Novel Application of Metal–Organic Frameworks as Efficient Sorbents for Solid-Phase Extraction of Chemical Warfare Agents and Related Compounds in Water Samples
In this work, we test metal–organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three M...
Saved in:
| Published in | Molecules (Basel, Switzerland) Vol. 29; no. 14; p. 3259 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Switzerland
MDPI AG
10.07.2024
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1420-3049 1420-3049 |
| DOI | 10.3390/molecules29143259 |
Cover
| Abstract | In this work, we test metal–organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three MOFs were used: MIL-100(Fe), ZIF-8(Zn), and UiO-66(Zr). The obtained materials were characterized using FT-IR/ATR, SEM, and XRD. CWA’s and related compounds were analyzed using gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). The effect of the type of elution solvent and the amount of sorbent (MOFs) in the column on the efficiency of the conducted extraction were verified. The LOD ranged from 0.04 to 7.54 ng mL−1, and the linearity range for the analytes tested extended from 0.11/22.62 (depending on the compound) to 1000 ng mL−1. It was found that MOFs showed the most excellent selectivity to compounds having aromatic rings in their structure or a “spread” spatial structure. The best recoveries were obtained for DPAA, CAP, and malathion. Environmental water samples collected from the Baltic Sea were analyzed using an optimized procedure to verify the developed method’s usefulness. |
|---|---|
| AbstractList | In this work, we test metal–organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three MOFs were used: MIL-100(Fe), ZIF-8(Zn), and UiO-66(Zr). The obtained materials were characterized using FT-IR/ATR, SEM, and XRD. CWA’s and related compounds were analyzed using gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). The effect of the type of elution solvent and the amount of sorbent (MOFs) in the column on the efficiency of the conducted extraction were verified. The LOD ranged from 0.04 to 7.54 ng mL−1, and the linearity range for the analytes tested extended from 0.11/22.62 (depending on the compound) to 1000 ng mL−1. It was found that MOFs showed the most excellent selectivity to compounds having aromatic rings in their structure or a “spread” spatial structure. The best recoveries were obtained for DPAA, CAP, and malathion. Environmental water samples collected from the Baltic Sea were analyzed using an optimized procedure to verify the developed method’s usefulness. In this work, we test metal-organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three MOFs were used: MIL-100(Fe), ZIF-8(Zn), and UiO-66(Zr). The obtained materials were characterized using FT-IR/ATR, SEM, and XRD. CWA's and related compounds were analyzed using gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). The effect of the type of elution solvent and the amount of sorbent (MOFs) in the column on the efficiency of the conducted extraction were verified. The LOD ranged from 0.04 to 7.54 ng mL-1, and the linearity range for the analytes tested extended from 0.11/22.62 (depending on the compound) to 1000 ng mL-1. It was found that MOFs showed the most excellent selectivity to compounds having aromatic rings in their structure or a "spread" spatial structure. The best recoveries were obtained for DPAA, CAP, and malathion. Environmental water samples collected from the Baltic Sea were analyzed using an optimized procedure to verify the developed method's usefulness.In this work, we test metal-organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three MOFs were used: MIL-100(Fe), ZIF-8(Zn), and UiO-66(Zr). The obtained materials were characterized using FT-IR/ATR, SEM, and XRD. CWA's and related compounds were analyzed using gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). The