Solid–Liquid Metastable Equilibria for Solar Evaporation of Brines and Solubility Determination: A Critical Discussion
Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or...
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Published in | Journal of solution chemistry Vol. 48; no. 7; pp. 1009 - 1024 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
31.07.2019
Springer Nature B.V |
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Online Access | Get full text |
ISSN | 0095-9782 1572-8927 |
DOI | 10.1007/s10953-018-0794-0 |
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Abstract | Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities. |
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AbstractList | Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities. Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities. |
Author | Steiger, Michael Voigt, Wolfgang |
Author_xml | – sequence: 1 givenname: Michael orcidid: 0000-0002-7527-1097 surname: Steiger fullname: Steiger, Michael email: michael.steiger@chemie.uni-hamburg.de organization: Department of Chemistry, University of Hamburg – sequence: 2 givenname: Wolfgang surname: Voigt fullname: Voigt, Wolfgang organization: Department of Inorganic Chemistry, TU Bergakademie Freiberg |
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CitedBy_id | crossref_primary_10_1007_s13146_021_00687_9 crossref_primary_10_1016_j_fluid_2024_114171 crossref_primary_10_1515_pac_2020_0403 crossref_primary_10_1016_j_desal_2024_117816 crossref_primary_10_1007_s10953_019_00871_5 crossref_primary_10_1021_acs_jced_8b01263 crossref_primary_10_1016_j_ctta_2021_100008 |
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Keywords | Solubility diagram Solubility determination Solar evaporation diagram Metastable solubility Metastable equilibrium |
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SubjectTerms | Brines Chemistry Chemistry and Materials Science Condensed Matter Physics Crystallization Equilibrium Evaporation Geochemistry Industrial applications Industrial Chemistry/Chemical Engineering Inorganic Chemistry Metastable phases Oceanography Phase equilibria Physical Chemistry Solubility |
Title | Solid–Liquid Metastable Equilibria for Solar Evaporation of Brines and Solubility Determination: A Critical Discussion |
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