Viscous properties of new mould flux based on aluminate system with CeO2 for continuous casting of RE alloyed heat resistant steel
The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions occur generally in the mold. To restrain the interface reaction and improve conditions for continuous casting, a new mould flux based on alumin...
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| Published in | Journal of rare earths Vol. 34; no. 3; pp. 328 - 335 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.03.2016
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1002-0721 2509-4963 |
| DOI | 10.1016/S1002-0721(16)60032-7 |
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| Abstract | The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions occur generally in the mold. To restrain the interface reaction and improve conditions for continuous casting, a new mould flux based on aluminate system was devised. The viscous properties were investigated. Scanning electron microscopy and X-ray diffraction were applied to detect and characterize the crystalline phases in the continuous cooling process. The results showed that appropriate addition of CeO_2 could avoid the precipitation of CaO and decrease the viscosity of the mould flux. Increasing the mass ratio of CaO /Al_2O_3, especially to a value exceeding 1, could worsen the stability of the mould flux. With a content of less than 14 wt.%, Li_2O could reduce the viscosity and breaking temperature, but its effect could be weakened for the promoted precipitation of LiAlO_2. To obtain a mould flux with stable viscous properties, such as viscosity and breaking temperature, appropriate contents of CeO_2 and Li_2O should be controlled to around 10 wt.% and 14 wt.%, while the mass ratio of CaO /Al_2O_3 should not be more than 1. |
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| AbstractList | The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions occur generally in the mold. To restrain the interface reaction and improve conditions for continuous casting, a new mould flux based on aluminate system was devised. The viscous properties were investigated. Scanning electron microscopy and X-ray diffraction were applied to detect and characterize the crystalline phases in the continuous cooling process. The results showed that appropriate addition of CeO_2 could avoid the precipitation of CaO and decrease the viscosity of the mould flux. Increasing the mass ratio of CaO /Al_2O_3, especially to a value exceeding 1, could worsen the stability of the mould flux. With a content of less than 14 wt.%, Li_2O could reduce the viscosity and breaking temperature, but its effect could be weakened for the promoted precipitation of LiAlO_2. To obtain a mould flux with stable viscous properties, such as viscosity and breaking temperature, appropriate contents of CeO_2 and Li_2O should be controlled to around 10 wt.% and 14 wt.%, while the mass ratio of CaO /Al_2O_3 should not be more than 1. The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions occur generally in the mold. To restrain the interface reaction and improve conditions for continuous casting, a new mould flux based on aluminate system was devised. The viscous properties were investigated. Scanning electron microscopy and X-ray diffraction were applied to detect and characterize the crystalline phases in the continuous cooling process. The results showed that appropriate addition of CeO2 could avoid the precipitation of CaO and decrease the viscosity of the mould flux. Increasing the mass ratio of CaO/Al2O3, especially to a value exceeding 1, could worsen the stability of the mould flux. With a content of less than 14 wt.%, Li2O could reduce the viscosity and breaking temperature, but its effect could be weakened for the promoted precipitation of LiAlO2. To obtain a mould flux with stable viscous properties, such as viscosity and breaking temperature, appropriate contents of CeO2 and Li2O should be controlled to around 10 wt.% and 14 wt.%, while the mass ratio of CaO/Al2O3 should not be more than 1. Effects of CeO2 on the breaking temperature and the viscosities at 1300 and 1225 °C |