effect of the type of elution solvent and the amount of sorbent (MOFs) in the column on the efficiency of the conducted extraction were verified. The LOD ranged from 0.04 to 7.54 ng mL-1, and the linearity range for the analytes tested extended from 0.11/22.62 (depending on the compound) to 1000 ng mL-1. It was found that MOFs showed the most excellent selectivity to compounds having aromatic rings in their structure or a "spread" spatial structure. The best recoveries were obtained for DPAA, CAP, and malathion. Environmental water samples collected from the Baltic Sea were analyzed using an optimized procedure to verify the developed method's usefulness. In this work, we test metal-organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and their related compounds in water samples. During this study, we used 13 target compounds to test the selectivity of MOFs thoroughly. Three MOFs were used: MIL-100( ), ZIF-8( ), and UiO-66( ). The obtained materials were characterized using FT-IR/ATR, SEM, and XRD. CWA's and related compounds were analyzed using gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). The effect of the type of elution solvent and the amount of sorbent (MOFs) in the column on the efficiency of the conducted extraction were verified. The LOD ranged from 0.04 to 7.54 ng mL , and the linearity range for the analytes tested extended from 0.11/22.62 (depending on the compound) to 1000 ng mL . It was found that MOFs showed the most excellent selectivity to compounds having aromatic rings in their structure or a "spread" spatial structure. The best recoveries were obtained for DPAA, CAP, and malathion. Environmental water samples collected from the Baltic Sea were analyzed using an optimized procedure to verify the developed method's usefulness. |
| Author | Nawała, Jakub Popiel, Stanisław Zasada, Dariusz Szczęśniak, Barbara Woźniak, Jakub Choma, Jerzy |
| Author_xml | – sequence: 1 givenname: Jakub orcidid: 0000-0002-1662-5406 surname: Woźniak fullname: Woźniak, Jakub – sequence: 2 givenname: Stanisław orcidid: 0000-0001-5557-5061 surname: Popiel fullname: Popiel, Stanisław – sequence: 3 givenname: Jakub surname: Nawała fullname: Nawała, Jakub – sequence: 4 givenname: Barbara orcidid: 0000-0002-3448-2592 surname: Szczęśniak fullname: Szczęśniak, Barbara – sequence: 5 givenname: Jerzy orcidid: 0000-0003-0582-7608 surname: Choma fullname: Choma, Jerzy – sequence: 6 givenname: Dariusz surname: Zasada fullname: Zasada, Dariusz |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/39064838$$D View this record in MEDLINE/PubMed |
| BookMark | eNplks1u1DAQgC1URH_gAbggS1y4BOzYSePjarWllQpF_IhjNLHHWy9OnNoJlBvvwBvwaDwJ3m5bIbh4PNY3n2bkOSR7QxiQkKecvRRCsVd98Khnj6lUXIqyUg_IAZclKwSTau-v-z45TGnDWMklrx6R_Vxcy0Y0B-TX2_AVPV2Mo3caJhcGGix9gxP43z9-XsQ1DE7Tkwg9fgvxS6KQ6Mpapx0OE_0QYpdjojbEnHhnineXkJCurqcI-k63vMQ-2z39DNFCRLpY31TBYOh79DChocvQj2EeTKJuyNyEWQj9mId7TB5a8Amf3MYj8ulk9XF5WpxfvD5bLs4LnceZCtmBlszqDq2VipuG1xWqRnWNkJwxzAdiLUrZoDaqYSUoIzQ7RlUfC621OCJnO68JsGnH6HqI39sArr15CHHdQpyc9tiWlahNV0lbdlZaWavaWG6A1ciBGzTZ9WLnGmO4mjFNbe-SRu9hwDCnVrCm4lzVTGb0-T_oJsxxyJNuKZk7Vc2WenZLzV2P5r69u5_MAN8BOoaUItp7hLN2uy3tf9si_gAhx7bX |
| Cites_doi | 10.1016/j.talanta.2016.03.042 10.1063/10.0009664 10.7205/MILMED-D-11-00363 10.1016/j.talanta.2019.03.019 10.1016/j.trac.2015.04.026 10.1002/jssc.201200983 10.1016/j.cjche.2021.05.031 10.1016/j.dsr2.2015.01.017 10.1016/j.aca.2016.05.033 10.1016/j.chemosphere.2018.01.157 10.1039/C6AN00353B 10.1039/c3cc46105j 10.1021/acsami.8b00289 10.1016/j.carbon.2012.12.011 10.1016/j.jcis.2019.02.057 10.1021/acs.cgd.6b01776 10.1016/j.ccr.2017.10.010 10.3390/separations6040047 10.1021/acs.jpcc.9b05574 10.1002/aoc.6769 10.1021/ja01269a023 10.1016/j.marenvres.2020.105079 10.1021/acsami.7b19232 10.1038/46248 10.1002/9783527821099 10.1021/acs.analchem.8b02157 10.1038/natrevmats.2015.18 10.1007/s10934-018-0678-0 10.1016/j.aquatox.2020.105693 10.1080/07373937.2011.645413 10.1016/j.aca.2021.338984 10.1016/j.marenvres.2020.105112 10.1021/ja00146a033 10.1021/acs.analchem.8b01428 10.3390/molecules25040960 10.1016/j.chroma.2017.01.069 10.1021/jacs.5b08752 10.1021/acsanm.1c03863 10.1016/j.talanta.2018.10.037 10.1016/j.chroma.2014.05.027 10.1021/acs.est.8b00092 10.1016/j.aca.2017.02.023 10.1016/j.chroma.2020.460949 10.1039/D0DT04382F 10.3390/molecules24071211 10.1016/j.chroma.2011.09.066 10.1007/s10904-020-01548-z 10.1016/j.marenvres.2020.105077 |
