Liquid-liquid equilibrium data for water-ethanol-entrainer ternary system with entrainers: Cyclohexane, n-pentane, DEE (diethyl ether), DIPE (di-isopropyl ether), ETBE (ethyl tert-butyl ether)
The water-ethanol system was studied experimentally to find the liquid-liquid equilibrium (LLE) data at various temperature values by using five different entrainers: cyclohexane, n-pentane, DEE (diethyl ether), DIPE (diisopropyl ether), and ETBE (ethyl tert-butyl ether). Ternary LLE data for water-...
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| Published in | The Korean journal of chemical engineering Vol. 33; no. 7; pp. 2179 - 2185 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.07.2016
한국화학공학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0256-1115 1975-7220 |
| DOI | 10.1007/s11814-016-0066-x |
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| Abstract | The water-ethanol system was studied experimentally to find the liquid-liquid equilibrium (LLE) data at various temperature values by using five different entrainers: cyclohexane, n-pentane, DEE (diethyl ether), DIPE (diisopropyl ether), and ETBE (ethyl tert-butyl ether). Ternary LLE data for water-ethanol-entrainer system was determined based on an experimental procedure. Exact liquid activity coefficient parameters were found by experimental data and LLE data was predicted. For this purpose, two thermodynamic models, NRTL and UNIQUAC, were compared and contrasted with experimental data to probe into the better thermodynamic model for the azeotropic processes of ethanol system. The most promising entrainer was found through root mean square and average absolute deviations. |
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| AbstractList | The water-ethanol system was studied experimentally to find the liquid-liquid equilibrium (LLE) data at various temperature values by using five different entrainers: cyclohexane, n-pentane, DEE (diethyl ether), DIPE (diisopropyl ether), and ETBE (ethyl tert-butyl ether). Ternary LLE data for water-ethanol-entrainer system was determined based on an experimental procedure. Exact liquid activity coefficient parameters were found by experimental data and LLE data was predicted. For this purpose, two thermodynamic models, NRTL and UNIQUAC, were compared and contrasted with experimental data to probe into the better thermodynamic model for the azeotropic processes of ethanol system. The most promising entrainer was found through root mean square and average absolute deviations. The water-ethanol system was studied experimentally to find the liquid-liquid equilibrium (LLE) data at various temperature values by using five different entrainers: cyclohexane, n-pentane, DEE (diethyl ether), DIPE (diisopropyl ether), and ETBE (ethyl tert-butyl ether). Ternary LLE data for water-ethanol-entrainer system was determined based on an experimental procedure. Exact liquid activity coefficient parameters were found by experimental data and LLE data was predicted. For this purpose, two thermodynamic models, NRTL and UNIQUAC, were compared and contrasted with experimental data to probe into the better thermodynamic model for the azeotropic processes of ethanol system. The most promising entrainer was found through root mean square and average absolute deviations. KCI Citation Count: 3 |
| Author | Shin, Jae Sun Park, Sang Jin Choi, Hyeung Chul Qasim, Faraz |
| Author_xml | – sequence: 1 givenname: Faraz surname: Qasim fullname: Qasim, Faraz organization: Department of Chemical Engineering, Dongguk University – sequence: 2 givenname: Hyeung Chul surname: Choi fullname: Choi, Hyeung Chul organization: Daesung Industrial Gases Co., Ltd – sequence: 3 givenname: Jae Sun surname: Shin fullname: Shin, Jae Sun organization: Department of Chemical Engineering, Dongguk University – sequence: 4 givenname: Sang Jin surname: Park fullname: Park, Sang Jin email: sjpark@dongguk.edu organization: Department of Chemical Engineering, Dongguk University |
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| Keywords | UNIQUAC NRTL Root Mean Square Deviation Entrainer Liquid-liquid Equilibrium (LLE) Data Average Absolute Deviation |
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| Snippet | The water-ethanol system was studied experimentally to find the liquid-liquid equilibrium (LLE) data at various temperature values by using five different... |
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| Title | Liquid-liquid equilibrium data for water-ethanol-entrainer ternary system with entrainers: Cyclohexane, n-pentane, DEE (diethyl ether), DIPE (di-isopropyl ether), ETBE (ethyl tert-butyl ether) |
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