Development strategies in transition metal carbide for hydrogen evolution reaction: A review
Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst Transition metal carbides (TMCs) have many merits such as low price, platinum-like catalytic activity, high physical stability, and electrical conductivity. This review presents strate...
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| Published in | The Korean journal of chemical engineering Vol. 37; no. 8; pp. 1317 - 1330 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.08.2020
Springer Nature B.V 한국화학공학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0256-1115 1975-7220 |
| DOI | 10.1007/s11814-020-0612-4 |
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| Abstract | Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst Transition metal carbides (TMCs) have many merits such as low price, platinum-like catalytic activity, high physical stability, and electrical conductivity. This review presents strategies for improving the catalytic activity of TMCs. It highlights synthesis using nanostructuring by inorganic-organic complexes and carbon supports to increase the number of active sites and to facilitate mass transport, and modification of electronic configuration by heteroatom doping, heterostructure, and phase control to increase intrinsic activity. The review concludes with an outlook on challenges to achieving practical TMC catalysts for the hydrogen evolution reaction. |
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| AbstractList | Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst Transition metal carbides (TMCs) have many merits such as low price, platinum-like catalytic activity, high physical stability, and electrical conductivity. This review presents strategies for improving the catalytic activity of TMCs. It highlights synthesis using nanostructuring by inorganic-organic complexes and carbon supports to increase the number of active sites and to facilitate mass transport, and modification of electronic configuration by heteroatom doping, heterostructure, and phase control to increase intrinsic activity. The review concludes with an outlook on challenges to achieving practical TMC catalysts for the hydrogen evolution reaction. Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst. Transition metal carbides (TMCs) have many merits such as low price, platinum-like catalytic activity, high physical stability, and electrical conductivity. This review presents strategies for improving the catalytic activity of TMCs. It highlights synthesis using nanostructuring by inorganic-organic complexes and carbon supports to increase the number of active sites and to facilitate mass transport, and modification of electronic configuration by heteroatom doping, heterostructure, and phase control to increase intrinsic activity. The review concludes with an outlook on challenges to achieving practical TMC catalysts for the hydrogen evolution reaction. KCI Citation Count: 13 |
| Author | Jun, Hyunwoo Kim, Seongbeen Lee, Jinwoo |
| Author_xml | – sequence: 1 givenname: Hyunwoo surname: Jun fullname: Jun, Hyunwoo organization: Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST) – sequence: 2 givenname: Seongbeen surname: Kim fullname: Kim, Seongbeen organization: Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH) – sequence: 3 givenname: Jinwoo surname: Lee fullname: Lee, Jinwoo email: jwlee1@kaist.ac.kr organization: Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST) |
| BackLink | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART002610720$$DAccess content in National Research Foundation of Korea (NRF) |
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| Snippet | Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst Transition metal carbides (TMCs) have many... Economically viable hydrogen production by water electrolysis requires an inexpensive and efficient electrocatalyst. Transition metal carbides (TMCs) have many... |
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| SubjectTerms | Biotechnology Catalysis Catalytic activity Chemistry Chemistry and Materials Science Electrical resistivity Electrocatalysts Electrolysis Heterostructures Hydrogen evolution reactions Hydrogen production Industrial Chemistry/Chemical Engineering Invited Review Paper Materials Science Metal carbides Phase control Platinum Transition metals 화학공학 |
| Title | Development strategies in transition metal carbide for hydrogen evolution reaction: A review |
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