| ContentType | Journal Article |
| Copyright | 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| Copyright_xml | – notice: 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
| DBID | AAYXX CITATION NPM 3V. 7X7 7XB 88E 8FI 8FJ 8FK ABUWG AFKRA AZQEC BENPR CCPQU DWQXO FYUFA GHDGH K9. M0S M1P PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQQKQ PQUKI PRINS 7X8 DOA |
| DOI | 10.3390/molecules29143259 |
| DatabaseName | CrossRef PubMed ProQuest Central (Corporate) Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) ProQuest Central UK/Ireland ProQuest Central Essentials ProQuest Central ProQuest One ProQuest Central Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Health & Medical Complete (Alumni) Health & Medical Collection (Alumni) Medical Database Proquest Central Premium ProQuest One Academic (New) Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) ProQuest One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central China MEDLINE - Academic DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef PubMed Publicly Available Content Database ProQuest One Academic Middle East (New) ProQuest Central Essentials ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest One Health & Nursing ProQuest Central China ProQuest Central Health Research Premium Collection Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Health & Medical Research Collection ProQuest Central (New) ProQuest Medical Library (Alumni) ProQuest One Academic Eastern Edition ProQuest Hospital Collection Health Research Premium Collection (Alumni) ProQuest Hospital Collection (Alumni) ProQuest Health & Medical Complete ProQuest Medical Library ProQuest One Academic UKI Edition ProQuest One Academic ProQuest One Academic (New) ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | Publicly Available Content Database MEDLINE - Academic PubMed CrossRef |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: BENPR name: ProQuest Central url: http://www.proquest.com/pqcentral?accountid=15518 sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1420-3049 |
| ExternalDocumentID | oai_doaj_org_article_2536db54f2bf4f4696df1da06e1a1ded 39064838 10_3390_molecules29143259 |
| Genre | Journal Article |
| GroupedDBID | --- 0R~ 123 2WC 53G 5VS 7X7 88E 8FE 8FG 8FH 8FI 8FJ A8Z AADQD AAFWJ AAHBH AAYXX ABDBF ABUWG ACGFO ACIWK ACPRK ACUHS AEGXH AENEX AFKRA AFPKN AFRAH AFZYC AIAGR ALIPV ALMA_UNASSIGNED_HOLDINGS BENPR BPHCQ BVXVI CCPQU CITATION CS3 D1I DIK DU5 E3Z EBD EMOBN ESX FYUFA GROUPED_DOAJ GX1 HH5 HMCUK HYE HZ~ I09 IAO IHR ITC KQ8 LK8 M1P MODMG O-U O9- OK1 P2P PHGZM PHGZT PIMPY PQQKQ PROAC PSQYO RPM SV3 TR2 TUS UKHRP ~8M NPM 3V. 7XB 8FK AZQEC DWQXO K9. PJZUB PKEHL PPXIY PQEST PQUKI PRINS 7X8 ESTFP PUEGO |
| ID | FETCH-LOGICAL-c390t-4bac40fcbeff491d8165e989b834100e410ee63248ecd9802a9d3c07e9673ccc3 |
| IEDL.DBID | DOA |
| ISSN | 1420-3049 |
| IngestDate | Wed Aug 27 01:25:30 EDT 2025 Fri Sep 05 11:54:33 EDT 2025 Sat Jul 26 03:00:39 EDT 2025 Thu Apr 03 07:04:03 EDT 2025 Tue Jul 01 03:59:55 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 14 |
| Keywords | water samples gas chromatography–tandem mass spectrometry metal–organic framework solid-phase extraction chemical warfare agents |
| Language | English |
