Pyrene monomer-excimer dynamics to reveal molecular organization in mesoporous hybrid silica films
Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembl...
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| Published in | Nanoscale Vol. 16; no. 4; pp. 18918 - 18932 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
17.10.2024
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2040-3364 2040-3372 2040-3372 |
| DOI | 10.1039/d4nr02987a |
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| Abstract | Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembly of such films, we synthesized an efficient molecular probe of the triethoxysilane precursor bearing a pyrene derivative. The probe was introduced into the porous film at the synthesis stage through the sol-gel co-condensation method. At different synthesis stages, the emission of pyrene moieties was measured by fluorescence spectroscopy, revealing the placement of probes within the film. We also report dynamic excimer formation upon template removal. Moreover, we evaluate the influence of several parameters on the pyrene excimer formation phenomenon. The pore geometry, probe concentration, and the presence of another organosilane precursor are investigated in this work.
Pyrene derivative is used as a molecular probe to investigate the interactions in hybrid mesoporous films through fluorescence spectroscopy. The dynamic formation of pyrene excimer provides insight into the nanoscale organization of the material. |
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| AbstractList | Pyrene derivative is used as a molecular probe to investigate the interactions in hybrid mesoporous films through fluorescence spectroscopy. The dynamic formation of pyrene excimer provides insight into the nanoscale organization of the material. Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembly of such films, we synthesized an efficient molecular probe of the triethoxysilane precursor bearing a pyrene derivative. The probe was introduced into the porous film at the synthesis stage through the sol-gel co-condensation method. At different synthesis stages, the emission of pyrene moieties was measured by fluorescence spectroscopy, revealing the placement of probes within the film. We also report dynamic excimer formation upon template removal. Moreover, we evaluate the influence of several parameters on the pyrene excimer formation phenomenon. The pore geometry, probe concentration, and the presence of another organosilane precursor are investigated in this work. Pyrene derivative is used as a molecular probe to investigate the interactions in hybrid mesoporous films through fluorescence spectroscopy. The dynamic formation of pyrene excimer provides insight into the nanoscale organization of the material. Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembly of such films, we synthesized an efficient molecular probe of the triethoxysilane precursor bearing a pyrene derivative. The probe was introduced into the porous film at the synthesis stage through the sol–gel co-condensation method. At different synthesis stages, the emission of pyrene moieties was measured by fluorescence spectroscopy, revealing the placement of probes within the film. We also report dynamic excimer formation upon template removal. Moreover, we evaluate the influence of several parameters on the pyrene excimer formation phenomenon. The pore geometry, probe concentration, and the presence of another organosilane precursor are investigated in this work. Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembly of such films, we synthesized an efficient molecular probe of the triethoxysilane precursor bearing a pyrene derivative. The probe was introduced into the porous film at the synthesis stage through the sol-gel co-condensation method. At different synthesis stages, the emission of pyrene moieties was measured by fluorescence spectroscopy, revealing the placement of probes within the film. We also report dynamic excimer formation upon template removal. Moreover, we evaluate the influence of several parameters on the pyrene excimer formation phenomenon. The pore geometry, probe concentration, and the presence of another organosilane precursor are investigated in this work.Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation and formation of micelles makes our understanding of this process insufficient. To provide an insight into the evaporation-induced self-assembly of such films, we synthesized an efficient molecular probe of the triethoxysilane precursor bearing a pyrene derivative. The probe was introduced into the porous film at the synthesis stage through the sol-gel co-condensation method. At different synthesis stages, the emission of pyrene moieties was measured by fluorescence spectroscopy, revealing the placement of probes within the film. We also report dynamic excimer formation upon template removal. Moreover, we evaluate the influence of several parameters on the pyrene excimer formation phenomenon. The pore geometry, probe concentration, and the presence of another organosilane precursor are investigated in this work. |
| Author | Kusz, Jakub Sanchez, Clément Parola, Stephane Boissiere, Cédric Bretonnière, Yann |
| AuthorAffiliation | Université Claude Bernard Lyon 1 Sorbonne Université CNRS Collège de France École Normale Supérieure de Lyon Laboratoire de Chimie Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP) |
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| Author_xml | – sequence: 1 givenname: Jakub surname: Kusz fullname: Kusz, Jakub – sequence: 2 givenname: Cédric surname: Boissiere fullname: Boissiere, Cédric – sequence: 3 givenname: Yann surname: Bretonnière fullname: Bretonnière, Yann – sequence: 4 givenname: Clément surname: Sanchez fullname: Sanchez, Clément – sequence: 5 givenname: Stephane surname: Parola fullname: Parola, Stephane |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/39267607$$D View this record in MEDLINE/PubMed https://hal.science/hal-04735829$$DView record in HAL |
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| Snippet | Self-assembly and characteristics of hybrid mesoporous silica film templates remain a subject of inquiry. The short time scale of the inorganic condensation... Pyrene derivative is used as a molecular probe to investigate the interactions in hybrid mesoporous films through fluorescence spectroscopy. The dynamic... |
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| SubjectTerms | Chemical Sciences Chemical synthesis Condensation Excimers Micelles Precursors Self-assembly Silicon dioxide Sol-gel processes |
| Title | Pyrene monomer-excimer dynamics to reveal molecular organization in mesoporous hybrid silica films |
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