Cage-like metallasilsesquioxanes in catalysis: A review
The review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field—from well-known applications of such catalysts to recent discovery of their activity in CH compounds’ functionalization. [Display omitted] •Cage metallasilsesquioxanes as uniq...
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| Published in | Journal of molecular catalysis. A, Chemical Vol. 426; pp. 297 - 304 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1381-1169 1873-314X |
| DOI | 10.1016/j.molcata.2016.06.016 |
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| Abstract | The review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field—from well-known applications of such catalysts to recent discovery of their activity in CH compounds’ functionalization.
[Display omitted]
•Cage metallasilsesquioxanes as unique structured catalysts.•Calcination of metallasilsesquioxanes as an approach to active inorganic catalysts.•Cage metallasilsesquioxanes in effective functionalization of CH compounds.
The review describes catalytic properties of a unique class of metal complexes—polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С–H compounds. |
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| AbstractList | The review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field—from well-known applications of such catalysts to recent discovery of their activity in CH compounds’ functionalization.
[Display omitted]
•Cage metallasilsesquioxanes as unique structured catalysts.•Calcination of metallasilsesquioxanes as an approach to active inorganic catalysts.•Cage metallasilsesquioxanes in effective functionalization of CH compounds.
The review describes catalytic properties of a unique class of metal complexes—polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С–H compounds. |
| Author | Yalymov, Alexey I. Kulakova, Alena N. Bilyachenko, Аlexey N. Levitsky, Mikhail M. Petrov, Аrtem А. |
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| Keywords | С–H compound functionalization Oxidation Peroxides Catalysis Cage metallasilsesquioxanes |
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| Snippet | The review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field—from well-known applications of... |
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| SubjectTerms | Cage metallasilsesquioxanes Catalysis Oxidation Peroxides С–H compound functionalization |
| Title | Cage-like metallasilsesquioxanes in catalysis: A review |
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