Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed by 2,2':6',2''-terpyridine and 2,2'-biphenyldicarboxylic acid
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structu...
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Published in | Journal of rare earths Vol. 30; no. 3; pp. 256 - 261 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.03.2012
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China |
Subjects | |
Online Access | Get full text |
ISSN | 1002-0721 2509-4963 |
DOI | 10.1016/S1002-0721(12)60033-7 |
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Abstract | Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. |
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AbstractList | O626; Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1,Yb 2,H2dpdc=2,2'-biphenyldicarboxylic acid and tpy=2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diff action analysis.The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(Ⅲ) centers.In the asymmetric unit,the two Er(Ⅲ) ions in 3 were both nine-coordinated and had similar coordination environments.The Er(Ⅲ) ions were bridged by dpdc2- ligands into dinuclear structures.The complexes were also characterized by IR spectra and thermogravimetric analysis.The solid fluorescence of 1 and 3 was also investigated at room temperature. Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2′-biphenyldicarboxylic acid and tpy= 2,2′:6′,2″-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)23 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2− ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. |
Author | 谢洪珍 张燕广 龚丹宇 魏丹毅 |
AuthorAffiliation | State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China |
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Cites_doi | 10.1021/cm000386c 10.1002/ejic.200300121 10.1021/ic701817n 10.1039/b314220e 10.1002/macp.200900354 10.1080/00958970802189858 10.1021/ja0002619 10.1038/378703a0 10.1021/cr900362e 10.1016/S1002-0721(08)60337-3 10.1016/j.inoche.2007.11.004 10.1016/j.ica.2011.01.037 10.1021/ja071707p 10.1021/ic0110124 |
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Keywords | fluorescence lanthanide coordination complexes crystal structures 2,2′-biphenyldicarboxylic acid rare earths 2,2'-biphenyldicarboxylic acid |
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Notes | lanthanide coordination complexes crystal structures fluorescence 2,2'-biphenyldicarboxylic acid rare earths 11-2788/TF Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one dinuclear complex Er2(dpdc)2(Hdpdc)2(tpy)2 3 were obtained via hydrothermal reactions and determined by X-ray diffraction analysis. The crystal structure data of 1 and 2 revealed that two coordination polymers were isostructural and possessed a 1D chain framework consisting of eight-coordinated Ln(III) centers. In the asymmetric unit, the two Er(III) ions in 3 were both nine-coordinated and had similar coordination environments. The Er(III) ions were bridged by dpdc2-ligands into dinuclear structures. The complexes were also characterized by IR spectra and thermogravimetric analysis. The solid fluorescence of 1 and 3 was also investigated at room temperature. |
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Snippet | Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2'-biphenyldicarboxylic acid and tpy= 2,2':6',2''-terpyridine] and one... Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2′-biphenyldicarboxylic acid and tpy= 2,2′:6′,2″-terpyridine] and one dinuclear... O626; Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1,Yb 2,H2dpdc=2,2'-biphenyldicarboxylic acid and tpy=2,2':6',2''-terpyridine] and one... |
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SubjectTerms | 2,2′-biphenyldicarboxylic acid crystal structures fluorescence lanthanide coordination complexes rare earths X射线衍射分析 三联吡啶 双核配合物 水热合成 表征 配位聚合物 铒(Ⅲ) 镧系元素 |
Title | Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed by 2,2':6',2''-terpyridine and 2,2'-biphenyldicarboxylic acid |
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