Thiourea-Immobilized Polymer Beads for Sorption of Cr(VI) Ions in Acidic Aqueous Media

Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized polystyrene beads containing immobilized thiourea (mTA-PS) were prepared through suspension polymerization and two successive chemical modificatio...

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Published inMacromolecular research Vol. 27; no. 5; pp. 515 - 521
Main Authors Bhattarai, Saurabha, Kim, Jong Soo, Yun, Yeoung-Sang, Lee, Youn-Sik
Format Journal Article
LanguageEnglish
Published Seoul The Polymer Society of Korea 01.05.2019
Springer Nature B.V
한국고분자학회
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ISSN1598-5032
2092-7673
DOI10.1007/s13233-019-7139-8

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Abstract Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized polystyrene beads containing immobilized thiourea (mTA-PS) were prepared through suspension polymerization and two successive chemical modifications. The sorbent was stable even at pH of 0 under room temperature. The effects of pH, contact time, and initial concentration on sorption of Cr(VI) anions were studied. The isotherm data was fitted to the Freundlich model accordingly. The Langmuir model predicted the sorbent to have a maximum sorption capacity of 137 mg g −1 at pH 1. The sorbent exhibited a significant selective sorption of Cr(VI) ions over trivalent chromium (Cr(III)) ions. These results show that such polymer sorbent can be utilized to remove Cr(VI) ions from a highly acidic aqueous media.
AbstractList Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized polystyrene beads containing immobilized thiourea (mTA-PS) were prepared through suspension polymerization and two successive chemical modifications. The sorbent was stable even at pH of 0 under room temperature. The effects of pH, contact time, and initial concentration on sorption of Cr(VI) anions were studied. The isotherm data was fitted to the Freundlich model accordingly. The Langmuir model predicted the sorbent to have a maximum sorption capacity of 137 mg g −1 at pH 1. The sorbent exhibited a significant selective sorption of Cr(VI) ions over trivalent chromium (Cr(III)) ions. These results show that such polymer sorbent can be utilized to remove Cr(VI) ions from a highly acidic aqueous media.
Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized polystyrene beads containing immobilized thiourea (mTA-PS) were prepared through suspension polymerization and two successive chemical modifications. The sorbent was stable even at pH of 0 under room temperature. The effects of pH, contact time, and initial concentration on sorption of Cr(VI) anions were studied. The isotherm data was fitted to the Freundlich model accordingly. The Langmuir model predicted the sorbent to have a maximum sorption capacity of 137 mg g-1 at pH 1. The sorbent exhibited a significant selective sorption of Cr(VI) ions over trivalent chromium (Cr(III)) ions. These results show that such polymer sorbent can be utilized to remove Cr(VI) ions from a highly acidic aqueous media. KCI Citation Count: 5
Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized polystyrene beads containing immobilized thiourea (mTA-PS) were prepared through suspension polymerization and two successive chemical modifications. The sorbent was stable even at pH of 0 under room temperature. The effects of pH, contact time, and initial concentration on sorption of Cr(VI) anions were studied. The isotherm data was fitted to the Freundlich model accordingly. The Langmuir model predicted the sorbent to have a maximum sorption capacity of 137 mg g−1 at pH 1. The sorbent exhibited a significant selective sorption of Cr(VI) ions over trivalent chromium (Cr(III)) ions. These results show that such polymer sorbent can be utilized to remove Cr(VI) ions from a highly acidic aqueous media.
Author Yun, Yeoung-Sang
Kim, Jong Soo
Lee, Youn-Sik
Bhattarai, Saurabha
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  fullname: Kim, Jong Soo
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Keywords thiourea-immobilized polymer bead
suspension polymerization
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chromium ion
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Snippet Polymer sorbents used for the removal of hexavalent chromium (Cr(VI)) ions from highly acidic aqueous media (pH≤1) are needed. In this study, micronsized...
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SubjectTerms Aqueous solutions
Beads
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Chromium
Complex Fluids and Microfluidics
Hexavalent chromium
Nanochemistry
Nanotechnology
Organic chemistry
Physical Chemistry
Polymer Sciences
Polymers
Polystyrene resins
Soft and Granular Matter
Sorbents
Sorption
Suspension polymerization
Thioureas
Trivalent chromium
고분자공학
Title Thiourea-Immobilized Polymer Beads for Sorption of Cr(VI) Ions in Acidic Aqueous Media
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