| Author | 亓捷 刘承军 李春龙 姜茂发 |
| AuthorAffiliation | Key Laboratory for Ecological Metallurgy of Multimetallic Ores （Ministry of Education）, Northeastern University, Shenyang 110819, China Baotou Iron and Steel （Group） Co., Ltd., Baotou 014000, China |
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| CitedBy_id | crossref_primary_10_1007_s11663_016_0850_3 crossref_primary_10_1007_s12613_019_1765_1 crossref_primary_10_1016_j_jnoncrysol_2017_09_014 crossref_primary_10_1080_00084433_2017_1309165 crossref_primary_10_2355_isijinternational_ISIJINT_2017_252 crossref_primary_10_1016_j_molliq_2023_123088 crossref_primary_10_1007_s11663_023_02874_6 crossref_primary_10_1177_03019233241254237 crossref_primary_10_1002_srin_202200494 crossref_primary_10_1016_j_ceramint_2021_08_352 crossref_primary_10_1016_j_matchemphys_2021_124526 crossref_primary_10_1080_00084433_2022_2037287 crossref_primary_10_1002_srin_202300392 crossref_primary_10_1007_s11015_024_01655_z crossref_primary_10_1016_j_ceramint_2021_04_083 crossref_primary_10_1016_j_jnoncrysol_2020_120085 crossref_primary_10_3390_met15030286 crossref_primary_10_3390_met9030333 crossref_primary_10_1016_j_molliq_2022_120738 crossref_primary_10_1007_s12613_023_2621_x crossref_primary_10_2355_isijinternational_ISIJINT_2018_760 crossref_primary_10_3390_met8100737 crossref_primary_10_1016_j_jnoncrysol_2021_120681 |
| Cites_doi | 10.2355/isijinternational.ISIJINT-2015-193 10.1016/j.jnoncrysol.2008.09.012 10.1007/s11663-012-9769-5 10.1007/s11663-012-9667-x 10.1002/srin.201400523 10.1007/s11663-011-9600-8 10.1016/S1002-0721(14)60137-X 10.2355/isijinternational.47.1409 10.1007/s11663-012-9770-z 10.2355/isijinternational.42.38 10.1002/srin.201200092 10.1016/S1002-0721(14)60390-2 10.1007/s11663-004-0028-2 10.2355/isijinternational.48.739 10.1179/1743281213Y.0000000107 10.1179/174328109X461419 10.1179/1743281211Y.0000000011 10.1016/S1002-0721(14)60535-4 |
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| Keywords | viscosity aluminate melt heat resistant steel mould flux rare earth steel |
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| Notes | 11-2788/TF mould flux; aluminate melt; viscosity; rare earth steel; heat resistant steel The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions occur generally in the mold. To restrain the interface reaction and improve conditions for continuous casting, a new mould flux based on aluminate system was devised. The viscous properties were investigated. Scanning electron microscopy and X-ray diffraction were applied to detect and characterize the crystalline phases in the continuous cooling process. The results showed that appropriate addition of CeO_2 could avoid the precipitation of CaO and decrease the viscosity of the mould flux. Increasing the mass ratio of CaO /Al_2O_3, especially to a value exceeding 1, could worsen the stability of the mould flux. With a content of less than 14 wt.%, Li_2O could reduce the viscosity and breaking temperature, but its effect could be weakened for the promoted precipitation of LiAlO_2. To obtain a mould flux with stable viscous properties, such as viscosity and breaking temperature, appropriate contents of CeO_2 and Li_2O should be controlled to around 10 wt.% and 14 wt.%, while the mass ratio of CaO /Al_2O_3 should not be more than 1. QI Jie , LIU Chengjun , LI Chunlong , JIANG Maofa （L Key Laboratory for Ecological Metallurgy of Multimetallic Ores （Ministry of Education）, Northeastern University, Shenyang l10819, China; 2. Baotou Iron and Steel （Group） Co., Ltd., Baotou 014000, China） |
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| Snippet | The conventional mould fluxes can not be applied to the continuous casting of RE alloyed heat resistant steel, because severe slag-metal interface reactions... |
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| SubjectTerms | aluminate melt CeO2 heat resistant steel mould flux rare earth steel viscosity 模具 稀土合金 粘性 耐热钢 连铸 通量 铝酸盐体系 |
| Title | Viscous properties of new mould flux based on aluminate system with CeO2 for continuous casting of RE alloyed heat resistant steel |
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