Article
LanguageEnglish
Published New York Springer US 01.02.2016
Springer Verlag
Subjects
Online AccessGet full text
ISSN0195-928X
1572-9567
DOI10.1007/s10765-015-2032-y

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Abstract Recently, the concept of diesel–ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability limitations entailed by the contrasted physicochemical properties of hydrated ethanol and diesel oil. Biodiesel is often used as a third solvent since it behaves successfully as a surface-active agent to stabilize ethanol/diesel fuel blends. In this paper, a flash algorithm, employing the UNIFAC-Dortmund g E -model for calculating the activity coefficients, has been used to evaluate the Minimal Miscibility Temperature (MMT) of alcohol–biodiesel–hydrocarbon systems. The simulation work was focused on the influence of various parameters such as the paraffinic/aromatic/naphthenic character of the hydrocarbon fraction, the hydration level of the alcohol, the size of the alcohol molecule, and the composition of the added biodiesel. The results show that biodiesel enhances ethanol/hydrocarbon miscibility whichever the nature of the fossil fractions. They also highlight the importance of the aromatic content of the fuel in the miscibility of the alcohol/hydrocarbon blends. The chain moiety of the alcohol as well as its hydration degree were found relevant for the fuel blends stability. Conversely, while increasing biodiesel concentration leads to significant decreases of the MMT, the influence of the biodiesel chemical structure remains practically insignificant.
AbstractList Recently, the concept of diesel-ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability limitations entailed by the contrasted physicochemical properties of hydrated ethanol and diesel oil. Biodiesel is often used as a third solvent since it behaves successfully as a surface-active agent to stabilize ethanol/diesel fuel blends. In this paper, a flash algorithm, employing the UNIFAC-Dortmund \({\text {g}}\mathrm{E}}\)-model for calculating the activity coefficients, has been used to evaluate the Minimal Miscibility Temperature (MMT) of alcohol-biodiesel-hydrocarbon systems. The simulation work was focused on the influence of various parameters such as the paraffinic/aromatic/naphthenic character of the hydrocarbon fraction, the hydration level of the alcohol, the size of the alcohol molecule, and the composition of the added biodiesel. The results show that biodiesel enhances ethanol/hydrocarbon miscibility whichever the nature of the fossil fractions. They also highlight the importance of the aromatic content of the fuel in the miscibility of the alcohol/hydrocarbon blends. The chain moiety of the alcohol as well as its hydration degree were found relevant for the fuel blends stability. Conversely, while increasing biodiesel concentration leads to significant decreases of the MMT, the influence of the biodiesel chemical structure remains practically insignificant.
Recently, the concept of diesel–ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability limitations entailed by the contrasted physicochemical properties of hydrated ethanol and diesel oil. Biodiesel is often used as a third solvent since it behaves successfully as a surface-active agent to stabilize ethanol/diesel fuel blends. In this paper, a flash algorithm, employing the UNIFAC-Dortmund g E -model for calculating the activity coefficients, has been used to evaluate the Minimal Miscibility Temperature (MMT) of alcohol–biodiesel–hydrocarbon systems. The simulation work was focused on the influence of various parameters such as the paraffinic/aromatic/naphthenic character of the hydrocarbon fraction, the hydration level of the alcohol, the size of the alcohol molecule, and the composition of the added biodiesel. The results show that biodiesel enhances ethanol/hydrocarbon miscibility whichever the nature of the fossil fractions. They also highlight the importance of the aromatic content of the fuel in the miscibility of the alcohol/hydrocarbon blends. The chain moiety of the alcohol as well as its hydration degree were found relevant for the fuel blends stability. Conversely, while increasing biodiesel concentration leads to significant decreases of the MMT, the influence of the biodiesel chemical structure remains practically insignificant.
