Incorporation of Cu() and its selective reduction to Cu() within confined spaces: efficient active sites for CO adsorption
Cu( i )-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu( i ) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to...
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| Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 6; no. 19; pp. 893 - 8939 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
2018
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2050-7488 2050-7496 2050-7496 |
| DOI | 10.1039/c8ta01805g |
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| Abstract | Cu(
i
)-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu(
i
) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to fabricate Cu(
i
) sites in a representative metal-organic framework, MIL-101(Cr); this strategy ensures that both introduction of the Cu(
ii
) precursor and its reduction to Cu(
i
) occur inside the pores and significantly minimizes the aggregation of Cu species. This is difficult to realize through conventional methods used for Cu(
ii
) introduction (wet impregnation) or reduction (liquid-phase reduction). The two-step DS strategy involves selective reduction of Cu(
ii
) to form Cu(
i
) without the formation of any Cu(0). The obtained Cu(
i
)-containing materials exhibit an excellent CO adsorption capacity (up to 2.42 mmol g
−1
) at 298 K and 1 bar, much better than that of the benchmark adsorbents including CuCl/γ-Al
2
O
3
(1.0 mmol g
−1
), CuCl/MCM-41 (0.57 mmol g
−1
), and CuZSM-5 (0.11 mmol g
−1
).
A two-step double-solvent strategy was first used to incorporate Cu(
i
) sites into MIL-101(Cr), which obviously improves the CO adsorption performance. |
|---|---|
| AbstractList | Cu(i)-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu(i) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to fabricate Cu(i) sites in a representative metal–organic framework, MIL-101(Cr); this strategy ensures that both introduction of the Cu(ii) precursor and its reduction to Cu(i) occur inside the pores and significantly minimizes the aggregation of Cu species. This is difficult to realize through conventional methods used for Cu(ii) introduction (wet impregnation) or reduction (liquid-phase reduction). The two-step DS strategy involves selective reduction of Cu(ii) to form Cu(i) without the formation of any Cu(0). The obtained Cu(i)-containing materials exhibit an excellent CO adsorption capacity (up to 2.42 mmol g−1) at 298 K and 1 bar, much better than that of the benchmark adsorbents including CuCl/γ-Al2O3 (1.0 mmol g−1), CuCl/MCM-41 (0.57 mmol g−1), and CuZSM-5 (0.11 mmol g−1). Cu( i )-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu( i ) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to fabricate Cu( i ) sites in a representative metal-organic framework, MIL-101(Cr); this strategy ensures that both introduction of the Cu( ii ) precursor and its reduction to Cu( i ) occur inside the pores and significantly minimizes the aggregation of Cu species. This is difficult to realize through conventional methods used for Cu( ii ) introduction (wet impregnation) or reduction (liquid-phase reduction). The two-step DS strategy involves selective reduction of Cu( ii ) to form Cu( i ) without the formation of any Cu(0). The obtained Cu( i )-containing materials exhibit an excellent CO adsorption capacity (up to 2.42 mmol g −1 ) at 298 K and 1 bar, much better than that of the benchmark adsorbents including CuCl/γ-Al 2 O 3 (1.0 mmol g −1 ), CuCl/MCM-41 (0.57 mmol g −1 ), and CuZSM-5 (0.11 mmol g −1 ). A two-step double-solvent strategy was first used to incorporate Cu( i ) sites into MIL-101(Cr), which obviously improves the CO adsorption performance. Cu( i )-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu( i ) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to fabricate Cu( i ) sites in a representative metal–organic framework, MIL-101(Cr); this strategy ensures that both introduction of the Cu( ii ) precursor and its reduction to Cu( i ) occur inside the pores and significantly minimizes the aggregation of Cu species. This is difficult to realize through conventional methods used for Cu( ii ) introduction (wet impregnation) or reduction (liquid-phase reduction). The two-step DS strategy involves selective reduction of Cu( ii ) to form Cu( i ) without the formation of any Cu(0). The obtained Cu( i )-containing materials exhibit an excellent CO adsorption capacity (up to 2.42 mmol g −1 ) at 298 K and 1 bar, much better than that of the benchmark adsorbents including CuCl/γ-Al 2 O 3 (1.0 mmol g −1 ), CuCl/MCM-41 (0.57 mmol g −1 ), and CuZSM-5 (0.11 mmol g −1 ). Cu(i)-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method to produce Cu(i) sites remains a significant challenge; herein, a two-step double-solvent (DS) strategy is reported for the first time to fabricate Cu(i) sites in a representative metal–organic framework, MIL-101(Cr); this strategy ensures that both introduction of the Cu(ii) precursor and its reduction to Cu(i) occur inside the pores and significantly minimizes the aggregation of Cu species. This is difficult to realize through conventional methods used for Cu(ii) introduction (wet impregnation) or reduction (liquid-phase reduction). The two-step DS strategy involves selective reduction of Cu(ii) to form Cu(i) without the formation of any Cu(0). The obtained Cu(i)-containing materials exhibit an excellent CO adsorption capacity (up to 2.42 mmol g⁻¹) at 298 K and 1 bar, much better than that of the benchmark adsorbents including CuCl/γ-Al₂O₃ (1.0 mmol g⁻¹), CuCl/MCM-41 (0.57 mmol g⁻¹), and CuZSM-5 (0.11 mmol g⁻¹). |
| Author | Li, Yu-Xia Sun, Lin-Bing Xue, Ding-Ming Jin, Meng-Meng Li, Shuai-Shuai Liu, Xiao-Qin |
| AuthorAffiliation | College of Chemical Engineering Nanjing Tech University Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) State Key Laboratory of Materials-Oriented Chemical Engineering |
| AuthorAffiliation_xml | – sequence: 0 name: Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) – sequence: 0 name: Nanjing Tech University – sequence: 0 name: College of Chemical Engineering – sequence: 0 name: State Key Laboratory of Materials-Oriented Chemical Engineering |
| Author_xml | – sequence: 1 givenname: Yu-Xia surname: Li fullname: Li, Yu-Xia – sequence: 2 givenname: Shuai-Shuai surname: Li fullname: Li, Shuai-Shuai – sequence: 3 givenname: Ding-Ming surname: Xue fullname: Xue, Ding-Ming – sequence: 4 givenname: Xiao-Qin surname: Liu fullname: Liu, Xiao-Qin – sequence: 5 givenname: Meng-Meng surname: Jin fullname: Jin, Meng-Meng – sequence: 6 givenname: Lin-Bing surname: Sun fullname: Sun, Lin-Bing |
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| Snippet | Cu(
i
)-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable... Cu(i)-containing materials have great potential in various applications such as in CO adsorption; however, development of an efficient and controllable method... |
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| SubjectTerms | active sites adsorbents Adsorption Aluminum oxide Chromium Confined spaces coordination polymers Copper Copper chloride Reduction Strategy |
| Title | Incorporation of Cu() and its selective reduction to Cu() within confined spaces: efficient active sites for CO adsorption |
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