Solid–Liquid Metastable Equilibria for Solar Evaporation of Brines and Solubility Determination: A Critical Discussion

Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or...

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Published inJournal of solution chemistry Vol. 48; no. 7; pp. 1009 - 1024
Main Authors Steiger, Michael, Voigt, Wolfgang
Format Journal Article
LanguageEnglish
Published New York Springer US 31.07.2019
Springer Nature B.V
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Online AccessGet full text
ISSN0095-9782
1572-8927
DOI10.1007/s10953-018-0794-0

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Abstract Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities.
AbstractList Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities.
Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable solubilities’. The main objective of these studies was to carry out experiments under conditions closely meeting those in solar evaporation ponds or industrial evaporation–crystallization processes. Occasionally, such studies were subject to controversial discussion and criticism and the question was raised whether metastable equilibrium data are worth being published at all. This paper provides a critical discussion of such evaporation experiments. The thermodynamic background of stable and metastable solubility and typical experimental difficulties in solubility determinations are discussed in detail. We also demonstrate that the knowledge of metastable equilibria is very useful in different research areas such as geochemistry or industrial application of solubility equilibria. Finally, it is shown that so-called ‘isothermal evaporation method’ used in the above-mentioned studies does not yield stable or metastable solubilities.
Author Steiger, Michael
Voigt, Wolfgang
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  givenname: Wolfgang
  surname: Voigt
  fullname: Voigt, Wolfgang
  organization: Department of Inorganic Chemistry, TU Bergakademie Freiberg
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Issue 7
Keywords Solubility diagram
Solubility determination
Solar evaporation diagram
Metastable solubility
Metastable equilibrium
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Snippet Within the last two decades, a large number of articles were published that report, as the authors claim, ‘metastable phase equilibria’, or ‘metastable...
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springer
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StartPage 1009
SubjectTerms Brines
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Crystallization
Equilibrium
Evaporation
Geochemistry
Industrial applications
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Metastable phases
Oceanography
Phase equilibria
Physical Chemistry
Solubility
Title Solid–Liquid Metastable Equilibria for Solar Evaporation of Brines and Solubility Determination: A Critical Discussion
URI https://link.springer.com/article/10.1007/s10953-018-0794-0
https://www.proquest.com/docview/2268172596
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