Magnetocaloric properties, microhardness and corrosion resistance of Gd100-xZrx alloys
With the intention to improve its mechanical properties and corrosion resistance, the magnetocaloric metal Gd was alloyed with Zr by arc melting and heat treatment. All Gd100？xZrx （x=0, 0.5, 1, 1.5, 2） alloys with various Zr dopings showed hexagonal crystal structure. The Curie temperatures （TCs） of...
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| Published in | Journal of rare earths Vol. 34; no. 9; pp. 889 - 894 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.09.2016
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1002-0721 2509-4963 |
| DOI | 10.1016/S1002-0721(16)60111-4 |
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| Abstract | With the intention to improve its mechanical properties and corrosion resistance, the magnetocaloric metal Gd was alloyed with Zr by arc melting and heat treatment. All Gd100？xZrx （x=0, 0.5, 1, 1.5, 2） alloys with various Zr dopings showed hexagonal crystal structure. The Curie temperatures （TCs） of Zr doped alloys were lower than that of Gd by ~2 K. The maximum magnetic entropy changes of Gd99.5Zr0.5 alloy under magnetic field changes of 0？2 T and 0？5 T were 5.27 and 9.41 J/（kg·K）, respectively, which were larger than that of pure Gd metal. The addition of a small amount of Zr increased the microhardness of Gd by at least 29.3%. The corrosion resistance of Gd was also improved by Zr doping, demonstrated by increased corrosion potential and reduced corrosion current density in electrochemical polarization curves measurements. These enhanced properties were beneficial to the potential ap-plications of Gd100？xZrx alloys as magnetic refrigerants at room temperature. |
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| AbstractList | With the intention to improve its mechanical properties and corrosion resistance, the magnetocaloric metal Gd was alloyed with Zr by arc melting and heat treatment. All Gd100？xZrx （x=0, 0.5, 1, 1.5, 2） alloys with various Zr dopings showed hexagonal crystal structure. The Curie temperatures （TCs） of Zr doped alloys were lower than that of Gd by ~2 K. The maximum magnetic entropy changes of Gd99.5Zr0.5 alloy under magnetic field changes of 0？2 T and 0？5 T were 5.27 and 9.41 J/（kg·K）, respectively, which were larger than that of pure Gd metal. The addition of a small amount of Zr increased the microhardness of Gd by at least 29.3%. The corrosion resistance of Gd was also improved by Zr doping, demonstrated by increased corrosion potential and reduced corrosion current density in electrochemical polarization curves measurements. These enhanced properties were beneficial to the potential ap-plications of Gd100？xZrx alloys as magnetic refrigerants at room temperature. With the intention to improve its mechanical properties and corrosion resistance, the magnetocaloric metal Gd was alloyed with Zr by arc melting and heat treatment. All Gd100–xZrx (x=0, 0.5, 1, 1.5, 2) alloys with various Zr dopings showed hexagonal crystal structure. The Curie temperatures (TCs) of Zr doped alloys were lower than that of Gd by ∼2 K. The maximum magnetic entropy changes of Gd99.5Zr0.5 alloy under magnetic field changes of 0–2 T and 0–5 T were 5.27 and 9.41 J/(kg·K), respectively, which were larger than that of pure Gd metal. The addition of a small amount of Zr increased the microhardness of Gd by at least 29.3%. The corrosion resistance of Gd was also improved by Zr doping, demonstrated by increased corrosion potential and reduced corrosion current density in electrochemical polarization curves measurements. These enhanced properties were beneficial to the potential applications of Gd100–xZrx alloys as magnetic refrigerants at room temperature. Polarization curves of Gd100-xZrx (x=0, 0.5, 1, 1.5 and 2) alloys in distilled water |
| Author | 钟喜春 沈小艳 刘仲武 |
| AuthorAffiliation | School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China |
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| CitedBy_id | crossref_primary_10_1016_j_jre_2018_01_009 crossref_primary_10_1007_s11837_022_05495_7 crossref_primary_10_1016_j_ssc_2024_115444 crossref_primary_10_4028_www_scientific_net_KEM_833_176 crossref_primary_10_1016_j_jre_2024_06_009 crossref_primary_10_1039_C9RA00106A crossref_primary_10_1007_s42247_024_00820_z crossref_primary_10_1016_j_matdes_2017_05_038 crossref_primary_10_1016_j_jre_2018_03_016 crossref_primary_10_1016_j_jmrt_2024_09_024 crossref_primary_10_1039_D1RA03495B crossref_primary_10_1016_j_jre_2019_02_008 crossref_primary_10_3390_ma13245758 crossref_primary_10_1016_j_jre_2024_08_004 |
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| Keywords | microhardness corrosion resistance magnetocaloric effect Gd100–xZrx alloys rare earths |
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| Notes | ZHONG Xichun , SHEN Xiaoyan , LIU Zhongwu （School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China） 11-2788/TF With the intention to improve its mechanical properties and corrosion resistance, the magnetocaloric metal Gd was alloyed with Zr by arc melting and heat treatment. All Gd100？xZrx （x=0, 0.5, 1, 1.5, 2） alloys with various Zr dopings showed hexagonal crystal structure. The Curie temperatures （TCs） of Zr doped alloys were lower than that of Gd by ~2 K. The maximum magnetic entropy changes of Gd99.5Zr0.5 alloy under magnetic field changes of 0？2 T and 0？5 T were 5.27 and 9.41 J/（kg·K）, respectively, which were larger than that of pure Gd metal. The addition of a small amount of Zr increased the microhardness of Gd by at least 29.3%. The corrosion resistance of Gd was also improved by Zr doping, demonstrated by increased corrosion potential and reduced corrosion current density in electrochemical polarization curves measurements. These enhanced properties were beneficial to the potential ap-plications of Gd100？xZrx alloys as magnetic refrigerants at room temperature. Gd100-xZrx alloys; magnetocaloric effect; microhardness; corrosion resistance; rare earths |
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| Title | Magnetocaloric properties, microhardness and corrosion resistance of Gd100-xZrx alloys |
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