Synthesis of Aqueous CdTe Nanocrystals with High Efficient Blue-Green Emission of Exciton

• Published in: Chinese journal of chemistry Vol. 30; no. 4; pp. 803 - 808
• Main Author: 邵海宝 王春雷 李荣青 徐淑宏 张海升 崔一平
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.04.2012; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: blue-emitting; CdTe; CdTe纳米晶; Emissions; Growth conditions; nanocrystals; Nucleation; X-射线光电子能谱; 光量子产率; 合成条件; 水溶液; 激子; 绿色发光; 透射电子显微镜
• ISSN: 1001-604X; 1614-7065
• DOI: 10.1002/cjoc.201100113

As one of the most popular nanocrystals （NCs）, aqueous CdTe NCs have very weak green emission under con- ventional synthesis conditions. In this work, we report the first example of blue-emitting CdTe NCs directly synthe- sized in aqueous solution by slowing down the growth rate after nucleation. The key for the synthesis is the optimi- zation of NC growth conditions, namely pH range of 7.5 to 8.5, TGA/Cd ratio of 3.6, Cd/Te ratio of 10, and Te concentration of 2 × 10-5 mol/L, to get a slow growth rate after nucleation. The as-prepared blue-emitting CdTe NCs have small size （as small as 1.9 nm） and bright emission [with 4% photoluminescence quantum yield （PL QY） at 486 nm and 17% PLQY at 500 nm]. Transmission electron microscopy （TEM） images of the as-prepared CdTe show monodispersed NCs which exhibit cubic zinc blend structure. Moreover, time-resolved PL decay and X-ray photoelectron spectroscopy （XPS） results show the as-prepared NCs have better surface modification by ligand, which makes these luminescent small CdTe NCs have higher photoluminescence quantum yield, compared with NCs synthesized under conventional conditions.