| License | https://creativecommons.org/licenses/by/4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c390t-4bac40fcbeff491d8165e989b834100e410ee63248ecd9802a9d3c07e9673ccc3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0000-0001-5557-5061 0000-0003-0582-7608 0000-0002-3448-2592 0000-0002-1662-5406 |
| OpenAccessLink | https://doaj.org/article/2536db54f2bf4f4696df1da06e1a1ded |
| PMID | 39064838 |
| PQID | 3084980984 |
| PQPubID | 2032355 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_2536db54f2bf4f4696df1da06e1a1ded proquest_miscellaneous_3085119604 proquest_journals_3084980984 pubmed_primary_39064838 crossref_primary_10_3390_molecules29143259 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2024-Jul-10 |
| PublicationDateYYYYMMDD | 2024-07-10 |
| PublicationDate_xml | – month: 07 year: 2024 text: 2024-Jul-10 day: 10 |
| PublicationDecade | 2020 |
| PublicationPlace | Switzerland |
| PublicationPlace_xml | – name: Switzerland – name: Basel |
| PublicationTitle | Molecules (Basel, Switzerland) |
| PublicationTitleAlternate | Molecules |
| PublicationYear | 2024 |
| Publisher | MDPI AG |
| Publisher_xml | – name: MDPI AG |
| References | Vaher (ref_50) 2018; 198 Czub (ref_39) 2020; 161 ref_14 Augustus (ref_23) 2017; 5 Roy (ref_49) 2018; 90 Katz (ref_57) 2013; 49 Yang (ref_46) 2013; 36 Zhao (ref_56) 2015; 137 Gwardiak (ref_53) 2019; 26 Bondzic (ref_58) 2022; 5 Pang (ref_31) 2019; 199 Klusek (ref_7) 2016; 128 Brunauer (ref_52) 1938; 60 Chalela (ref_9) 2012; 177 Lian (ref_40) 2018; 10 Popiel (ref_11) 2011; 1218 ref_24 ref_22 ref_21 ref_20 Ruffley (ref_42) 2019; 123 Abuzalat (ref_43) 2021; 50 Yan (ref_44) 2022; 5 Howarth (ref_27) 2016; 1 Czub (ref_5) 2021; 230 Bi (ref_34) 2020; 30 Shang (ref_36) 2014; 1357 Goud (ref_48) 2018; 90 Xia (ref_33) 2020; 1619 Containing (ref_18) 1995; 117 Li (ref_35) 2021; 1184 Vanninen (ref_13) 2020; 161 Dhummakupt (ref_41) 2018; 10 Wexler (ref_4) 2023; Volume 7 Ghani (ref_32) 2017; 1488 ref_38 ref_37 Wong (ref_45) 2022; 36 Zhang (ref_17) 2022; 42 Jakacki (ref_12) 2020; 161 Jagiello (ref_54) 2013; 55 Buszewski (ref_15) 2012; 42 Guesh (ref_55) 2017; 17 Popiel (ref_10) 2016; 933 Li (ref_19) 1999; 402 Zhang (ref_29) 2016; 141 ref_1 Tang (ref_26) 2018; 52 ref_3 ref_2 (ref_16) 2015; 73 Vellingiri (ref_25) 2017; 353 ref_8 Sajid (ref_30) 2017; 965 Liu (ref_28) 2019; 194 ref_6 Dai (ref_47) 2016; 154 Ke (ref_51) 2019; 544 |
| References_xml | – volume: 154 start-page: 581 year: 2016 ident: ref_47 article-title: A combined experimental/computational study on metal-organic framework MIL-101(Cr) as a SPE sorbent for the determination of sulphonamides in environmental water samples coupling with UPLC-MS/MS publication-title: Talanta doi: 10.1016/j.talanta.2016.03.042 – volume: 5 start-page: 013005 year: 2022 ident: ref_44 article-title: A prototype portable instrument employing micro-preconcentrator and FBAR sensor for the detection of chemical warfare agents publication-title: Nanotechnol. Precis. Eng. doi: 10.1063/10.0009664 – volume: 177 start-page: 495 year: 2012 ident: ref_9 article-title: Chemical terrorism for the intensivist publication-title: Mil. Med. doi: 10.7205/MILMED-D-11-00363 – volume: 199 start-page: 499 year: 2019 ident: ref_31 article-title: Metal-organic framework-monolith composite-based in-tube solid phase microextraction on-line coupled to high-performance liquid chromatography-fluorescence detection for the highly sensitive monitoring of fluoroquinolones in water and food samples publication-title: Talanta doi: 10.1016/j.talanta.2019.03.019 – volume: 73 start-page: 19 year: 2015 ident: ref_16 article-title: Miniaturized solid-phase extraction techniques publication-title: TrAC Trends Anal. Chem. doi: 10.1016/j.trac.2015.04.026 – volume: 36 start-page: 1283 year: 2013 ident: ref_46 article-title: Evaluation of metal-organic framework 5 as a new SPE material for the determination of polycyclic aromatic