Regulating of MnO2 photocatalytic activity in degradation of organic dyes by polymorphic engineering

Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized b...

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Published inSolid state sciences Vol. 132; p. 106997
Main Authors Belousov, Artem S., Suleimanov, Evgeny V., Parkhacheva, Alina A., Fukina, Diana G., Koryagin, Andrey V., Koroleva, Aleksandra V., Zhizhin, Evgeny V., Gorshkov, Alexey P.
Format Journal Article
LanguageEnglish
Published Elsevier Masson SAS 01.10.2022
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Online AccessGet full text
ISSN1293-2558
1873-3085
DOI10.1016/j.solidstatesciences.2022.106997

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Abstract Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and low-temperature nitrogen adsorption-desorption techniques. It was shown that the highest efficiency was achieved in the degradation of cationic methylene in the presence of the δ-MnO2 photocatalyst (conversion of methylene blue was 90.4% after 180 min). These results are explained by unique physicochemical properties of the δ-MnO2 polymorph. It was observed that there is a synergetic effect between various physicochemical properties of δ-MnO2 which allows to obtain the high photodegradation efficiency: high adsorption ability towards methylene blue, unique 2D morphology, lower Mn–O bond strength, and high surface Mn4+/Mn3+ molar ratio. The reaction mechanism as well as the main products of the methylene blue photooxidation process over δ-MnO2 were also investigated. [Display omitted] •The highest photodegradation rates in the presence of MnO2 were observed when methylene blue was used as amodel dye.•All the prepared polymorphs are characterized by a low adsorption capacity towards methyl orange and low photocatalytic activity.•The photoconversion of methylene blue after 180 min decreased in the following order: δ-MnO2 > α-MnO2 > γ-MnO2 > β-MnO2.•The excellent photocatalytic performance of δ-MnO2 is explained by a synergetic effect between physicochemical properties.
AbstractList Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and low-temperature nitrogen adsorption-desorption techniques. It was shown that the highest efficiency was achieved in the degradation of cationic methylene in the presence of the δ-MnO2 photocatalyst (conversion of methylene blue was 90.4% after 180 min). These results are explained by unique physicochemical properties of the δ-MnO2 polymorph. It was observed that there is a synergetic effect between various physicochemical properties of δ-MnO2 which allows to obtain the high photodegradation efficiency: high adsorption ability towards methylene blue, unique 2D morphology, lower Mn–O bond strength, and high surface Mn4+/Mn3+ molar ratio. The reaction mechanism as well as the main products of the methylene blue photooxidation process over δ-MnO2 were also investigated. [Display omitted] •The highest photodegradation rates in the presence of MnO2 were observed when methylene blue was used as amodel dye.•All the prepared polymorphs are characterized by a low adsorption capacity towards methyl orange and low photocatalytic activity.•The photoconversion of methylene blue after 180 min decreased in the following order: δ-MnO2 > α-MnO2 > γ-MnO2 > β-MnO2.•The excellent photocatalytic performance of δ-MnO2 is explained by a synergetic effect between physicochemical properties.
ArticleNumber 106997
Author Belousov, Artem S.
Suleimanov, Evgeny V.
Gorshkov, Alexey P.
Fukina, Diana G.
Parkhacheva, Alina A.
Zhizhin, Evgeny V.
Koryagin, Andrey V.
Koroleva, Aleksandra V.
Author_xml – sequence: 1
  givenname: Artem S.
  orcidid: 0000-0001-6411-9762
  surname: Belousov
  fullname: Belousov, Artem S.
  email: belousov@ichem.unn.ru
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
– sequence: 2
  givenname: Evgeny V.
  surname: Suleimanov
  fullname: Suleimanov, Evgeny V.
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
– sequence: 3
  givenname: Alina A.
  surname: Parkhacheva
  fullname: Parkhacheva, Alina A.
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
– sequence: 4
  givenname: Diana G.
  surname: Fukina
  fullname: Fukina, Diana G.
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
– sequence: 5
  givenname: Andrey V.
  orcidid: 0000-0002-4858-3351
  surname: Koryagin
  fullname: Koryagin, Andrey V.
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
– sequence: 6
  givenname: Aleksandra V.
  surname: Koroleva
  fullname: Koroleva, Aleksandra V.
  organization: Saint-Petersburg State University, Universitetskaya Nab. 7–9, Saint-Petersburg, 199034, Russian Federation
– sequence: 7
  givenname: Evgeny V.
  surname: Zhizhin
  fullname: Zhizhin, Evgeny V.
  organization: Saint-Petersburg State University, Universitetskaya Nab. 7–9, Saint-Petersburg, 199034, Russian Federation
– sequence: 8
  givenname: Alexey P.
  surname: Gorshkov
  fullname: Gorshkov, Alexey P.
  organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation
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Keywords Manganese dioxide
Visible light
Dye degradation
Polymorphs
Photocatalyst
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Snippet Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the...
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StartPage 106997
SubjectTerms Dye degradation
Manganese dioxide
Photocatalyst
Polymorphs
Visible light
Title Regulating of MnO2 photocatalytic activity in degradation of organic dyes by polymorphic engineering
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