Electrochemical characteristics of semi conductive silicon anode for lithium polymer batteries
In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type sili...
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Published in | Journal of electroceramics Vol. 24; no. 4; pp. 308 - 312 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Boston
Springer US
01.06.2010
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
ISSN | 1385-3449 1573-8663 |
DOI | 10.1007/s10832-009-9573-z |
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Abstract | In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type silicon electrode shows the most stable cyclic performance after the 40
th
cycle and still maintains a reversible specific capacity of about 2,500 mAh/g. The enhanced electrochemical performance of the doped silicon anode was attributed to the enhancement of its electrical conductivity, which was further confirmed by impedance spectroscopy and surface analysis by XPS. |
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AbstractList | In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type silicon electrode shows the most stable cyclic performance after the 40 super(th) cycle and still maintains a reversible specific capacity of about 2,500 mAh/g. The enhanced electrochemical performance of the doped silicon anode was attributed to the enhancement of its electrical conductivity, which was further confirmed by impedance spectroscopy and surface analysis by XPS. In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type silicon electrode shows the most stable cyclic performance after the 40 th cycle and still maintains a reversible specific capacity of about 2,500 mAh/g. The enhanced electrochemical performance of the doped silicon anode was attributed to the enhancement of its electrical conductivity, which was further confirmed by impedance spectroscopy and surface analysis by XPS. In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type silicon electrode shows the most stable cyclic performance after the 40^sup th^ cycle and still maintains a reversible specific capacity of about 2,500 mAh/g. The enhanced electrochemical performance of the doped silicon anode was attributed to the enhancement of its electrical conductivity, which was further confirmed by impedance spectroscopy and surface analysis by XPS.[PUBLICATION ABSTRACT] |
Author | Kee Lee, Joong Chang, Wonyoung Andreas Arie, Arenst |
Author_xml | – sequence: 1 givenname: Arenst surname: Andreas Arie fullname: Andreas Arie, Arenst organization: Advanced Energy Materials Processing Laboratory, Battery Research Center, Korea Institute of Science and Technology, Energy Conversion Technology Division, University of Science and Technology – sequence: 2 givenname: Wonyoung surname: Chang fullname: Chang, Wonyoung organization: Advanced Energy Materials Processing Laboratory, Battery Research Center, Korea Institute of Science and Technology – sequence: 3 givenname: Joong surname: Kee Lee fullname: Kee Lee, Joong email: leejk@kist.re.kr organization: Advanced Energy Materials Processing Laboratory, Battery Research Center, Korea Institute of Science and Technology |
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Cites_doi | 10.1016/S0378-7753(98)00211-0 10.1016/S0378-7753(01)00887-4 10.1016/j.jpowsour.2004.03.014 10.1038/35104644 10.1016/S0013-4686(02)00317-1 10.1016/j.jpowsour.2005.03.110 10.1016/j.jpowsour.2005.03.097 10.1016/j.jpowsour.2003.09.003 10.1016/S0378-7753(99)00529-7 10.1016/S0167-2738(98)00557-8 |
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Keywords | Thin films Semi conductive Lithium polymer battery Impedance |
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SubjectTerms | Anodes Batteries Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Crystallography and Scattering Methods Electric batteries Electrochemistry Electrodes Glass Lithium Materials Science Natural Materials Optical and Electronic Materials Semifabricated products Silicon X-ray photoelectron spectroscopy |
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