An overview on non-spherical semiconductors for heterogeneous photocatalytic degradation of organic water contaminants
Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulatio...
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| Published in | Chemosphere (Oxford) Vol. 280; p. 130907 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.10.2021
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0045-6535 1879-1298 1879-1298 |
| DOI | 10.1016/j.chemosphere.2021.130907 |
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| Abstract | Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulation, etc., have relatively higher operating costs and can generate highly toxic secondary contaminants. On the other hand, heterogeneous photocatalysis, an advanced oxidation process (AOP), is considered a clean and cost-effective process for organic pollutants degradation. Owing to their distinctive structure and physicochemical properties non-spherical semiconductors have gained considerable limelight in the photocatalytic degradation of organic contaminants. The current review briefly introduces a wide range of organic water contaminants. Recent advances in non-spherical semiconductor assembly and their photocatalytic degradation applications are highlighted. The underlying mechanism, fundamentals of photocatalytic reactions, and the factors affecting the degradation performance are also alluded including the current challenges and future research perspectives.
[Display omitted]
•Applications of non-spherical semiconductors in photocatalytic degradation discussed.•Various parameters such as morphology and crystal plan were discussed.•There exists a correlation between catalyst morphology and its photocatalytic activity.•Reaction parameters e.g., catalyst concentration influenced in alter the reaction rates. |
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| AbstractList | Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulation, etc., have relatively higher operating costs and can generate highly toxic secondary contaminants. On the other hand, heterogeneous photocatalysis, an advanced oxidation process (AOP), is considered a clean and cost-effective process for organic pollutants degradation. Owing to their distinctive structure and physicochemical properties non-spherical semiconductors have gained considerable limelight in the photocatalytic degradation of organic contaminants. The current review briefly introduces a wide range of organic water contaminants. Recent advances in non-spherical semiconductor assembly and their photocatalytic degradation applications are highlighted. The underlying mechanism, fundamentals of photocatalytic reactions, and the factors affecting the degradation performance are also alluded including the current challenges and future research perspectives. Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulation, etc., have relatively higher operating costs and can generate highly toxic secondary contaminants. On the other hand, heterogeneous photocatalysis, an advanced oxidation process (AOP), is considered a clean and cost-effective process for organic pollutants degradation. Owing to their distinctive structure and physicochemical properties non-spherical semiconductors have gained considerable limelight in the photocatalytic degradation of organic contaminants. The current review briefly introduces a wide range of organic water contaminants. Recent advances in non-spherical semiconductor assembly and their photocatalytic degradation applications are highlighted. The underlying mechanism, fundamentals of photocatalytic reactions, and the factors affecting the degradation performance are also alluded including the current challenges and future research perspectives. [Display omitted] •Applications of non-spherical semiconductors in photocatalytic degradation discussed.•Various parameters such as morphology and crystal plan were discussed.•There exists a correlation between catalyst morphology and its photocatalytic activity.•Reaction parameters e.g., catalyst concentration influenced in alter the reaction rates. Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulation, etc., have relatively higher operating costs and can generate highly toxic secondary contaminants. On the other hand, heterogeneous photocatalysis, an advanced oxidation process (AOP), is considered a clean and cost-effective process for organic pollutants degradation. Owing to their distinctive structure and physicochemical properties non-spherical semiconductors have gained considerable limelight in the photocatalytic degradation of organic contaminants. The current review briefly introduces a wide range of organic water contaminants. Recent advances in non-spherical semiconductor assembly and their photocatalytic degradation applications are highlighted. The underlying mechanism, fundamentals of photocatalytic reactions, and the factors affecting the degradation