Metal-graphene interfaces in epitaxial and bulk systems: A review

[Display omitted] The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of solutions for technological applications. Interfacing graphene with bulk metals is fundamental for a wide range of interesting multi-dimensional sy...

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Published inProgress in materials science Vol. 110; pp. 100652 - 57
Main Authors Yang, Ming, Liu, Yue, Fan, Tongxiang, Zhang, Di
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.05.2020
Elsevier BV
Subjects
Online AccessGet full text
ISSN0079-6425
1873-2208
DOI10.1016/j.pmatsci.2020.100652

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Abstract [Display omitted] The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of solutions for technological applications. Interfacing graphene with bulk metals is fundamental for a wide range of interesting multi-dimensional systems ranging from incorporating graphene into fully dense metal matrices, and graphene epitaxy on metal substrates to the deposition of metal overlayers on graphene. The microstructure, interaction and properties of metal-graphene interfaces (MGIs), which substantially govern the epitaxial growth mode, mass exchange and overall properties, are central topics for all these metal-graphene systems. This review covers MGIs produced by both bottom-up and top-down approaches, which correspond to epitaxial and bulk metal-graphene systems, respectively. Importantly, we attempt to link and build a bridge among these systems, with highlight on the shared roles and critical functions of MGIs. We describe the structure, physicochemcial properties, fabrication and optimum design of MGIs, and we examine the roles of their properties and pertinent phenomena in governing the overall performance in a vast array of specific applications. We conclude by making a prospect on MGIs and underscoring the concept of interface nanoengineering for a broad spectrum of metal/low-dimensional material hybrid systems.
AbstractList The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of solutions for technological applications. Interfacing graphene with bulk metals is fundamental for a wide range of interesting multi-dimensional systems ranging from incorporating graphene into fully dense metal matrices, and graphene epitaxy on metal substrates to the deposition of metal overlayers on graphene. The microstructure, interaction and properties of metal-graphene interfaces (MGIs), which substantially govern the epitaxial growth mode, mass exchange and overall properties, are central topics for all these metal-graphene systems. This review covers MGIs produced by both bottom-up and top-down approaches, which correspond to epitaxial and bulk metal-graphene systems, respectively. Importantly, we attempt to link and build a bridge among these systems, with highlight on the shared roles and critical functions of MGIs. We describe the structure, physicochemcial properties, fabrication and optimum design of MGIs, and we examine the roles of their properties and pertinent phenomena in governing the overall performance in a vast array of specific applications. We conclude by making a prospect on MGIs and underscoring the concept of interface nanoengineering for a broad spectrum of metal/low-dimensional material hybrid systems.
[Display omitted] The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of solutions for technological applications. Interfacing graphene with bulk metals is fundamental for a wide range of interesting multi-dimensional systems ranging from incorporating graphene into fully dense metal matrices, and graphene epitaxy on metal substrates to the deposition of metal overlayers on graphene. The microstructure, interaction and properties of metal-graphene interfaces (MGIs), which substantially govern the epitaxial growth mode, mass exchange and overall properties, are central topics for all these metal-graphene systems. This review covers MGIs produced by both bottom-up and top-down approaches, which correspond to epitaxial and bulk metal-graphene systems, respectively. Importantly, we attempt to link and build a bridge among these systems, with highlight on the shared roles and critical functions of MGIs. We describe the structure, physicochemcial properties, fabrication and optimum design of MGIs, and we examine the roles of their properties and pertinent phenomena in governing the overall performance in a vast array of specific applications. We conclude by making a prospect on MGIs and underscoring the concept of interface nanoengineering for a broad spectrum of metal/low-dimensional material hybrid systems.
ArticleNumber 100652
Author Yang, Ming
Fan, Tongxiang
Liu, Yue
Zhang, Di
Author_xml – sequence: 1
  givenname: Ming
  surname: Yang
  fullname: Yang, Ming
– sequence: 2
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  surname: Liu
  fullname: Liu, Yue
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  givenname: Tongxiang
  orcidid: 0000-0002-4591-6093
  surname: Fan
  fullname: Fan, Tongxiang
  email: txfan@sjtu.edu.cn
– sequence: 4
  givenname: Di
  surname: Zhang
  fullname: Zhang, Di
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Snippet [Display omitted] The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of...
The prosperity of graphene in the past decade has provided us with both a versatile platform for scientific studies and a multitude of solutions for...
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SubjectTerms CVD
Epitaxial growth
Graphene
Graphical user interface
Hybrid systems
Interface
Materials science
Metal matrix composites
Metal-graphene contact
Nanoengineering
Physicomechanical properties
Properties (attributes)
Substrates
Title Metal-graphene interfaces in epitaxial and bulk systems: A review
URI https://dx.doi.org/10.1016/j.pmatsci.2020.100652
https://www.proquest.com/docview/2457716437
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