hydrocarbons in environmental waters publication-title: J. Sep. Sci. doi: 10.1002/jssc.201200983 – volume: Volume 7 start-page: 121 year: 2023 ident: ref_4 article-title: The OPCW publication-title: Encyclopedia of Toxicology – volume: 42 start-page: 245 year: 2022 ident: ref_17 article-title: Development trend and prospect of solid phase extraction technology publication-title: Chin. J. Chem. Eng. doi: 10.1016/j.cjche.2021.05.031 – volume: 128 start-page: 85 year: 2016 ident: ref_7 article-title: Chemical Munitions Search & Assessment-An evaluation of the dumped munitions problem in the Baltic Sea publication-title: Deep Sea Res. Part II doi: 10.1016/j.dsr2.2015.01.017 – volume: 933 start-page: 103 year: 2016 ident: ref_10 article-title: Development of the HS-SPME-GC-MS/MS method for analysis of chemical warfare agent and their degradation products in environmental samples publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2016.05.033 – ident: ref_1 – volume: 198 start-page: 460 year: 2018 ident: ref_50 article-title: Evaluation of carbon aerogel-based solid-phase extraction sorbent for the analysis of sulfur mustard degradation products in environmental water samples publication-title: Chemosphere doi: 10.1016/j.chemosphere.2018.01.157 – volume: 141 start-page: 4219 year: 2016 ident: ref_29 article-title: Metal-organic frameworks@graphene hybrid aerogels for solid-phase extraction of non-steroidal anti-inflammatory drugs and selective enrichment of proteins publication-title: Analyst doi: 10.1039/C6AN00353B – ident: ref_8 – volume: 49 start-page: 9449 year: 2013 ident: ref_57 article-title: A facile synthesis of UiO-66, UiO-67 and their derivatives publication-title: Chem. Commun. doi: 10.1039/c3cc46105j – volume: 10 start-page: 14869 year: 2018 ident: ref_40 article-title: Trace Detection of Organophosphorus Chemical Warfare Agents in Wastewater and Plants by Luminescent UIO-67(Hf) and Evaluating the Bioaccumulation of Organophosphorus Chemical Warfare Agents publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.8b00289 – volume: 55 start-page: 70 year: 2013 ident: ref_54 article-title: 2D-NLDFT adsorption models for carbon slit-shaped pores with surface energetical heterogeneity and geometrical corrugation publication-title: Carbon doi: 10.1016/j.carbon.2012.12.011 – volume: 544 start-page: 312 year: 2019 ident: ref_51 article-title: Structures and dimensions of micelle-templated nanoporous silicas derived from swollen spherical micelles of temperature-dependent size publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2019.02.057 – volume: 17 start-page: 1806 year: 2017 ident: ref_55 article-title: Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water publication-title: Cryst. Growth Des. doi: 10.1021/acs.cgd.6b01776 – volume: 353 start-page: 159 year: 2017 ident: ref_25 article-title: Metal–organic frameworks as media for the catalytic degradation of chemical warfare agents publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2017.10.010 – ident: ref_24 doi: 10.3390/separations6040047 – volume: 123 start-page: 19748 year: 2019 ident: ref_42 article-title: Design, Synthesis, and Characterization of Metal-Organic Frameworks for Enhanced Sorption of Chemical Warfare Agent Simulants publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.9b05574 – volume: 36 start-page: e6769 year: 2022 ident: ref_45 article-title: In situ encapsulation of ZrQ in UiO-66 (Zr-BDC) for pore size control to enhance detection of a nerve agent simulant dimethyl methyl phosphonate publication-title: Appl. Organomet. Chem. doi: 10.1002/aoc.6769 – volume: 5 start-page: 61 year: 2017 ident: ref_23 article-title: Metal-organic Frameworks as Novel Adsorbents: A Preview publication-title: Am. J. Environ. Prot. – volume: 60 start-page: 309 year: 1938 ident: ref_52 article-title: Adsorption of Gases in