Insights into the Phosphate Species on Niobia Treated with H3PO4
Solid acid catalysts are largely used in several industrial processes, and the development of materials with high activity, selectivity and reusability is a subject of study of research groups around the world. The improvement of oxide acidity could be performed by phosphation with phosphoric acid b...
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| Published in | Catalysis letters Vol. 150; no. 5; pp. 1496 - 1504 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.05.2020
Springer Nature B.V Springer Verlag |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1011-372X 1572-879X |
| DOI | 10.1007/s10562-019-03056-3 |
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| Abstract | Solid acid catalysts are largely used in several industrial processes, and the development of materials with high activity, selectivity and reusability is a subject of study of research groups around the world. The improvement of oxide acidity could be performed by phosphation with phosphoric acid but the investigation of phosphated niobia is still incipient. In this work, niobia was treated with phosphoric acid solutions to generate catalysts with higher esterification activity at mild condition. The phosphated catalysts were obtained and characterized by XRD, N
2
adsorption, NH
3
and pyridine chemisorption and FTIR, and were tested in the esterification of acetic acid with ethanol at 60 °C and RT. DFPT calculations indicated that H
2
PO
4
group was the predominant phosphate species on the hydroxylated surface. Theoretical results also show that ethanol adsorbs preferentially at H
2
PO
4
acidic sites on the phosphated catalyst as compared to acetic acid.
Graphic Abstract |
|---|---|
| AbstractList | Solid acid catalysts are largely used in several industrial processes, and the development of materials with high activity, selectivity and reusability is a subject of study of research groups around the world. The improvement of oxide acidity could be performed by phosphation with phosphoric acid but the investigation of phosphated niobia is still incipient. In this work, niobia was treated with phosphoric acid solutions to generate catalysts with higher esterification activity at mild condition. The phosphated catalysts were obtained and characterized by XRD, N2 adsorption, NH3 and pyridine chemisorption and FTIR, and were tested in the esterification of acetic acid with ethanol at 60 °C and RT. DFPT calculations indicated that H2PO4 group was the predominant phosphate species on the hydroxylated surface. Theoretical results also show that ethanol adsorbs preferentially at H2PO4 acidic sites on the phosphated catalyst as compared to acetic acid.Graphic Abstract Solid acid catalysts are largely used in several industrial processes, and the development of materials with high activity, selectivity and reusability is a subject of study of research groups around the world. The improvement of oxide acidity could be performed by phosphation with phosphoric acid but the investigation of phosphated niobia is still incipient. In this work, niobia was treated with phosphoric acid solutions to generate catalysts with higher esterification activity at mild condition. The phosphated catalysts were obtained and characterized by XRD, N 2 adsorption, NH 3 and pyridine chemisorption and FTIR, and were tested in the esterification of acetic acid with ethanol at 60 °C and RT. DFPT calculations indicated that H 2 PO 4 group was the predominant phosphate species on the hydroxylated surface. Theoretical results also show that ethanol adsorbs preferentially at H 2 PO 4 acidic sites on the phosphated catalyst as compared to acetic acid. Graphic Abstract |
| Author | Oliveira, Ricardo R. Misael, Wilken A. Rocha, Angela S. Rocha, Alexandre B. de Araujo, Lúcia R. Raddi Costa, Gustavo C. |
| Author_xml | – sequence: 1 givenname: Angela S. orcidid: 0000-0002-3575-4844 surname: Rocha fullname: Rocha, Angela S. email: angela.sanches.rocha@gmail.com organization: Departamento de Físico-Química, Instituto de Química, Universidade do Estado do Rio de Janeiro – sequence: 2 givenname: Gustavo C. surname: Costa fullname: Costa, Gustavo C. organization: Departamento de Físico-Química, Instituto de Química, Universidade do Estado do Rio de Janeiro – sequence: 3 givenname: Lúcia R. Raddi surname: de Araujo fullname: de Araujo, Lúcia R. Raddi organization: Departamento de Físico-Química, Instituto de Química, Universidade do Estado do Rio de Janeiro – sequence: 4 givenname: Wilken A. surname: Misael fullname: Misael, Wilken A. organization: Departamento de Físico-Química, Instituto de Química, Universidade Federal do Rio de Janeiro – sequence: 5 givenname: Ricardo R. surname: Oliveira fullname: Oliveira, Ricardo R. organization: Departamento de Físico-Química, Instituto de Química, Universidade Federal do Rio de Janeiro – sequence: 6 givenname: Alexandre B. surname: Rocha fullname: Rocha, Alexandre B. organization: Departamento de Físico-Química, Instituto de Química, Universidade Federal do Rio de Janeiro |
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| Issue | 5 |
| Keywords | Theoretical calculation Solid acid Phosphated niobia Esterification |
| Language | English |
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| Title | Insights into the Phosphate Species on Niobia Treated with H3PO4 |
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