Structural variation of transition metal-organic frameworks using deep eutectic solvents with different hydrogen bond donors
Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 48; no. 27; pp. 1199 - 129 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
21.07.2019
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1477-9226 1477-9234 1477-9234 |
| DOI | 10.1039/c9dt01050e |
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| Abstract | Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-organic frameworks, namely [NH
4
][Zn(BTC)(NH
3
)
2
]·H
2
O (
1
), [Cu(PDC)(NH
3
)] (
2
), [Co(H
2
BTC)
2
(e-urea)
2
]·(e-urea)·1/4H
2
O (
3
), K
0.63
(NH
4
)
0.37
[Mn(PZDC)] (
4
), [NH
4
][Mn(BTC)(H
2
O)] (
5
), [CH
3
NH
3
][Mn
3
(HBTC)
2
(BTC)·3H
2
O (
6
), and [Co
3
(BTC)
2
(urea)
2
]·2H
2
O (
7
), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H
3
BTC = 1,3,5-benzenetricarboxylic acid; H
2
PDC = 2,6-pyridinedicarboxylic acid; H
2
PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea =
N
,
N
-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound
7
exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal-organic frameworks.
Seven transition metal-organic frameworks with structures ranging from one-dimensional chains to three-dimensional networks have been synthesized in deep eutectic solvents. |
|---|---|
| AbstractList | Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal–organic frameworks, namely [NH
4
][Zn(BTC)(NH
3
)
2
]·H
2
O (
1
), [Cu(PDC)(NH
3
)] (
2
), [Co(H
2
BTC)
2
(e-urea)
2
]·(e-urea)·1/4H
2
O (
3
), K
0.63
(NH
4
)
0.37
[Mn(PZDC)] (
4
), [NH
4
][Mn(BTC)(H
2
O)] (
5
), [CH
3
NH
3
][Mn
3
(HBTC)
2
(BTC)·3H
2
O (
6
), and [Co
3
(BTC)
2
(urea)
2
]·2H
2
O (
7
), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H
3
BTC = 1,3,5-benzenetricarboxylic acid; H
2
PDC = 2,6-pyridinedicarboxylic acid; H
2
PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea =
N
,
N
-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound
7
exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal–organic frameworks. Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-organic frameworks, namely [NH4][Zn(BTC)(NH3)2]·H2O (1), [Cu(PDC)(NH3)] (2), [Co(H2BTC)2(e-urea)2]·(e-urea)·1/4H2O (3), K0.63(NH4)0.37[Mn(PZDC)] (4), [NH4][Mn(BTC)(H2O)] (5), [CH3NH3][Mn3(HBTC)2(BTC)·3H2O (6), and [Co3(BTC)2(urea)2]·2H2O (7), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H3BTC = 1,3,5-benzenetricarboxylic acid; H2PDC = 2,6-pyridinedicarboxylic acid; H2PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea = N,N-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound 7 exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal-organic frameworks.Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-organic frameworks, namely [NH4][Zn(BTC)(NH3)2]·H2O (1), [Cu(PDC)(NH3)] (2), [Co(H2BTC)2(e-urea)2]·(e-urea)·1/4H2O (3), K0.63(NH4)0.37[Mn(PZDC)] (4), [NH4][Mn(BTC)(H2O)] (5), [CH3NH3][Mn3(HBTC)2(BTC)·3H2O (6), and [Co3(BTC)2(urea)2]·2H2O (7), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H3BTC = 1,3,5-benzenetricarboxylic acid; H2PDC = 2,6-pyridinedicarboxylic acid; H2PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea = N,N-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound 7 exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal-organic frameworks. Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-organic frameworks, namely [NH 4 ][Zn(BTC)(NH 3 ) 2 ]·H 2 O ( 1 ), [Cu(PDC)(NH 3 )] ( 2 ), [Co(H 2 BTC) 2 (e-urea) 2 ]·(e-urea)·1/4H 2 O ( 3 ), K 0.63 (NH 4 ) 0.37 [Mn(PZDC)] ( 4 ), [NH 4 ][Mn(BTC)(H 2 O)] ( 5 ), [CH 3 NH 3 ][Mn 3 (HBTC) 2 (BTC)·3H 2 O ( 6 ), and [Co 3 (BTC) 2 (urea) 2 ]·2H 2 O ( 7 ), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H 3 BTC = 1,3,5-benzenetricarboxylic acid; H 2 PDC = 2,6-pyridinedicarboxylic acid; H 2 PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea = N , N -dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound 7 exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal-organic frameworks. Seven transition metal-organic frameworks with structures ranging from one-dimensional chains to three-dimensional networks have been synthesized in deep eutectic solvents. Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal–organic frameworks, namely [NH4][Zn(BTC)(NH3)2]·H2O (1), [Cu(PDC)(NH3)] (2), [Co(H2BTC)2(e-urea)2]·(e-urea)·1/4H2O (3), K0.63(NH4)0.37[Mn(PZDC)] (4), [NH4][Mn(BTC)(H2O)] (5), [CH3NH3][Mn3(HBTC)2(BTC)·3H2O (6), and [Co3(BTC)2(urea)2]·2H2O (7), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H3BTC = 1,3,5-benzenetricarboxylic acid; H2PDC = 2,6-pyridinedicarboxylic acid; H2PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea = N,N-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound 7 exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal–organic frameworks. Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical properties to the traditional ionic liquids (ILs) while being much cheaper and more environmentally friendly. Herein, seven transition metal-organic frameworks, namely [NH ][Zn(BTC)(NH ) ]·H O (1), [Cu(PDC)(NH )] (2), [Co(H BTC) (e-urea) ]·(e-urea)·1/4H O (3), K (NH ) [Mn(PZDC)] (4), [NH ][Mn(BTC)(H O)] (5), [CH NH ][Mn (HBTC) (BTC)·3H O (6), and [Co (BTC) (urea) ]·2H O (7), were synthesized in deep eutectic solvents of choline chloride and urea/e-urea/m-urea (H BTC = 1,3,5-benzenetricarboxylic acid; H PDC = 2,6-pyridinedicarboxylic acid; H PZDC = 3,5-pyrazoledicarboxylic acid; e-urea = ethylene urea; m-urea = N,N-dimethylurea). Of particular interest is the fact that the utilization of different hydrogen bond donors in DES mixtures can lead to the formation of different frameworks. The multiple roles of hydrogen bond donors in the reactions were discussed. Furthermore, compound 7 exhibited catalytic activity for the oxidation of styrene, and thus it can be used as a heterogeneous catalyst due to its good stability. These results promote the understanding of the application of DESs in synthesizing novel transition metal-organic frameworks. |
| Author | Cai, Ting Zhu, Jian-Nan Li, Wei Cheng, Fang-Fang Zhao, Ming-Yu Li, Peng Xiong, Wei-Wei |
| AuthorAffiliation | School of Pharmacy Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University (NanjingTech) Nanjing University of Chinese Medicine Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) |
| AuthorAffiliation_xml | – sequence: 0 name: Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) – sequence: 0 name: Nanjing Tech University (NanjingTech) – sequence: 0 name: School of Pharmacy – sequence: 0 name: Nanjing University of Chinese Medicine – sequence: 0 name: Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) |
| Author_xml | – sequence: 1 givenname: Ming-Yu surname: Zhao fullname: Zhao, Ming-Yu – sequence: 2 givenname: Jian-Nan surname: Zhu fullname: Zhu, Jian-Nan – sequence: 3 givenname: Peng surname: Li fullname: Li, Peng – sequence: 4 givenname: Wei surname: Li fullname: Li, Wei – sequence: 5 givenname: Ting surname: Cai fullname: Cai, Ting – sequence: 6 givenname: Fang-Fang surname: Cheng fullname: Cheng, Fang-Fang – sequence: 7 givenname: Wei-Wei surname: Xiong fullname: Xiong, Wei-Wei |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31192327$$D View this record in MEDLINE/PubMed |
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| ContentType | Journal Article |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI Electronic supplementary information (ESI) available: Crystallographic data in CIF format, PXRD patterns, and TGA curves. CCDC 1901745-1901751 10.1039/c9dt01050e ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| Snippet | Deep eutectic solvents (DESs) have attracted extensive attention in the field of material synthesis as green solvents. They have similar physical and chemical... |
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| SubjectTerms | Ammonia Catalysis Catalytic activity Chemical properties Choline Crystallography Donors (electronic) Eutectics Format Hydrogen bonds Ionic liquids Metal-organic frameworks Organic chemistry Oxidation Solvents Transition metals Urea Zinc |
| Title | Structural variation of transition metal-organic frameworks using deep eutectic solvents with different hydrogen bond donors |
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