Utilisation of carbon dioxide and nitrate for urea electrosynthesis with a Cu-based metal-organic framework
It is important and challenging to utilise CO 2 and NO 3 − as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO 4 active sites, as an efficient electrocatalyst for coupling CO 2 and NO 3 − into urea, achieving a hi...
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| Published in | Chemical communications (Cambridge, England) Vol. 6; no. 27; pp. 3669 - 3672 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
28.03.2024
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1359-7345 1364-548X 1364-548X |
| DOI | 10.1039/d3cc05821b |
Cover
| Abstract | It is important and challenging to utilise CO
2
and NO
3
−
as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO
4
active sites, as an efficient electrocatalyst for coupling CO
2
and NO
3
−
into urea, achieving a high yield rate of 1.46 g h
−1
g
cat
−1
with a current density of 44.2 mA cm
−1
at −0.6 V
vs.
RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis.
A hexagonal 2D Cu-based MOF with planar CuO
4
nodes, denoted as
Cu-HATNA
, was developed and employed as an electrocatalyst for direct electrosynthesis of urea from CO
2
and NO
3
−
. |
|---|---|
| AbstractList | It is important and challenging to utilise CO
and NO
as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO
active sites, as an efficient electrocatalyst for coupling CO
and NO
into urea, achieving a high yield rate of 1.46 g h
g
with a current density of 44.2 mA cm
at -0.6 V
RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis. It is important and challenging to utilise CO 2 and NO 3 − as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO 4 active sites, as an efficient electrocatalyst for coupling CO 2 and NO 3 − into urea, achieving a high yield rate of 1.46 g h −1 g cat −1 with a current density of 44.2 mA cm −1 at −0.6 V vs. RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis. A hexagonal 2D Cu-based MOF with planar CuO 4 nodes, denoted as Cu-HATNA , was developed and employed as an electrocatalyst for direct electrosynthesis of urea from CO 2 and NO 3 − . It is important and challenging to utilise CO2 and NO3− as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal–organic framework (MOF) Cu-HATNA, possessing planar CuO4 active sites, as an efficient electrocatalyst for coupling CO2 and NO3− into urea, achieving a high yield rate of 1.46 g h−1 gcat−1 with a current density of 44.2 mA cm−1 at −0.6 V vs. RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis. It is important and challenging to utilise CO 2 and NO 3 − as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal–organic framework (MOF) Cu-HATNA, possessing planar CuO 4 active sites, as an efficient electrocatalyst for coupling CO 2 and NO 3 − into urea, achieving a high yield rate of 1.46 g h −1 g cat −1 with a current density of 44.2 mA cm −1 at −0.6 V vs. RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis. It is important and challenging to utilise CO2 and NO3- as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO4 active sites, as an efficient electrocatalyst for coupling CO2 and NO3- into urea, achieving a high yield rate of 1.46 g h-1 gcat-1 with a current density of 44.2 mA cm-1 at -0.6 V vs. RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis.It is important and challenging to utilise CO2 and NO3- as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO4 active sites, as an efficient electrocatalyst for coupling CO2 and NO3- into urea, achieving a high yield rate of 1.46 g h-1 gcat-1 with a current density of 44.2 mA cm-1 at -0.6 V vs. RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis. |
| Author | Chen, Xiao-Ming Liao, Pei-Qin Zhang, Meng-Di Huang, Jia-Run |
| AuthorAffiliation | Chemistry and Chemical Engineering Guangdong Laboratory MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University |
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| Snippet | It is important and challenging to utilise CO
2
and NO
3
−
as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework... It is important and challenging to utilise CO 2 and NO 3 − as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal–organic framework... It is important and challenging to utilise CO and NO as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF)... It is important and challenging to utilise CO2 and NO3− as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal–organic framework... It is important and challenging to utilise CO2 and NO3- as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework... |
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| SubjectTerms | Carbon dioxide Copper Electrocatalysts Metal-organic frameworks Urea |
| Title | Utilisation of carbon dioxide and nitrate for urea electrosynthesis with a Cu-based metal-organic framework |
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