Carbon–sulfur bond formation via photochemical strategies: An efficient method for the synthesis of sulfur-containing compounds
The development of green and convenient methods for C–S bond formation has received significant attention because C–S bond widely occurs in many important pharmaceutical and biological compounds. Recently, visible-light photoredox catalysis has been established as an efficient and general tool for t...
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| Published in | Chinese chemical letters Vol. 33; no. 4; pp. 1798 - 1816 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.04.2022
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science,MOE,State Key Laboratory Base of Eco-Chemical Engineering,College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China%School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,China |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-8417 1878-5964 |
| DOI | 10.1016/j.cclet.2021.09.068 |
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| Abstract | The development of green and convenient methods for C–S bond formation has received significant attention because C–S bond widely occurs in many important pharmaceutical and biological compounds. Recently, visible-light photoredox catalysis has been established as an efficient and general tool for the construction of C–C and C-heteroatom bonds. In this review, we have focused on the research on recent advances in C–S bond formation via visible-light photoredox catalysis, and the growing opportunities they present to the construction of complex chemical scaffolds for applications encompassing bioactive molecules synthesis, synthetic methodology development, and sulfur-containing drugs. We hope that this review will provide chemists with a synthetic tool that will open the door to further development of organsulfur chemistry
[Display omitted] In this review, we highlight the recent advances of C–S bond formation via visible-light photoredox catalysis, and analyze the reaction mechanism of various transformations in detail. We hope that this review will provide chemists with a synthetic tool and open new avenues for further development of organsulfur chemistry. |
|---|---|
| AbstractList | The development of green and convenient methods for C-S bond formation has received significant at-tention because C-S bond widely occurs in many important pharmaceutical and biological compounds.Recently,visible-light photoredox catalysis has been established as an efficient and general tool for the construction of C-C and C-heteroatom bonds.In this review,we have focused on the research on recent advances in C-S bond formation via visible-light photoredox catalysis,and the growing opportunities they present to the construction of complex chemical scaffolds for applications encompassing bioactive molecules synthesis,synthetic methodology development,and sulfur-containing drugs.We hope that this review will provide chemists with a synthetic tool that will open the door to further development of organsulfur chemistry The development of green and convenient methods for C–S bond formation has received significant attention because C–S bond widely occurs in many important pharmaceutical and biological compounds. Recently, visible-light photoredox catalysis has been established as an efficient and general tool for the construction of C–C and C-heteroatom bonds. In this review, we have focused on the research on recent advances in C–S bond formation via visible-light photoredox catalysis, and the growing opportunities they present to the construction of complex chemical scaffolds for applications encompassing bioactive molecules synthesis, synthetic methodology development, and sulfur-containing drugs. We hope that this review will provide chemists with a synthetic tool that will open the door to further development of organsulfur chemistry [Display omitted] In this review, we highlight the recent advances of C–S bond formation via visible-light photoredox catalysis, and analyze the reaction mechanism of various transformations in detail. We hope that this review will provide chemists with a synthetic tool and open new avenues for further development of organsulfur chemistry. |
| Author | Yang, Daoshan Yan, Qiuli He, Wei-Min Lv, Jian Zhu, Enjie |
| AuthorAffiliation | Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science,MOE,State Key Laboratory Base of Eco-Chemical Engineering,College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China%School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,China |
| AuthorAffiliation_xml | – name: Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science,MOE,State Key Laboratory Base of Eco-Chemical Engineering,College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China%School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,China |
| Author_xml | – sequence: 1 givenname: Daoshan surname: Yang fullname: Yang, Daoshan email: yangdaoshan@tsinghua.org.cn organization: Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China – sequence: 2 givenname: Qiuli surname: Yan fullname: Yan, Qiuli organization: Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China – sequence: 3 givenname: Enjie surname: Zhu fullname: Zhu, Enjie organization: Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China – sequence: 4 givenname: Jian surname: Lv fullname: Lv, Jian organization: Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China – sequence: 5 givenname: Wei-Min surname: He fullname: He, Wei-Min email: weiminhe2016@yeah.net organization: School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China |
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| Keywords | Visible light Sulfur-containing compouds Cyclization Radical C-S bond formation |
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| Snippet | The development of green and convenient methods for C–S bond formation has received significant attention because C–S bond widely occurs in many important... The development of green and convenient methods for C-S bond formation has received significant at-tention because C-S bond widely occurs in many important... |
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| SubjectTerms | C-S bond formation Cyclization Radical Sulfur-containing compouds Visible light |
| Title | Carbon–sulfur bond formation via photochemical strategies: An efficient method for the synthesis of sulfur-containing compounds |
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