Influence of Zinc and Humic Acids on Dye Adsorption from Water by Two Composts
Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsor...
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| Published in | International journal of environmental research and public health Vol. 20; no. 7; p. 5353 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Switzerland
MDPI AG
31.03.2023
MDPI |
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| Online Access | Get full text |
| ISSN | 1660-4601 1661-7827 1660-4601 |
| DOI | 10.3390/ijerph20075353 |
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| Abstract | Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts—municipal solid waste compost and pine bark compost—in the presence of Zn (5 mg L−1) or dissolved organic matter (100 mg humic acids L−1) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g−1 for DB71, 2 mg g−1 for AB113, and 40 mg g−1 for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g−1 versus 6.8 mg g−1). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions. |
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| AbstractList | Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts—municipal solid waste compost and pine bark compost—in the presence of Zn (5 mg L−1) or dissolved organic matter (100 mg humic acids L−1) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g−1 for DB71, 2 mg g−1 for AB113, and 40 mg g−1 for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g−1 versus 6.8 mg g−1). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions. Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts-municipal solid waste compost and pine bark compost-in the presence of Zn (5 mg L ) or dissolved organic matter (100 mg humic acids L ) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g for DB71, 2 mg g for AB113, and 40 mg g for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g versus 6.8 mg g ). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions. Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts-municipal solid waste compost and pine bark compost-in the presence of Zn (5 mg L-1) or dissolved organic matter (100 mg humic acids L-1) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g-1 for DB71, 2 mg g-1 for AB113, and 40 mg g-1 for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g-1 versus 6.8 mg g-1). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions.Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts-municipal solid waste compost and pine bark compost-in the presence of Zn (5 mg L-1) or dissolved organic matter (100 mg humic acids L-1) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g-1 for DB71, 2 mg g-1 for AB113, and 40 mg g-1 for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g-1 versus 6.8 mg g-1). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions. Searching for alternative low-cost biosorbents for the removal of textile dyes from wastewater is currently an important subject of research. In this work, we have investigated how the presence of other contaminants in textile wastewaters can affect dye adsorption by biosorbents. We tested the adsorption of three dyes of different types: Basic Violet 10 (BV10), Acid Blue 113 (AB113) and Direct Blue 71 (DB71) by two different composts-municipal solid waste compost and pine bark compost-in the presence of Zn (5 mg L[sup.−1]) or dissolved organic matter (100 mg humic acids L[sup.−1]) in batch experiments. Dye adsorption capacity for both composts followed the following sequence: BV10 > AB113 > DB71. In general, dye sorption at the equilibrium was adequately described by the Freundlich model, but not always by the Langmuir model, which did not allow for the estimation of maximum retention capacities in all cases. In general, these were around 1 mg g[sup.−1] for DB71, 2 mg g[sup.−1] for AB113, and 40 mg g[sup.−1] for BV10. Municipal solid waste compost had slightly higher affinity than pine bark compost for the anionic dyes AB113 and DB71, whereas for the cationic dye BV10, pine bark compost presented a much higher adsorption capacity (41.7 mg g[sup.−1] versus 6.8 mg g[sup.−1]). The presence of Zn or dissolved organic matter in the solutions at typical wastewater concentrations did not decrease the dye adsorption capacity of the composts. This result is positive both for the real application of composts to real textile wastewaters and for the validity of the results of biosorbent performance obtained with single-dye solutions. |
| Audience | Academic |
| Author | Al-Zawahreh, Khaled Barral, Maria Teresa García, Paula González, Alba Paradelo, Remigio |
| AuthorAffiliation | 1 CRETUS-Department of Soil Science and Agricultural Chemistry, University of Santiago de Compostela, 15782 Santiago de Compostela, Spain 2 Department of Earth Sciences and Environment, Prince El-Hassan bin Talal Faculty for Natural Resources and Environment, The Hashemite University, Zarqa 13133, Jordan |
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| Author_xml | – sequence: 1 givenname: Remigio orcidid: 0000-0002-4165-177X surname: Paradelo fullname: Paradelo, Remigio – sequence: 2 givenname: Paula surname: García fullname: García, Paula – sequence: 3 givenname: Alba surname: González fullname: González, Alba – sequence: 4 givenname: Khaled surname: Al-Zawahreh fullname: Al-Zawahreh, Khaled – sequence: 5 givenname: Maria Teresa surname: Barral fullname: Barral, Maria Teresa |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/37047967$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1007_s40710_025_00746_6 crossref_primary_10_1007_s11270_024_07419_4 crossref_primary_10_1016_j_biteb_2024_101983 crossref_primary_10_3390_app14146128 crossref_primary_10_1080_21622515_2024_2404650 |
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| Keywords | adsorption pine bark compost direct blue 71 basic violet 10 acid blue 113 municipal solid waste compost |
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| SubjectTerms | Acids Adsorbents Adsorption Aqueous solutions Biodegradation Coloring Agents Communication Composting Dissolved Organic Matter Dyes Equilibrium Humic acid Humic Substances Hydrogen-Ion Concentration Kinetics Municipal solid waste Salinity Solid Waste Wastewater Water Water Pollutants, Chemical Zinc |
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| Title | Influence of Zinc and Humic Acids on Dye Adsorption from Water by Two Composts |
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