Nano-preparation promoting effectively luminescent properties of one-dimensional rare earth oxides

Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostmcatres were synthesized hydrothermally under facile and mild conditions with two surfactants, and characterized by X-ray diffraction (XRD), thermal gravimetry (TG), scanning electron microscopy (SEM), transmission electron microscop...

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Published inJournal of rare earths Vol. 30; no. 11; pp. 1096 - 1101
Main Author 李俊峰 卢冠忠 谢宝庚 王艳芹 郭耘 郭杨龙
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2012
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ISSN1002-0721
2509-4963
DOI10.1016/S1002-0721(12)60186-0

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Abstract Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostmcatres were synthesized hydrothermally under facile and mild conditions with two surfactants, and characterized by X-ray diffraction (XRD), thermal gravimetry (TG), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence. The results showed that the synthesized rare earth oxides behaved regular nano- and micro-scale structures. And the morphologies of samples depended on the radii of rare earth ions, with the help of two sur- factants of sodium dodecyl sulfonic and PEG 600. Nanocrystalline La2O3:Eu^3+ possessed good photoluminescence (PL) property and might be used as a nanosized phosphor, its PL intensity was akered by the doping Eu^3+ concentration and the optimum concentration of Eu^3+ was 3 mol.%. In comparison with bulk Eu^3+/La2O3, Eu^3+/nano-La2O3 showed better photoluminescence property, nearly equal to that of nanocrtstalline La2O3:Eu^3+. Tb4O7 microwires showed interesting photoluminescence properties.
AbstractList Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostructures were synthesized hydrothermally under facile and mild conditions with two surfactants, and characterized by X-ray diffraction (XRD), thermal gravimetry (TG), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence. The results showed that the synthesized rare earth oxides behaved regular nano- and micro-scale structures. And the morphologies of samples depended on the radii of rare earth ions, with the help of two surfactants of sodium dodecyl sulfonic and PEG 600. Nanocrystalline La2O3:Eu3+ possessed good photoluminescence (PL) property and might be used as a nanosized phosphor, its PL intensity was altered by the doping Eu3+ concentration and the optimum concentration of Eu3+ was 3 mol.%. In comparison with bulk Eu3+/La2O3, Eu3+/nano-La2O3 showed better photoluminescence property, nearly equal to that of nanocrtstalline La2O3:Eu3+. Tb4O7 microwires showed interesting photoluminescence properties.
Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostmcatres were synthesized hydrothermally under facile and mild conditions with two surfactants, and characterized by X-ray diffraction (XRD), thermal gravimetry (TG), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence. The results showed that the synthesized rare earth oxides behaved regular nano- and micro-scale structures. And the morphologies of samples depended on the radii of rare earth ions, with the help of two sur- factants of sodium dodecyl sulfonic and PEG 600. Nanocrystalline La2O3:Eu^3+ possessed good photoluminescence (PL) property and might be used as a nanosized phosphor, its PL intensity was akered by the doping Eu^3+ concentration and the optimum concentration of Eu^3+ was 3 mol.%. In comparison with bulk Eu^3+/La2O3, Eu^3+/nano-La2O3 showed better photoluminescence property, nearly equal to that of nanocrtstalline La2O3:Eu^3+. Tb4O7 microwires showed interesting photoluminescence properties.
Author 李俊峰 卢冠忠 谢宝庚 王艳芹 郭耘 郭杨龙
AuthorAffiliation Key Laboratory for Advanced Materials and Research institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China
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Issue 11
Keywords one-dimensional morphology
luminescence property
rare earth oxides
hydrothermal synthesis
Eu3+ dopant
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Notes Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostmcatres were synthesized hydrothermally under facile and mild conditions with two surfactants, and characterized by X-ray diffraction (XRD), thermal gravimetry (TG), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence. The results showed that the synthesized rare earth oxides behaved regular nano- and micro-scale structures. And the morphologies of samples depended on the radii of rare earth ions, with the help of two sur- factants of sodium dodecyl sulfonic and PEG 600. Nanocrystalline La2O3:Eu^3+ possessed good photoluminescence (PL) property and might be used as a nanosized phosphor, its PL intensity was akered by the doping Eu^3+ concentration and the optimum concentration of Eu^3+ was 3 mol.%. In comparison with bulk Eu^3+/La2O3, Eu^3+/nano-La2O3 showed better photoluminescence property, nearly equal to that of nanocrtstalline La2O3:Eu^3+. Tb4O7 microwires showed interesting photoluminescence properties.
rare earth oxides; one-dimensional morphology; hydrothermal synthesis; luminescence property; Eu^3+ dopant
11-2788/TF
LI Junfeng , LU Guanzhong , XIE Baogeng , WANG Yanqin, GUO Yun , GUO Yanglong (Key Laboratory for Advanced Materials and Research institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China)
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Snippet Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostmcatres were synthesized hydrothermally under facile and mild conditions with two...
Rare earth (La, Nd and Tb) oxides with one-dimensional micro/nanostructures were synthesized hydrothermally under facile and mild conditions with two...
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SubjectTerms Eu3+ dopant
hydrothermal synthesis
luminescence property
Nanocomposites
Nanomaterials
Nanostructure
one-dimensional morphology
Photoluminescence
Rare earth compounds
Rare earth metals
rare earth oxides
Scanning electron microscopy
Surfactants
一维
光致发光性质
发光性能
扫描电子显微镜
水热法合成
稀土氧化物
纳米氧化镧
透射电子显微镜
Title Nano-preparation promoting effectively luminescent properties of one-dimensional rare earth oxides
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Volume 30
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