Supramolecular structure of electroactive polymer thin films
This paper presents the results of an experimental investigation of the supramolecular structure of polydiphenylenephthalide thin films that exhibit effects of resistive switching. The supramolecular structure of the polymer has been investigated using small-angle neutron scattering in conjunction w...
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| Published in | Physics of the solid state Vol. 58; no. 5; pp. 1065 - 1070 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.05.2016
Springer |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1063-7834 1090-6460 |
| DOI | 10.1134/S1063783416050115 |
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| Abstract | This paper presents the results of an experimental investigation of the supramolecular structure of polydiphenylenephthalide thin films that exhibit effects of resistive switching. The supramolecular structure of the polymer has been investigated using small-angle neutron scattering in conjunction with atomic force microscopy. It has been found that the internal structure of polymer films consists of structural elements in the form of spheroids. The sizes of the structural elements, which were obtained from the neutron scattering data and analysis of the atomic force microscopy images, correlate well with each other. A model of the formation of polymer layers has been proposed. The observed structural elements in polymer films are formed due to the association of macromolecules in the initial polymer solution. |
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| AbstractList | This paper presents the results of an experimental investigation of the supramolecular structure of polydiphenylenephthalide thin films that exhibit effects of resistive switching. The supramolecular structure of the polymer has been investigated using small-angle neutron scattering in conjunction with atomic force microscopy. It has been found that the internal structure of polymer films consists of structural elements in the form of spheroids. The sizes of the structural elements, which were obtained from the neutron scattering data and analysis of the atomic force microscopy images, correlate well with each other. A model of the formation of polymer layers has been proposed. The observed structural elements in polymer films are formed due to the association of macromolecules in the initial polymer solution. DOI: 10.1134/S1063783416050115 This paper presents the results of an experimental investigation of the supramolecular structure of polydiphenylenephthalide thin films that exhibit effects of resistive switching. The supramolecular structure of the polymer has been investigated using small-angle neutron scattering in conjunction with atomic force microscopy. It has been found that the internal structure of polymer films consists of structural elements in the form of spheroids. The sizes of the structural elements, which were obtained from the neutron scattering data and analysis of the atomic force microscopy images, correlate well with each other. A model of the formation of polymer layers has been proposed. The observed structural elements in polymer films are formed due to the association of macromolecules in the initial polymer solution. |
| Audience | Academic |
| Author | Nabiullin, I. R. Karamov, D. D. Kul’velis, Yu. V. Lachinov, A. N. Kornilov, V. M. |
| Author_xml | – sequence: 1 givenname: V. M. surname: Kornilov fullname: Kornilov, V. M. organization: Akmullah Bashkir State Pedagogical University – sequence: 2 givenname: A. N. surname: Lachinov fullname: Lachinov, A. N. organization: Akmullah Bashkir State Pedagogical University, Ufa Scientific Centre of the Russian Academy of Sciences – sequence: 3 givenname: D. D. surname: Karamov fullname: Karamov, D. D. email: karamov_danfis@bk.ru organization: Akmullah Bashkir State Pedagogical University, Ufa Scientific Centre of the Russian Academy of Sciences – sequence: 4 givenname: I. R. surname: Nabiullin fullname: Nabiullin, I. R. organization: Akmullah Bashkir State Pedagogical University – sequence: 5 givenname: Yu. V. surname: Kul’velis fullname: Kul’velis, Yu. V. organization: Konstantinov Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute,” |