Multimolecular Layers publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01269a023 – volume: 161 start-page: 105079 year: 2020 ident: ref_12 article-title: High resolution model for assessment of contamination by chemical warfare agents dumped in the Baltic Sea publication-title: Mar. Environ. Res. doi: 10.1016/j.marenvres.2020.105079 – ident: ref_38 – volume: 10 start-page: 8359 year: 2018 ident: ref_41 article-title: Metal-Organic Framework Modified Glass Substrate for Analysis of Highly Volatile Chemical Warfare Agents by Paper Spray Mass Spectrometry publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.7b19232 – volume: 402 start-page: 276 year: 1999 ident: ref_19 article-title: Design and synthesis of an exceptionally stable and highly porous metal-organic framework publication-title: Nature doi: 10.1038/46248 – ident: ref_20 doi: 10.1002/9783527821099 – volume: 90 start-page: 8295 year: 2018 ident: ref_48 article-title: Efficient Extraction of Sulfur and Nitrogen Mustards from Nonpolar Matrix and an Investigation on Their Sorption Behavior on Silica publication-title: Anal. Chem. doi: 10.1021/acs.analchem.8b02157 – volume: 1 start-page: 15018 year: 2016 ident: ref_27 article-title: Chemical, thermal and mechanical stabilities of metal-organic frameworks publication-title: Nat. Rev. Mater. doi: 10.1038/natrevmats.2015.18 – volume: 26 start-page: 775 year: 2019 ident: ref_53 article-title: Benzene adsorption on synthesized and commercial metal–organic frameworks publication-title: J. Porous Mater. doi: 10.1007/s10934-018-0678-0 – volume: 230 start-page: 105693 year: 2021 ident: ref_5 article-title: Acute aquatic toxicity of arsenic-based chemical warfare agents to Daphnia magna publication-title: Aquat. Toxicol. doi: 10.1016/j.aquatox.2020.105693 – volume: 42 start-page: 198 year: 2012 ident: ref_15 article-title: Past, Present, and Future of Solid Phase Extraction: A Review publication-title: Crit. Rev. Anal. Chem. doi: 10.1080/07373937.2011.645413 – volume: 1184 start-page: 338984 year: 2021 ident: ref_35 article-title: Macro-microporous zeolitic imidazole framework-8/cellulose aerogel for semi-automated pipette tip solid phase extraction of fluoroquinolones in water publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2021.338984 – ident: ref_3 – volume: 161 start-page: 105112 year: 2020 ident: ref_13 article-title: Exposure status of sea-dumped chemical warfare agents in the Baltic Sea publication-title: Mar. Environ. Res doi: 10.1016/j.marenvres.2020.105112 – volume: 117 start-page: 10401 year: 1995 ident: ref_18 article-title: Hydrothermal synthesis of a Metal-Organic Framework containing large rectangular channels publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00146a033 – volume: 90 start-page: 7025 year: 2018 ident: ref_49 article-title: Polymeric Sorbent with Controlled Surface Polarity: An Alternate for Solid-Phase Extraction of Nerve Agents and Their Markers from Organic Matrix publication-title: Anal. Chem. doi: 10.1021/acs.analchem.8b01428 – ident: ref_14 – ident: ref_21 doi: 10.3390/molecules25040960 – volume: 1488 start-page: 1 year: 2017 ident: ref_32 article-title: Metal-organic framework mixed-matrix disks: Versatile supports for automated solid-phase extraction prior to chromatographic separation publication-title: J. Chromatogr. A doi: 10.1016/j.chroma.2017.01.069 – volume: 137 start-page: 13756 year: 2015 ident: ref_56 article-title: Facile Conversion of Hydroxy Double Salts to Metal-Organic Frameworks Using Metal Oxide Particles and Atomic Layer Deposition Thin-Film Templates publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b08752 – volume: 5 start-page: 3312 year: 2022 ident: ref_58 article-title: Synergistic Effect of Sorption and Hydrolysis by NU-1000 Nanostructures for Removal and Detoxification of Chlorpyrifos publication-title: ACS