Catalytic Performance and Coking Behavior of a Submicron HZSM-5 Zeolite in Ethanol Dehydration
The catalytic performance and coking behavior of a submicron ZSM-5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the mic...
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| Published in | Chinese journal of chemistry Vol. 29; no. 7; pp. 1326 - 1334 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
01.07.2011
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-604X 1614-7065 |
| DOI | 10.1002/cjoc.201180250 |
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| Abstract | The catalytic performance and coking behavior of a submicron ZSM-5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the micron one due to more mesopores and more strong acid sites. As the reaction temperature increased, ethanol conversion increased over the submicron catalyst, while ethylene selectivity went through a maximum. The selectivities of propylene and butylene increased with increasing reaction temperature, and they decreased with time on stream at constant temperature. The coke deposits can be divided into coke precursor and hard coke, which were attributed to polyalkylbenzene and poly- cyclic aromatic hydrocarbons, respectively; and increasing reaction temperature can accelerate the transformation of coke precursor into hard coke. A precoking pretreatment method was verified very effective for improving the catalyst stability. |
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| AbstractList | The catalytic performance and coking behavior of a submicron ZSM‐5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the micron one due to more mesopores and more strong acid sites. As the reaction temperature increased, ethanol conversion increased over the submicron catalyst, while ethylene selectivity went through a maximum. The selectivities of propylene and butylene increased with increasing reaction temperature, and they decreased with time on stream at constant temperature. The coke deposits can be divided into coke precursor and hard coke, which were attributed to polyalkylbenzene and polycyclic aromatic hydrocarbons, respectively; and increasing reaction temperature can accelerate the transformation of coke precursor into hard coke. A precoking pretreatment method was verified very effective for improving the catalyst stability. The catalytic performance and coking behavior of a submicron ZSM‐5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the micron one due to more mesopores and more strong acid sites. As the reaction temperature increased, ethanol conversion increased over the submicron catalyst, while ethylene selectivity went through a maximum. The selectivities of propylene and butylene increased with increasing reaction temperature, and they decreased with time on stream at constant temperature. The coke deposits can be divided into coke precursor and hard coke, which were attributed to polyalkylbenzene and polycyclic aromatic hydrocarbons, respectively; and increasing reaction temperature can accelerate the transformation of coke precursor into hard coke. A precoking pretreatment method was verified very effective for improving the catalyst stability. 13C NMR spectra show that the coke deposits on the submicron ZSM‐5 zeolite mainly consist of two carbon species. As the temperature increased, the saturated carbons in the range of δ 0–50 decreased while the unsaturated carbons in the range of δ 100–170 increased. These trends exhibit that the coke became more and more unsaturated with rising temperature. The catalytic performance and coking behavior of a submicron ZSM-5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the micron one due to more mesopores and more strong acid sites. As the reaction temperature increased, ethanol conversion increased over the submicron catalyst, while ethylene selectivity went through a maximum. The selectivities of propylene and butylene increased with increasing reaction temperature, and they decreased with time on stream at constant temperature. The coke deposits can be divided into coke precursor and hard coke, which were attributed to polyalkylbenzene and poly- cyclic aromatic hydrocarbons, respectively; and increasing reaction temperature can accelerate the transformation of coke precursor into hard coke. A precoking pretreatment method was verified very effective for improving the catalyst stability. |
| Author | Luo, Man Xiao, Wende Wang, Fei |
| AuthorAffiliation | State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China School of Chemistty, and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China |
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| CitedBy_id | crossref_primary_10_1002_cite_201500012 crossref_primary_10_1021_acscatal_4c04162 crossref_primary_10_1016_j_cej_2013_08_071 |
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| Notes | alcohols, submicron, zeolites, coking behavior, precoking 31-1547/O6 The catalytic performance and coking behavior of a submicron ZSM-5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature nitrogen adsorption, thermal gravimetric analysis, and nuclear magnetic resonance. The submicron catalyst showed higher activity than the micron one due to more mesopores and more strong acid sites. As the reaction temperature increased, ethanol conversion increased over the submicron catalyst, while ethylene selectivity went through a maximum. The selectivities of propylene and butylene increased with increasing reaction temperature, and they decreased with time on stream at constant temperature. The coke deposits can be divided into coke precursor and hard coke, which were attributed to polyalkylbenzene and poly- cyclic aromatic hydrocarbons, respectively; and increasing reaction temperature can accelerate the transformation of coke precursor into hard coke. A precoking pretreatment method was verified very effective for improving the catalyst stability. Wang, Feia LUO, Manb Xiao, Wende（a State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China b School of Chemistty, and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China） istex:C9408433D2EDAFB550BAF461FAA8C049C24BA708 ArticleID:CJOC201180250 ark:/67375/WNG-C5NFR14F-D ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
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| Snippet | The catalytic performance and coking behavior of a submicron ZSM-5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature... The catalytic performance and coking behavior of a submicron ZSM‐5 zeolite in dehydration of ethanol to ethylene were investigated by means of low temperature... |
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| SubjectTerms | alcohols Coke coking behavior Dehydration Ethanol Gravimetric analysis Low temperature NMR Nuclear magnetic resonance Polycyclic aromatic hydrocarbons precoking Shells submicron Zeolites 乙醇脱水 亚微米 催化性能 反应温度 沸石 焦化 行为 预处理方法 |
| Title | Catalytic Performance and Coking Behavior of a Submicron HZSM-5 Zeolite in Ethanol Dehydration |
| URI | http://lib.cqvip.com/qk/84126X/201107/38699282.html https://api.istex.fr/ark:/67375/WNG-C5NFR14F-D/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fcjoc.201180250 https://www.proquest.com/docview/1766807956 |
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