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| Cites_doi | 10.1134/S0965545X08030024 10.1070/PU2006v049n12ABEH006176 10.1107/S0021889892001663 10.1016/0379-6779(94)90024-8 10.1021/la050263c 10.1016/j.progpolymsci.2008.08.001 10.1088/0034-4885/75/7/076502 |
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| Keywords | Resistive Switching Atomic Force Microscopy Investigation Atomic Force Microscopy Polymer Film Supramolecular Structure |
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| References | WuC. R.LachinovA.JohanssonN.StafströmS.KuglerT.RasmussonJ.SalaneckW. R.Synth. Met.19946712510.1016/0379-6779(94)90024-8 SvergunD. I.J. Appl. Crystallogr.19922549510.1107/S0021889892001663 SalazkinS. N.ShaposhnikovaV. V.MachulenkoL. N.GilevaN. G.KraikinV. A.LachinovA. N.Polym. Sci., Ser. A.200850324310.1134/S0965545X08030024 SvergunD. I.FeiginL. A.Structure Analysis by Small-Angle X-Ray and Neutron Scattering1987 JeongD. S.ThomasR.KatiyarR. S.ScottJ. F.KohlstedtH.PetraruA.HwangC. S.Rep. Prog. Phys.20127570765022012RPPh...75g6502J10.1088/0034-4885/75/7/076502 Gul’V. E.Structure and Strength of Polymers1978 TagerA. A.Physical Chemistry of Polymers2007 LachinovA. N.Vorob’evaN. V.Phys.—Usp.20064912122310.1070/PU2006v049n12ABEH006176 LingQ.-D.LiawD.-J.ZhuC.ChanD. S. H.KangE. T.NeohK. G.Prog. Polym. Sci.20083391710.1016/j.progpolymsci.2008.08.001 HubbardF. P.SantonicolaG.KalerE. W.AbbottN. L.Langmuir200521613110.1021/la050263c A. N. Lachinov (1824_CR3) 2006; 49 Q.-D. Ling (1824_CR2) 2008; 33 D. I. Svergun (1824_CR6) 1987 S. N. Salazkin (1824_CR4) 2008; 50 D. S. Jeong (1824_CR1) 2012; 75 C. R. Wu (1824_CR5) 1994; 67 F. P. Hubbard (1824_CR8) 2005; 21 D. I. Svergun (1824_CR7) 1992; 25 V. E. Gul (1824_CR9) 1978 A. A. Tager (1824_CR10) 2007 |
| References_xml | – reference: SvergunD. I.FeiginL. A.Structure Analysis by Small-Angle X-Ray and Neutron Scattering1987 – reference: SvergunD. I.J. Appl. Crystallogr.19922549510.1107/S0021889892001663 – reference: LachinovA. N.Vorob’evaN. V.Phys.—Usp.20064912122310.1070/PU2006v049n12ABEH006176 – reference: JeongD. S.ThomasR.KatiyarR. S.ScottJ. F.KohlstedtH.PetraruA.HwangC. S.Rep. Prog. Phys.20127570765022012RPPh...75g6502J10.1088/0034-4885/75/7/076502 – reference: Gul’V. E.Structure and Strength of Polymers1978 – reference: LingQ.-D.LiawD.-J.ZhuC.ChanD. S. H.KangE. T.NeohK. G.Prog. Polym. Sci.20083391710.1016/j.progpolymsci.2008.08.001 – reference: SalazkinS. N.ShaposhnikovaV. V.MachulenkoL. N.GilevaN. G.KraikinV. A.LachinovA. N.Polym. Sci., Ser. A.200850324310.1134/S0965545X08030024 – reference: HubbardF. P.SantonicolaG.KalerE. W.AbbottN. L.Langmuir200521613110.1021/la050263c – reference: TagerA. A.Physical Chemistry of Polymers2007 – reference: WuC. R.LachinovA.JohanssonN.StafströmS.KuglerT.RasmussonJ.SalaneckW. R.Synth. Met.19946712510.1016/0379-6779(94)90024-8 – volume: 50 start-page: 243 issue: 3 year: 2008 ident: 1824_CR4 publication-title: Polym. Sci., Ser. A. doi: 10.1134/S0965545X08030024 – volume: 49 start-page: 1223 issue: 12 year: 2006 ident: 1824_CR3 publication-title: Phys.—Usp. doi: 10.1070/PU2006v049n12ABEH006176 – volume: 25 start-page: 495 year: 1992 ident: 1824_CR7 publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889892001663 – volume: 67 start-page: 125 year: 1994 ident: 1824_CR5 publication-title: Synth. Met. doi: 10.1016/0379-6779(94)90024-8 – volume-title: Structure Analysis by Small-Angle X-Ray and Neutron Scattering year: 1987 ident: 1824_CR6 – volume: 21 start-page: 6131 year: 2005 ident: 1824_CR8 publication-title: Langmuir doi: 10.1021/la050263c – volume: 33 start-page: 917 year: 2008 ident: 1824_CR2 publication-title: Prog. Polym. Sci. doi: 10.1016/j.progpolymsci.2008.08.001 – volume: 75 start-page: 076502 issue: 7 year: 2012 ident: 1824_CR1 publication-title: Rep. Prog. Phys. doi: 10.1088/0034-4885/75/7/076502 – volume-title: Structure and Strength of Polymers year: 1978 ident: 1824_CR9 – volume-title: Physical Chemistry of Polymers year: 2007 ident: 1824_CR10 |
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| SubjectTerms | Analysis Atomic force microscopy Dielectric films Physics Physics and Astronomy Polymers Solid State Physics Thin films |
| Title | Supramolecular structure of electroactive polymer thin films |
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