Electrografted monolayer based on a naphthalene diimide–ruthenium terpyridine complex dyad: efficient creation of large-area molecular junctions with high current densities

An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 80; pp. 10997 - 11000
Main Authors Frath, Denis, Nguyen, Van Quyen, Lafolet, Frédéric, Martin, Pascal, Lacroix, Jean-Christophe
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 05.10.2017
Subjects
Online AccessGet full text
ISSN1359-7345
1364-548X
1364-548X
DOI10.1039/C7CC04972B

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Abstract An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.
AbstractList An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.
An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.
An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct topcoat evaporation with a high yield of operating devices. Given the number of potential applications in molecular electronics, including switches, memories, transistors and rectifiers, the development of new molecular systems with multifunctional properties is of great importance.
Author Lafolet, Frédéric
Martin, Pascal
Nguyen, Van Quyen
Frath, Denis
Lacroix, Jean-Christophe
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  publication-title: Nat. Nanotechnol.
  doi: 10.1038/nnano.2017.110
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Snippet An electron donor–acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form...
An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form...
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SubjectTerms chemical reactions
Chemical Sciences
diazonium compounds
evaporation
naphthalene
Title Electrografted monolayer based on a naphthalene diimide–ruthenium terpyridine complex dyad: efficient creation of large-area molecular junctions with high current densities
URI https://www.ncbi.nlm.nih.gov/pubmed/28880324
https://www.proquest.com/docview/1936622679
https://www.proquest.com/docview/2986433845
https://hal.science/hal-01916367
Volume 53
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linkProvider Royal Society of Chemistry
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