A simulation study on selection of optimized process for azeotropic separation of methanol and benzene: Internal heat integration and economic analysis
This work provides an insight into the separation of azeotropic mixtures by using two different techniques: pressure swing distillation and extractive distillation. Both methods are used to separate an azeotropic mixture of methanol and benzene. This mixture exhibits a minimum boiling azeotrope at t...
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| Published in | The Korean journal of chemical engineering Vol. 35; no. 5; pp. 1185 - 1194 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.05.2018
Springer Nature B.V 한국화학공학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0256-1115 1975-7220 |
| DOI | 10.1007/s11814-018-0021-0 |
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| Abstract | This work provides an insight into the separation of azeotropic mixtures by using two different techniques: pressure swing distillation and extractive distillation. Both methods are used to separate an azeotropic mixture of methanol and benzene. This mixture exhibits a minimum boiling azeotrope at temperature 57.97 °C and pressure 1 bar with mole fractions of 0.61 and 0.39 for methanol and benzene, respectively. However, the azeotropic point in methanol and benzene mixture is pressure sensitive, which can be shifted by changing pressure with a process called pressure swing distillation. Extractive distillation with suitable solvent is another method to separate such kind of mixture. Both methods are rigorously simulated and optimized for minimum heat duties. Internal heat integration is applied too for increasing energy efficiency. New optimization techniques are carried out with process simulator Aspen HYSYS V8.4 and results reveal the best method for separation of methanol and benzene azeotropic mixture. |
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| AbstractList | This work provides an insight into the separation of azeotropic mixtures by using two different techniques: pressure swing distillation and extractive distillation. Both methods are used to separate an azeotropic mixture of methanol and benzene. This mixture exhibits a minimum boiling azeotrope at temperature 57.97 °C and pressure 1 bar with mole fractions of 0.61 and 0.39 for methanol and benzene, respectively. However, the azeotropic point in methanol and benzene mixture is pressure sensitive, which can be shifted by changing pressure with a process called pressure swing distillation. Extractive distillation with suitable solvent is another method to separate such kind of mixture. Both methods are rigorously simulated and optimized for minimum heat duties. Internal heat integration is applied too for increasing energy efficiency. New optimization techniques are carried out with process simulator Aspen HYSYS V8.4 and results reveal the best method for separation of methanol and benzene azeotropic mixture. This work provides an insight into the separation of azeotropic mixtures by using two different techniques: pressure swing distillation and extractive distillation. Both methods are used to separate an azeotropic mixture of methanol and benzene. This mixture exhibits a minimum boiling azeotrope at temperature 57.97 oC and pressure 1 bar with mole fractions of 0.61 and 0.39 for methanol and benzene, respectively. However, the azeotropic point in methanol and benzene mixture is pressure sensitive, which can be shifted by changing pressure with a process called pressure swing distillation. Extractive distillation with suitable solvent is another method to separate such kind of mixture. Both methods are rigorously simulated and optimized for minimum heat duties. Internal heat integration is applied too for increasing energy efficiency. New optimization techniques are carried out with process simulator Aspen HYSYS V8.4 and results reveal the best method for separation of methanol and benzene azeotropic mixture. KCI Citation Count: 8 |
| Author | Shin, Jae Sun Park, Sang Jin Qasim, Faraz |
| Author_xml | – sequence: 1 givenname: Faraz surname: Qasim fullname: Qasim, Faraz organization: Dongguk University – sequence: 2 givenname: Jae Sun surname: Shin fullname: Shin, Jae Sun organization: Dongguk University – sequence: 3 givenname: Sang Jin surname: Park fullname: Park, Sang Jin email: sjpark@dongguk.edu organization: Dongguk University |
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| CitedBy_id | crossref_primary_10_1007_s11814_023_1574_0 crossref_primary_10_1007_s11814_020_0682_3 crossref_primary_10_1002_jctb_6294 crossref_primary_10_3390_pr8121618 crossref_primary_10_3390_en14217183 crossref_primary_10_1016_j_cep_2018_11_005 crossref_primary_10_1080_15567036_2020_1829751 crossref_primary_10_1007_s11814_018_0182_x crossref_primary_10_1021_jacs_3c13480 crossref_primary_10_1007_s11814_020_0714_z crossref_primary_10_1371_journal_pone_0310541 |
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| SubjectTerms | Benzene Biotechnology Catalysis Chemical industry Chemistry Chemistry and Materials Science Distillation Economic analysis Hydrocarbons Industrial Chemistry/Chemical Engineering Materials Science Methanol Separation Separation Technology Simulation Thermodynamics 화학공학 |
| Title | A simulation study on selection of optimized process for azeotropic separation of methanol and benzene: Internal heat integration and economic analysis |
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