Appl. Nano Mater. doi: 10.1021/acsanm.1c03863 – volume: 194 start-page: 514 year: 2019 ident: ref_28 article-title: Magnetic nanoparticle of metal-organic framework with core-shell structure as an adsorbent for magnetic solid phase extraction of non-steroidal anti-inflammatory drugs publication-title: Talanta doi: 10.1016/j.talanta.2018.10.037 – volume: 1357 start-page: 165 year: 2014 ident: ref_36 article-title: Metal-organic framework UiO-66 coated stainless steel fiber for solid-phase microextraction of phenols in water samples publication-title: J. Chromatogr. A doi: 10.1016/j.chroma.2014.05.027 – ident: ref_6 – volume: 52 start-page: 5367 year: 2018 ident: ref_26 article-title: Metal Organic Framework with Coordinatively Unsaturated Sites as Efficient Fenton-like Catalyst for Enhanced Degradation of Sulfamethazine publication-title: Environ. Sci. Technol. doi: 10.1021/acs.est.8b00092 – volume: 965 start-page: 36 year: 2017 ident: ref_30 article-title: Porous membrane protected micro-solid-phase extraction: A review of features, advancements and applications publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2017.02.023 – volume: 1619 start-page: 460949 year: 2020 ident: ref_33 article-title: Adsorption behavior of a metal organic framework of University in Oslo 67 and its application to the extraction of sulfonamides in meat samples publication-title: J. Chromatogr. A doi: 10.1016/j.chroma.2020.460949 – ident: ref_2 – volume: 50 start-page: 3261 year: 2021 ident: ref_43 article-title: Facile and rapid synthesis of functionalized Zr-BTC for the optical detection of the blistering agent simulant 2-chloroethyl ethyl sulfide (CEES) publication-title: Dalton Trans. doi: 10.1039/D0DT04382F – ident: ref_37 doi: 10.3390/molecules24071211 – volume: 1218 start-page: 8457 year: 2011 ident: ref_11 article-title: Determination of chemical warfare agents and related compounds in environmental samples by solid-phase microextraction with gas chromatography publication-title: J. Chromatogr. A doi: 10.1016/j.chroma.2011.09.066 – volume: 30 start-page: 3388 year: 2020 ident: ref_34 article-title: Nano-Sized MIL-100(Fe) as a Carrier Material for Nitidine Chloride Reduces Toxicity and Enhances Anticancer Effects In Vitro publication-title: J. Inorg. Organomet. Polym. doi: 10.1007/s10904-020-01548-z – ident: ref_22 – volume: 161 start-page: 105077 year: 2020 ident: ref_39 article-title: Acute aquatic toxicity of sulfur mustard and its degradation products to Daphnia magna publication-title: Mar. Environ. Res. doi: 10.1016/j.marenvres.2020.105077 |
| SSID | ssj0021415 |
| Score | 2.4200945 |
| Snippet | In this work, we test metal–organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and... In this work, we test metal-organic frameworks (MOFs) as sorbents in the solid-phase extraction (SPE) technique to determine chemical warfare agents (CWAs) and... |
| SourceID | doaj proquest pubmed crossref |
| SourceType | Open Website Aggregation Database Index Database |
| StartPage | 3259 |
| SubjectTerms | Biological & chemical weapons Chemical reactions chemical warfare agents gas chromatography–tandem mass spectrometry metal–organic framework Military supplies Pollutants Qualitative research solid-phase extraction Sorbents water samples |
| SummonAdditionalLinks | – databaseName: ProQuest Technology Collection dbid: 8FG link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3NbtQwELagHOCCyv_SgozECSlq7DhZ-1SVapcKqRVSqegt8s-4rQRJSbaII-_AG_TReBJmnGSLhOASKcnEsTy2Z8Yz8w1jr6N2c-MDpSgLmykUaZl1QWbC2lJ64VDFpgTnw6Pq4ES9Py1PxwO3fgyrnPbEtFGH1tMZ-U6Ra2V0brTavfyaUdUo8q6OJTRusztCoqylTPHlu7XBJVA6DZ7MAk37nS9DwVnopUEtQRI86R-yKEH2_1vPTPJmucnuj4oi3xs4-4DdguYhu7s_1Wd7xK6P2m-ABDceaN5GfgioTf_68XPIsfR8OQVf9dz2fJEAI1DO8OO2cxRDwVFpxZvPFyH7cI4SjS--r7oh2YGam_AE-CfbRdsB3ztLX9km8BRHB4HTlkLFmXp-0SAdMoofWwId7h-zk-Xi4_5BNlZcyDwO0CpTznqVR-8gRmVE0KIqwWjjNAq7PAe8ABDAuwYfkBvSmlD4fA6mmhfe--IJ22jaBp4xHoywUboyRmnRBCxdAveae-2VcNHGGXszjX19OQBr1GiQEKPqvxg1Y2-JO2tCwsROD9rurB6XWC3LogquVPjXqCKa_VWIIti8AmFFgDBj2xNv63Gh9vXNtJqxV-vXyEnym9gG2qtEQ97WKkeap8OcWPcEu1spXejn_298i92TqA2lON98m22suit4gdrMyr1MU_Y3ucj51g priority: 102 providerName: ProQuest |