performance are also alluded including the current challenges and future research perspectives.Because of their carcinogenicity and mutagenicity, the elimination of organic contaminants from surface and subsurface water is a subject of environmental significance. Conventional water decontamination approaches such as membrane separation, ultrafiltration, adsorption, reverse osmosis, coagulation, etc., have relatively higher operating costs and can generate highly toxic secondary contaminants. On the other hand, heterogeneous photocatalysis, an advanced oxidation process (AOP), is considered a clean and cost-effective process for organic pollutants degradation. Owing to their distinctive structure and physicochemical properties non-spherical semiconductors have gained considerable limelight in the photocatalytic degradation of organic contaminants. The current review briefly introduces a wide range of organic water contaminants. Recent advances in non-spherical semiconductor assembly and their photocatalytic degradation applications are highlighted. The underlying mechanism, fundamentals of photocatalytic reactions, and the factors affecting the degradation performance are also alluded including the current challenges and future research perspectives. |
| ArticleNumber | 130907 |
| Author | Park, Yuri Varma, Rajender S. Zare, Ehsan Nazarzadeh Sillanpaa, Mika Iftekhar, Sidra Srivastava, Varsha Makvandi, Pooyan Joseph, Jessy Khan, Moonis Ali |
| Author_xml | – sequence: 1 givenname: Ehsan Nazarzadeh surname: Zare fullname: Zare, Ehsan Nazarzadeh email: ehsan.nazarzadehzare@gmail.com, e.nazarzadeh@du.ac.ir organization: School of Chemistry, Damghan University, Damghan 36716-41167, Iran – sequence: 2 givenname: Sidra surname: Iftekhar fullname: Iftekhar, Sidra organization: Department of Applied Physics, University of Eastern Finland, Kuopio, 70210, Finland – sequence: 3 givenname: Yuri surname: Park fullname: Park, Yuri organization: Department of Separation Science, Lappeenranta–Lahti University of Technology LUT, Sammonkatu 12, FI, 50130, Mikkeli, Finland – sequence: 4 givenname: Jessy surname: Joseph fullname: Joseph, Jessy organization: Department of Separation Science, Lappeenranta–Lahti University of Technology LUT, Sammonkatu 12, FI, 50130, Mikkeli, Finland – sequence: 5 givenname: Varsha surname: Srivastava fullname: Srivastava, Varsha organization: Department of Separation Science, Lappeenranta–Lahti University of Technology LUT, Sammonkatu 12, FI, 50130, Mikkeli, Finland – sequence: 6 givenname: Moonis Ali orcidid: 0000-0002-0548-8581 surname: Khan fullname: Khan, Moonis Ali organization: Chemistry Department, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia – sequence: 7 givenname: Pooyan surname: Makvandi fullname: Makvandi, Pooyan organization: Center for Materials Interfaces, Istituto Italiano di Tecnologia (IIT), Viale R. Piaggio 34, 56025, Pontedera, Pisa, Italy – sequence: 8 givenname: Mika surname: Sillanpaa fullname: Sillanpaa, Mika email: mika.sillanpaa@tdtu.edu.vn organization: Environmental Engineering and Management Research Group, Ton Duc Thang University, Ho Chi Minh City, Viet Nam – sequence: 9 givenname: Rajender S. orcidid: 0000-0001-9731-6228 surname: Varma fullname: Varma, Rajender S. email: Varma.Rajender@epa.gov organization: Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University in Olomouc, Šlechtitelů 27, 783 71, Olomouc, Czech Republic |
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| IngestDate | Sun Sep 28 07:28:58 EDT 2025 Sun Sep 28 06:09:20 EDT 2025 Thu Sep 25 00:24:48 EDT 2025 Thu Apr 24 22:56:12 EDT 2025 Fri Feb 23 02:45:11 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Photocatalytic degradation MPC PS LPUV L-H HOFe GDE Organic pollutants DOFe DP SCWO Non-spherical semiconductors HMs Synthesis EE2 DBP MB SPEF MDP THMs US WHO MPUV EF MP DCF LPVUV TOC EO VB RhB BPA HEFe CWAO HANs BDD WAO ENR CTAB Mechanism AOPs EDCs WO COD CBZ CB PTFE TDFe CN NPs PEF TIAA PCPs PC PMS ATL PAHs TCEP |
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| PublicationCentury | 2000 |
| PublicationDate | October 2021 2021-10-00 20211001 |
| PublicationDateYYYYMMDD | 2021-10-01 |
| PublicationDate_xml | – month: 10 year: 2021 text: October 2021 |
| PublicationDecade | 2020 |
| PublicationTitle | Chemosphere (Oxford) |
| PublicationYear | 2021 |
| Publisher | Elsevier Ltd |
| Publisher_xml | – name: Elsevier Ltd |
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| SubjectTerms | adsorption carcinogenicity coagulation cost effectiveness decontamination Mechanism mutagenicity Non-spherical semiconductors Organic pollutants oxidation photocatalysis Photocatalytic degradation reverse osmosis semiconductors Synthesis ultrafiltration water pollution |
| Title | An overview on non-spherical semiconductors for heterogeneous photocatalytic degradation of organic water contaminants |
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