Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed by 2,2':6',2''-terpyridine and 2,2'-biphenyldicarboxylic acid

Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structu...

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Published inJournal of rare earths Vol. 30; no. 3; pp. 256 - 261
Main Author 谢洪珍 张燕广 龚丹宇 魏丹毅
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.03.2012
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
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ISSN1002-0721
2509-4963
DOI10.1016/S1002-0721(12)60033-7

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Abstract Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature.
AbstractList O626; Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1,Yb 2,H2dpdc=2,2'-biphenyldicarboxylic acid and tpy=2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diff action analysis.The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(Ⅲ) centers.In the asymmetric unit,the two Er(Ⅲ) ions in 3 were both nine-coordinated and had similar coordination environments.The Er(Ⅲ) ions were bridged by dpdc2- ligands into dinuclear structures.The complexes were also characterized by IR spectra and thermogravimetric analysis.The solid fluorescence of 1 and 3 was also investigated at room temperature.
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature.
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2′-biphenyldicarboxylic acid and tpy= 2,2′:6′,2″-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)23 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2− ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature.
Author 谢洪珍 张燕广 龚丹宇 魏丹毅
AuthorAffiliation State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
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Issue 3
Keywords fluorescence
lanthanide coordination complexes
crystal structures
2,2′-biphenyldicarboxylic acid
rare earths
2,2'-biphenyldicarboxylic acid
Language English
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Notes lanthanide coordination complexes crystal structures fluorescence 2,2'-biphenyldicarboxylic acid rare earths
11-2788/TF
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature.
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Snippet Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one...
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2′-biphenyldicarboxylic acid and tpy= 2,2′:6′,2″-terpyridine] and one dinuclear...
O626; Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1,Yb 2,H2dpdc=2,2'-biphenyldicarboxylic acid and tpy=2,2':6',2''-terpyridine] and one...
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SubjectTerms 2,2′-biphenyldicarboxylic acid
crystal structures
fluorescence
lanthanide coordination complexes
rare earths
X射线衍射分析
三联吡啶
双核配合物
水热合成
表征
配位聚合物
铒(Ⅲ)
镧系元素
Title Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed by 2,2':6',2''-terpyridine and 2,2'-biphenyldicarboxylic acid
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Volume 30
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