Electrografted monolayer based on a naphthalene diimide–ruthenium terpyridine complex dyad: efficient creation of large-area molecular junctions with high current densities

An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 80; pp. 10997 - 11000
Main Authors Frath, Denis, Nguyen, Van Quyen, Lafolet, Frédéric, Martin, Pascal, Lacroix, Jean-Christophe
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 05.10.2017
Subjects
chemical reactions
Chemical Sciences
diazonium compounds
evaporation
naphthalene
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ISSN1359-7345
1364-548X
1364-548X
DOI10.1039/C7CC04972B

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Summary:An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C7CC04972B