Kinetics of glycerol effect on biodiesel production for optimal feeding of methanol

The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application for biodiesel production because of its high activity and stability. Enzyme deactivation caused by alcohol and effect of glycerol has to be re...

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Published inThe Korean journal of chemical engineering Vol. 28; no. 9; pp. 1908 - 1912
Main Authors Hong, Wan Pyo, Park, Jae Yeon, Min, Kyoungseon, Ko, Myung Joo, Park, Kyungmoon, Yoo, Young Je
Format Journal Article
LanguageEnglish
Published Boston Springer US 01.09.2011
한국화학공학회
Subjects
Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Materials Science
화학공학
Glycerol
Kinetic Model
Oil
Lipase
Enzyme
Biodiesel
Online AccessGet full text
ISSN0256-1115
1975-7220
DOI10.1007/s11814-011-0074-9

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Abstract The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application for biodiesel production because of its high activity and stability. Enzyme deactivation caused by alcohol and effect of glycerol has to be resolved for the industrial application of this process. In traditional kinetic studies of biodiesel production, the effects of alcohol and oil were only considered in the kinetic equation, while the effect by glycerol was neglected. A new kinetic model incorporating glycerol effect is proposed in this paper. The proposed kinetic equation is applied by predicting the supplying rate of methanol in a fed-batch addition of methanol. The conversion rate was improved from 59.7% to 94.6% in a fed-batch by considering glycerol effect.
AbstractList The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application for biodiesel production because of its high activity and stability. Enzyme deactivation caused by alcohol and effect of glycerol has to be resolved for the industrial application of this process. In traditional kinetic studies of biodiesel production, the effects of alcohol and oil were only considered in the kinetic equation, while the effect by glycerol was neglected. A new kinetic model incorporating glycerol effect is proposed in this paper. The proposed kinetic equation is applied by predicting the supplying rate of methanol in a fedbatch addition of methanol. The conversion rate was improved from 59.7% to 94.6% in a fed-batch by considering glycerol effect. KCI Citation Count: 11
The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application for biodiesel production because of its high activity and stability. Enzyme deactivation caused by alcohol and effect of glycerol has to be resolved for the industrial application of this process. In traditional kinetic studies of biodiesel production, the effects of alcohol and oil were only considered in the kinetic equation, while the effect by glycerol was neglected. A new kinetic model incorporating glycerol effect is proposed in this paper. The proposed kinetic equation is applied by predicting the supplying rate of methanol in a fed-batch addition of methanol. The conversion rate was improved from 59.7% to 94.6% in a fed-batch by considering glycerol effect.
Author Hong, Wan Pyo
Park, Kyungmoon
Yoo, Young Je
Min, Kyoungseon
Park, Jae Yeon
Ko, Myung Joo
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  givenname: Myung Joo
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  organization: Interdisciplinary Program of Bioengineering, Seoul National University, School of Chemical and Biological Engineering, Seoul National University
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Cites_doi 10.1016/0141-0229(95)00075-5
10.1016/S0141-0229(03)00090-5
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Keywords Glycerol
Kinetic Model
Oil
Lipase
Enzyme
Biodiesel
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Snippet The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application...
The enzymatic production of biodiesel has been considered as an eco-friendly process. Candida antarctica lipase B (CalB) has been studied for its application...
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SubjectTerms Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Materials Science
화학공학
Title Kinetics of glycerol effect on biodiesel production for optimal feeding of methanol
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