ArticleNumber 23
Author Privat, Romain
Molière, Michel
Juntarachat, Niramol
Pina-Martinez, Andrés
Jaubert, Jean-Noël
Coniglio, Lucie
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  surname: Pina-Martinez
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  givenname: Niramol
  surname: Juntarachat
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  givenname: Romain
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– sequence: 4
  givenname: Lucie
  surname: Coniglio
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  givenname: Jean-Noël
  surname: Jaubert
  fullname: Jaubert, Jean-Noël
  email: jean-noel.jaubert@univ-lorraine.fr
  organization: Université de Lorraine, École Nationale Supérieure des Industries Chimiques, Laboratoire Réactions et Génie des Procédés - UMR CNRS 7274
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IsPeerReviewed true
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Issue 2
Keywords Ethanol
Miscibility
Alcohol
Biofuel
Liquid–liquid equilibria
Diesel oil
Fuel oil
Language English
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– reference: JaubertJNConiglioLInd. Eng. Chem. Res.199938501110.1021/ie990544d
– reference: FernandoSHannaMEnergy Fuels200418169510.1021/ef049865e
– reference: GmehlingJLiJSchillerMInd. Eng. Chem. Res.19933217810.1021/ie00013a024
– reference: PolingBEPrausnitzJMO’ConnellJPThe Properties of Gases and Liquids20005New YorkMc Graw Hill335359
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– reference: Nani GuarieiroLLde SouzaAFTorresEAde AndradeJBAtmos. Environ.200943275410.1016/j.atmosenv.2009.02.0362009AtmEn..43.2754G
– reference: GlaudePAFournetRBounaceurRMolièreMFuel Process. Technol.20109122910.1016/j.fuproc.2009.10.002
– reference: NeauEJaubertJNRogalskiMInd. Eng. Chem. Res.199332119610.1021/ie00018a027
– reference: WeidlichUGmehlingJInd. Eng. Chem. Res.198726137310.1021/ie00067a018
– reference: de CaroPSMoulounguiZBergeJCFuel20018056510.1016/S0016-2361(00)00117-4
– reference: MolièreMPanarottoEAboujaibMBisseaudJMCampbellACitenoJMairePADucrestLProc. ASME Turbo Expo20071397
– reference: MolièreMVierlingMAboujaibMPatilPErankiACampbellATrivediRAnainaniARoySPandeyNProc. ASME Turbo Expo20091341
– reference: JaubertJNAvaulléeLPierreCInd. Eng. Chem. Res.20024130310.1021/ie010485f
– reference: KwanchareonPLuengnaruemitchaiAJai-InSFuel200786105310.1016/j.fuel.2006.09.034
– reference: ZöldyMTransport20112630310.3846/16484142.2011.623824
– reference: CheenkachornKFungtammasanBInt. J. Green Energy200965710.1080/15435070802701819
– reference: LarsenBRasmussenPFrdenslundAInd. Eng. Chem. Res.198726227410.1021/ie00071a018
– reference: BarabasITodorutABaldeanDFuel201089382710.1016/j.fuel.2010.07.011
– reference: RakopoulosDCRakopoulosCDKakarasECGiakoumisEGEnergy Conv. Manag.200849315510.1016/j.enconman.2008.05.023
– reference: AvaulleeLTrassyLNeauEJaubertJNFluid Phase Equilib.199713915510.1016/S0378-3812(97)00168-4
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Snippet Recently, the concept of diesel–ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability...
Recently, the concept of diesel-ethanol blends has emerged as an alternative to regular diesel oils. However, these blends present serious stability...
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SubjectTerms 13th Joint European Thermophysics Conference 2015
Alcohols
Biodiesel
Blends
Chemical and Process Engineering
Classical Mechanics
Condensed Matter Physics
Diesel fuels
Engineering Sciences
Ethanol
Ethyl alcohol
Industrial Chemistry/Chemical Engineering
JETC 2015: 13th Joint European Thermodynamics Conference
Miscibility
Physical Chemistry
Physics
Physics and Astronomy
Title Design of Hybrid Fuels Using a Modeling Study of the Miscibility of Ethanol–Biodiesel–Hydrocarbon Systems
URI https://link.springer.com/article/10.1007/s10765-015-2032-y
https://www.proquest.com/docview/1864553764
https://hal.univ-lorraine.fr/hal-01703485
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