Dynamics of stainless steel corrosion based on the theory of phase space reconstruction and chaos

• Published in: Anti-corrosion methods and materials Vol. 63; no. 3; pp. 214 - 225
• Main Authors: Men, Hong, Sun, Bin, Zhao, Xiao, Li, Xiujie, Liu, Jingjing, Xu, Zhiming
• Format: Journal Article
• Language: English
• Published: Bradford Emerald Group Publishing Limited 01.01.2016
• Subjects: Approximation; Aqueous solutions; Chaos theory; Corrosion; Corrosion rate; Corrosion resistance; Decomposition; Dynamics; Electrochemical noise; Electrochemical potential; Electrochemistry; Electrodes; Electrolytes; Liapunov exponents; Methods; Microscopy; Noise; Reconstruction; Sodium chloride; Sodium hydroxide; Spectrum analysis; Stainless steel; Standard deviation; Sulfuric acid; Sulphuric acid; Time domain analysis; Work stations; Electrochemical noise; Time domain analysis; Phase space reconstruction; Chaos theory; Stainless steel
• ISSN: 0003-5599; 1758-4221
• DOI: 10.1108/ACMM-11-2015-1613

Purpose The purpose of this study is to analyze the corrosion behavior of 304SS in three kinds of solution, 3.5 per cent NaCl, 5 per cent H2SO4 and 1 M (1 mol/L) NaOH, using electrochemical noise. Design/methodology/approach Corrosion types and rates were characterized by spectrum and time-domain analysis. EN signals were evaluated using a novel method of phase space reconstruction and chaos theory. To evaluate the chaotic characteristics of corrosion systems, the delay time was obtained by the mutual information method and the embedding dimension was obtained by the average false neighbors method. Findings The varying degrees of chaos in the corrosion systems were indicated by positive largest Lyapunov exponents of the electrochemical potential noise. Originality/value The change of correlation dimension in three kinds of solution demonstrated significant differences, clearly differentiating various types of corrosion.