Modeling and simulation of a continuous biomass hydrothermal carbonization process
This work evaluates a continuous biomass hydrothermal carbonization process through modeling and steady state simulation using the UniSim Design process simulator. The reactive process was divided into four stages: biomass hydrolysis, intermediate compounds degradation, aromatics formation, and poly...
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| Published in | Chemical engineering communications Vol. 207; no. 6; pp. 751 - 768 |
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| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Philadelphia
Taylor & Francis
02.06.2020
Taylor & Francis Ltd |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0098-6445 1563-5201 |
| DOI | 10.1080/00986445.2019.1621858 |
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| Abstract | This work evaluates a continuous biomass hydrothermal carbonization process through modeling and steady state simulation using the UniSim Design process simulator. The reactive process was divided into four stages: biomass hydrolysis, intermediate compounds degradation, aromatics formation, and polymerization process, which make it possible to obtain the solid product or hydrochar. Pure biomass types and their mixtures were compared, considering hydrochar and carbon yields, H/C, and O/C ratios, and their deviation from the batch process. The results of hydrochar yield indicated that biomass with high cellulose content can perform satisfactorily in the proposed model. In addition, the possibility of carrying out the process in reactive stages together with the recirculation of liquid product, allowed a greater yield with respect to the batch process. It is concluded that the proposed model improves the characteristics of the obtained hydrochar compared to its crude biomass, achieving lower proportions of hydrogen and oxygen in the solid product. |
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| AbstractList | This work evaluates a continuous biomass hydrothermal carbonization process through modeling and steady state simulation using the UniSim Design process simulator. The reactive process was divided into four stages: biomass hydrolysis, intermediate compounds degradation, aromatics formation, and polymerization process, which make it possible to obtain the solid product or hydrochar. Pure biomass types and their mixtures were compared, considering hydrochar and carbon yields, H/C, and O/C ratios, and their deviation from the batch process. The results of hydrochar yield indicated that biomass with high cellulose content can perform satisfactorily in the proposed model. In addition, the possibility of carrying out the process in reactive stages together with the recirculation of liquid product, allowed a greater yield with respect to the batch process. It is concluded that the proposed model improves the characteristics of the obtained hydrochar compared to its crude biomass, achieving lower proportions of hydrogen and oxygen in the solid product. |
| Author | Cubillos, Francisco Díaz-Robles, Luis A. Pazo, Amparo Monedero, Esperanza Silva, Javier Lapuerta, Magín Corsi, Giancarlo Campos, Valeria Pino-Cortés, Ernesto Paczkowski, Sebastian Gómez, Jaime Pelz, Stefan K. Carrasco, Samuel |
| Author_xml | – sequence: 1 givenname: Jaime surname: Gómez fullname: Gómez, Jaime email: jaime.gomez.l@usach.cl organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 2 givenname: Giancarlo surname: Corsi fullname: Corsi, Giancarlo organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 3 givenname: Ernesto surname: Pino-Cortés fullname: Pino-Cortés, Ernesto organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 4 givenname: Luis A. surname: Díaz-Robles fullname: Díaz-Robles, Luis A. organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 5 givenname: Valeria surname: Campos fullname: Campos, Valeria organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 6 givenname: Francisco surname: Cubillos fullname: Cubillos, Francisco organization: Departamento de Ingeniería Química, Universidad de Santiago de Chile – sequence: 7 givenname: Stefan K. surname: Pelz fullname: Pelz, Stefan K. organization: Institute for Applied Research, University of Applied Forest Sciences Rottenburg – sequence: 8 givenname: Sebastian surname: Paczkowski fullname: Paczkowski, Sebastian organization: Institute for Applied Research, University of Applied Forest Sciences Rottenburg – sequence: 9 givenname: Samuel surname: Carrasco fullname: Carrasco, Samuel organization: Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso – sequence: 10 givenname: Javier surname: Silva fullname: Silva, Javier organization: Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso – sequence: 11 givenname: Magín surname: Lapuerta fullname: Lapuerta, Magín organization: Escuela Técnica Superior de Ingenieros Industriales, Universidad de Castilla-La Mancha – sequence: 12 givenname: Amparo surname: Pazo fullname: Pazo, Amparo organization: Instituto de Investigación en Energías Renovables, Universidad de Castilla-La Mancha – sequence: 13 givenname: Esperanza surname: Monedero fullname: Monedero, Esperanza organization: Instituto de Investigación en Energías Renovables, Universidad de Castilla-La Mancha |
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| SubjectTerms | Biomass Carbonization Computer simulation Hydrochar Hydrothermal carbonization Modelling Steady state models |
| Title | Modeling and simulation of a continuous biomass hydrothermal carbonization process |
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