| Title | Novel Application of Metal–Organic Frameworks as Efficient Sorbents for Solid-Phase Extraction of Chemical Warfare Agents and Related Compounds in Water Samples |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/39064838 https://www.proquest.com/docview/3084980984 https://www.proquest.com/docview/3085119604 https://doaj.org/article/2536db54f2bf4f4696df1da06e1a1ded |
| Volume | 29 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV3NbtQwELagHOBS8c9CWRmJE1JUO3ES-9hWu1RIXVWUir1F_hlDJUiqZIs48g68AY_GkzC2k6USQly4WEoyiSaeiWcmnvmGkJdemlpZF0qUuc4EmrRMG5dnXOsyt9ygix0KnE9W1fG5eLMu19dafYWcsAQPnCZuPy-LyplS-Nx44TGYq5znTrMKuOYOXFh9mWJTMDWGWhztUtrDLDCo3_-cWs3CkCv0D_IATHrNCkWw_r97mNHSLO-S3dFFpAeJtXvkBrT3ye2jqTPbA_Jj1X0BJPi990w7T08A_eif376n6kpLl1Pa1UD1QBcRKgItDD3rehOyJyi6q3jw6cJlpx_RltHF102fyhzC4yYkAfpe9173QA8-xLt062jMoANHw2IS2jIN9KJFOhQRPdMBbnh4SM6Xi3dHx9nYayGzOEGbTBhtBfPWgPdCcSd5VYKSykg0c4wBDgAB2l2CdUqyXCtXWFaDqurCWls8Ijtt18ITQp3iGqVVep9rDP5KE2G9aiut4MZrPyOvprlvLhOkRoOhSBBU84egZuQwSGdLGNCw4wnUkWbUkeZfOjIje5Nsm_ETHZqCSYEvoqSYkRfbyyjJsGOiW-iuIk3YZ60Y0jxOOrHlBNmthCzk0__B4TNyJ0dvKfw05myP7Gz6K3iO3s7GzMnNel3jKJev5-TW4WJ1-nYelf0XleIG5g |
| linkProvider | Directory of Open Access Journals |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtR3LbtQw0CrlUC6IdxcKGAkuSFFjx0nsA0Kl7GpLuyuktmJvwc9SCZKSbHnc-Af-gA_go_gSZpLNLhKCWy-RkkxsKzOeh-dFyOMgTa6swxRlpiMBIi3SxvGIaZ1yywyo2JjgPJlm42PxapbO1sjPPhcGwyp7ntgyaldZPCPfTmIplIyVFM_PPkbYNQq9q30LjY4s9v3Xz2CyNc_2XgJ-n3A-Gh7tjqNFV4HIgn0_j4TRVsTBGh-CUMxJlqVeSWUkMPQ49nDxHouYS28dzMi1comNc6-yPLHWJjDuJXJZoIsR9k8-Wxl4DKRh5zlNYKrtD12DW99wBVoJx3Kof8i-tkXAv_XaVr6NrpGrC8WU7nSUdJ2s-fIG2djt-8HdJD-m1ScPACuPN60CnXjQ3n99-97ldFo66oO9GqobOmwLVIBco4dVbTBmg4KSDDfvT130-h1IUDr8Mq-75Aocrq9fQN_oOuja052T9itdOtrG7XlHkYVhM6iGnpYAB4RBDzUWOW5ukeMLwcVtsl5Wpd8k1CmmAzdpCFyDyZmatphYbqUVzAQdBuRp_--Ls66QRwEGECKq-AtRA_ICsbMExBrc7YOqPikWW7rgaZI5kwqYNYggMpW5wJyOM880c94NyFaP22LBGJpiRcYD8mj5GjCJfhpd-uq8hUHvbhYDzJ2OJpYrgeVmQiby7v8Hf0g2xkeTg-Jgb7p_j1zhoInhgTSLt8j6vD7390GTmpsHLflS8vai98tv2xc2_A |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwELZKKwGXijdbChgJLkjRxo6T2IcK9bGrltLVilLRW-pnqQRJSbY8bvwH_gE_pz-jv4Sxk2yRENx6WSm7E8faGc8jM_MNQs8dV7nQxrcoExkxMGmRVIZGRMqUaqLAxfYNznuTbPuAvT5MDxfQed8L48sqe50YFLWptH9HPkxizgSPBWdD15VFTLfGr04_R36ClM-09uM0ZDdmwawFuLGuyWPXfv8K4VyztrMFvH9B6Xj0bnM76iYORBpi_1nElNQsdlpZ55gghpMstYILxUHZx7GFD2s9wDm32sBuqBQm0XFuRZYnWusE1r2GlnKw-hAILm2MJtO38_CPgK1s86oJPGz4qR1_axsqwGehHiz1D8sYBgj82-sN1m98Cy13biteb-XsNlqw5R10Y7OfFncX_ZpUXywQXObDceXwngXf_uLHz7bjU-NxXwrWYNngUYCvAKuH96ta-YoODC40XHw8MdH0A9hXPPo2q9vWC79cj26A38vaydri9eNwlywNDlV91mCv4PyoqAaflEAHYoP3pYdAbu6hgyvhxn20WFalfYiwEUQ6qlLnqISANFUBaizXXDOinHQD9LL_74vTFuajgPDIM6r4i1EDtOG5Myf0CN3hi6o-LroDX9A0yYxKGTzVMccykRlHjIwzSyQx1gzQas_bolMbTXEp5AP0bP4zcNJncWRpq7NA43O_WQw0D1qZmO8EtpsxnvCV_y_-FF2Hs1O82ZnsPkI3Kbhp_m01iVfR4qw-s4_BzZqpJ538YnR01UfmN_yPQdc |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Novel+Application+of+Metal-Organic+Frameworks+as+Efficient+Sorbents+for+Solid-Phase+Extraction+of+Chemical+Warfare+Agents+and+Related+Compounds+in+Water+Samples&rft.jtitle=Molecules+%28Basel%2C+Switzerland%29&rft.au=Wo%C5%BAniak%2C+Jakub&rft.au=Popiel%2C+Stanis%C5%82aw&rft.au=Nawa%C5%82a%2C+Jakub&rft.au=Szcz%C4%99%C5%9Bniak%2C+Barbara&rft.date=2024-07-10&rft.issn=1420-3049&rft.eissn=1420-3049&rft.volume=29&rft.issue=14&rft_id=info:doi/10.3390%2Fmolecules29143259&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1420-3049&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1420-3049&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1420-3049&client=summon |