Regulating of MnO2 photocatalytic activity in degradation of organic dyes by polymorphic engineering
Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized b...
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| Published in | Solid state sciences Vol. 132; p. 106997 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Masson SAS
01.10.2022
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1293-2558 1873-3085 |
| DOI | 10.1016/j.solidstatesciences.2022.106997 |
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| Abstract | Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and low-temperature nitrogen adsorption-desorption techniques. It was shown that the highest efficiency was achieved in the degradation of cationic methylene in the presence of the δ-MnO2 photocatalyst (conversion of methylene blue was 90.4% after 180 min). These results are explained by unique physicochemical properties of the δ-MnO2 polymorph. It was observed that there is a synergetic effect between various physicochemical properties of δ-MnO2 which allows to obtain the high photodegradation efficiency: high adsorption ability towards methylene blue, unique 2D morphology, lower Mn–O bond strength, and high surface Mn4+/Mn3+ molar ratio. The reaction mechanism as well as the main products of the methylene blue photooxidation process over δ-MnO2 were also investigated.
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•The highest photodegradation rates in the presence of MnO2 were observed when methylene blue was used as amodel dye.•All the prepared polymorphs are characterized by a low adsorption capacity towards methyl orange and low photocatalytic activity.•The photoconversion of methylene blue after 180 min decreased in the following order: δ-MnO2 > α-MnO2 > γ-MnO2 > β-MnO2.•The excellent photocatalytic performance of δ-MnO2 is explained by a synergetic effect between physicochemical properties. |
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| AbstractList | Different phase nanostructured MnO2, including α-, β-, γ-, and δ-MnO2, were prepared by a hydrothermal route. Their photocatalytic activities in the degradation of cationic (methylene blue) and anionic (methyl orange) dyes were compared for the first time. The as-prepared oxides were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and low-temperature nitrogen adsorption-desorption techniques. It was shown that the highest efficiency was achieved in the degradation of cationic methylene in the presence of the δ-MnO2 photocatalyst (conversion of methylene blue was 90.4% after 180 min). These results are explained by unique physicochemical properties of the δ-MnO2 polymorph. It was observed that there is a synergetic effect between various physicochemical properties of δ-MnO2 which allows to obtain the high photodegradation efficiency: high adsorption ability towards methylene blue, unique 2D morphology, lower Mn–O bond strength, and high surface Mn4+/Mn3+ molar ratio. The reaction mechanism as well as the main products of the methylene blue photooxidation process over δ-MnO2 were also investigated.
[Display omitted]
•The highest photodegradation rates in the presence of MnO2 were observed when methylene blue was used as amodel dye.•All the prepared polymorphs are characterized by a low adsorption capacity towards methyl orange and low photocatalytic activity.•The photoconversion of methylene blue after 180 min decreased in the following order: δ-MnO2 > α-MnO2 > γ-MnO2 > β-MnO2.•The excellent photocatalytic performance of δ-MnO2 is explained by a synergetic effect between physicochemical properties. |
| ArticleNumber | 106997 |
| Author | Belousov, Artem S. Suleimanov, Evgeny V. Gorshkov, Alexey P. Fukina, Diana G. Parkhacheva, Alina A. Zhizhin, Evgeny V. Koryagin, Andrey V. Koroleva, Aleksandra V. |
| Author_xml | – sequence: 1 givenname: Artem S. orcidid: 0000-0001-6411-9762 surname: Belousov fullname: Belousov, Artem S. email: belousov@ichem.unn.ru organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation – sequence: 2 givenname: Evgeny V. surname: Suleimanov fullname: Suleimanov, Evgeny V. organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation – sequence: 3 givenname: Alina A. surname: Parkhacheva fullname: Parkhacheva, Alina A. organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation – sequence: 4 givenname: Diana G. surname: Fukina fullname: Fukina, Diana G. organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation – sequence: 5 givenname: Andrey V. orcidid: 0000-0002-4858-3351 surname: Koryagin fullname: Koryagin, Andrey V. organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation – sequence: 6 givenname: Aleksandra V. surname: Koroleva fullname: Koroleva, Aleksandra V. organization: Saint-Petersburg State University, Universitetskaya Nab. 7–9, Saint-Petersburg, 199034, Russian Federation – sequence: 7 givenname: Evgeny V. surname: Zhizhin fullname: Zhizhin, Evgeny V. organization: Saint-Petersburg State University, Universitetskaya Nab. 7–9, Saint-Petersburg, 199034, Russian Federation – sequence: 8 givenname: Alexey P. surname: Gorshkov fullname: Gorshkov, Alexey P. organization: Lobachevsky State University of Nizhny Novgorod, Gagarin Avenue 23, Nizhny Novgorod, 603950, Russian Federation |
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| Keywords | Manganese dioxide Visible light Dye degradation Polymorphs Photocatalyst |
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| SubjectTerms | Dye degradation Manganese dioxide Photocatalyst Polymorphs Visible light |
| Title | Regulating of MnO2 photocatalytic activity in degradation of organic dyes by polymorphic engineering |
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