A study on self-shielding effect of CaCO3 in cable pyrolysis using gas product analysis and PSO optimization

This paper investigates the self-shielding mechanism of CaCO3 during the pyrolysis of PVC-CaCO3 based cable. Previous studies have focused on HCl adsorption by CaCO3, neglecting the self-shielding effect. In this paper, thermogravimetric-infrared analyzer, pyrolysis gas chromatography-mass spectrome...

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Published inFire safety journal Vol. 140; p. 103917
Main Authors Li, Kaiyuan, Li, Yaoqiang, Jiang, Yaqiang, Zou, Yanyan, Wu, Xujuan, Yang, Yunpeng
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.10.2023
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ISSN0379-7112
DOI10.1016/j.firesaf.2023.103917

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Abstract This paper investigates the self-shielding mechanism of CaCO3 during the pyrolysis of PVC-CaCO3 based cable. Previous studies have focused on HCl adsorption by CaCO3, neglecting the self-shielding effect. In this paper, thermogravimetric-infrared analyzer, pyrolysis gas chromatography-mass spectrometer and particle swarm optimization (PSO) algorithm are used to investigate the self-shielding mechanism. The results show a three-stage pyrolysis process. In the first stage, CaCO3 weakens the autocatalytic decomposition of PVC by absorbing HCl in the solid phase. The 3rd Avrami Erofeev model was obtained by PSO, representing the production of CaCl2 crystals. The second stage demonstrates self-shielding due to a reduction in solid-phase porosity. CaCO3 encapsulation inhibits the pyrolysis of PVC resulting in macromolecular intermediates. The 3rd order-based model was obtained by PSO, with a lower pyrolysis reaction rate compared to pure PVC. In the third stage, the stability of Cl in the solid phase is weakened at high temperatures, which converts the Cl to the gas phase in the form of chlorinated hydrocarbons, leading to the failure of self-shielding effect of CaCO3. The 2nd order-based model was obtained by PSO, which is considered as a result of the solid phase reactions instead of pyrolysis. •CaCO3 leads to the self-shielding effect for PVC pyrolysis.•Self-shielding effect of CaCO3 hinders the solid phase degradation of PVC.•Solid Cl can be converted into gas phase owing to self-shielding effect failure.
AbstractList This paper investigates the self-shielding mechanism of CaCO3 during the pyrolysis of PVC-CaCO3 based cable. Previous studies have focused on HCl adsorption by CaCO3, neglecting the self-shielding effect. In this paper, thermogravimetric-infrared analyzer, pyrolysis gas chromatography-mass spectrometer and particle swarm optimization (PSO) algorithm are used to investigate the self-shielding mechanism. The results show a three-stage pyrolysis process. In the first stage, CaCO3 weakens the autocatalytic decomposition of PVC by absorbing HCl in the solid phase. The 3rd Avrami Erofeev model was obtained by PSO, representing the production of CaCl2 crystals. The second stage demonstrates self-shielding due to a reduction in solid-phase porosity. CaCO3 encapsulation inhibits the pyrolysis of PVC resulting in macromolecular intermediates. The 3rd order-based model was obtained by PSO, with a lower pyrolysis reaction rate compared to pure PVC. In the third stage, the stability of Cl in the solid phase is weakened at high temperatures, which converts the Cl to the gas phase in the form of chlorinated hydrocarbons, leading to the failure of self-shielding effect of CaCO3. The 2nd order-based model was obtained by PSO, which is considered as a result of the solid phase reactions instead of pyrolysis. •CaCO3 leads to the self-shielding effect for PVC pyrolysis.•Self-shielding effect of CaCO3 hinders the solid phase degradation of PVC.•Solid Cl can be converted into gas phase owing to self-shielding effect failure.
This paper investigates the self-shielding mechanism of CaCO₃ during the pyrolysis of PVC-CaCO₃ based cable. Previous studies have focused on HCl adsorption by CaCO₃, neglecting the self-shielding effect. In this paper, thermogravimetric-infrared analyzer, pyrolysis gas chromatography-mass spectrometer and particle swarm optimization (PSO) algorithm are used to investigate the self-shielding mechanism. The results show a three-stage pyrolysis process. In the first stage, CaCO₃ weakens the autocatalytic decomposition of PVC by absorbing HCl in the solid phase. The 3rd Avrami Erofeev model was obtained by PSO, representing the production of CaCl₂ crystals. The second stage demonstrates self-shielding due to a reduction in solid-phase porosity. CaCO₃ encapsulation inhibits the pyrolysis of PVC resulting in macromolecular intermediates. The 3rd order-based model was obtained by PSO, with a lower pyrolysis reaction rate compared to pure PVC. In the third stage, the stability of Cl in the solid phase is weakened at high temperatures, which converts the Cl to the gas phase in the form of chlorinated hydrocarbons, leading to the failure of self-shielding effect of CaCO₃. The 2nd order-based model was obtained by PSO, which is considered as a result of the solid phase reactions instead of pyrolysis.
ArticleNumber 103917
Author Yang, Yunpeng
Wu, Xujuan
Li, Yaoqiang
Li, Kaiyuan
Jiang, Yaqiang
Zou, Yanyan
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Keywords PVC-CaCO3 cable
Py-GC/MS
Kinetic parameters
Outer sheath
PSO
Self-shielding effect
TG-FTIR
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Snippet This paper investigates the self-shielding mechanism of CaCO3 during the pyrolysis of PVC-CaCO3 based cable. Previous studies have focused on HCl adsorption by...
This paper investigates the self-shielding mechanism of CaCO₃ during the pyrolysis of PVC-CaCO₃ based cable. Previous studies have focused on HCl adsorption by...
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StartPage 103917
SubjectTerms adsorption
algorithms
encapsulation
fire safety
gas chromatography
Kinetic parameters
Outer sheath
porosity
PSO
PVC-CaCO3 cable
Py-GC/MS
pyrolysis
Self-shielding effect
spectrometers
TG-FTIR
Title A study on self-shielding effect of CaCO3 in cable pyrolysis using gas product analysis and PSO optimization
URI https://dx.doi.org/10.1016/j.firesaf.2023.103917
https://www.proquest.com/docview/3242079202
Volume 140
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