Scalable exfoliation for few-layered hexagonal boron nitride nanosheets (BNNSs) by microwave-assisted expansion and liquid nitrogen intercalation
The reliable exfoliation for BNNSs nanosheets was successfully achieved, which adopted the combination of microwave-assisted expansion and liquid nitrogen intercalation. [Display omitted] The low cost and facile scalable exfoliation route for two-dimensional hexagonal boron nitride (h-BN) was still...
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| Published in | Chinese chemical letters Vol. 31; no. 7; pp. 1936 - 1940 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.07.2020
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-8417 1878-5964 |
| DOI | 10.1016/j.cclet.2020.01.019 |
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| Abstract | The reliable exfoliation for BNNSs nanosheets was successfully achieved, which adopted the combination of microwave-assisted expansion and liquid nitrogen intercalation.
[Display omitted]
The low cost and facile scalable exfoliation route for two-dimensional hexagonal boron nitride (h-BN) was still indispensable for potential applications. In this work, we presented a convenient and scalable exfoliation for few-layer BNNSs. Taking advantage of the advantages of swift heating of microwave and ultra low temperature vaporization of liquid nitrogen, bulk h-BN was high-efficiently exfoliated into few-layer BNNSs. The as-exfoliated BNNSs had a 2−6 nm thickness and approximately 7.91% yield, exhibiting scalable, facile and environment-friendly features. Furthermore, the as-exfoliated BNNSs were applied as additive in oil for reducing friction of oil. The COF of the BNNSs-based grease reduced by 20.10% compared to grease, and the antiwear performance decreased by 55.8% and 45.1% relative to grease and h-BN-based grease. |
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| AbstractList | The reliable exfoliation for BNNSs nanosheets was successfully achieved, which adopted the combination of microwave-assisted expansion and liquid nitrogen intercalation.
[Display omitted]
The low cost and facile scalable exfoliation route for two-dimensional hexagonal boron nitride (h-BN) was still indispensable for potential applications. In this work, we presented a convenient and scalable exfoliation for few-layer BNNSs. Taking advantage of the advantages of swift heating of microwave and ultra low temperature vaporization of liquid nitrogen, bulk h-BN was high-efficiently exfoliated into few-layer BNNSs. The as-exfoliated BNNSs had a 2−6 nm thickness and approximately 7.91% yield, exhibiting scalable, facile and environment-friendly features. Furthermore, the as-exfoliated BNNSs were applied as additive in oil for reducing friction of oil. The COF of the BNNSs-based grease reduced by 20.10% compared to grease, and the antiwear performance decreased by 55.8% and 45.1% relative to grease and h-BN-based grease. The low cost and facile scalable exfoliation route for two-dimensional hexagonal boron nitride (h-BN)was still indispensable for potential applications.In this work,we presented a convenient and scalable exfoliation for few-layer BNNSs.Taking advantage of the advantages of swift heating of microwave and ultra low temperature vaporization of liquid nitrogen,bulk h-BN was high-efficiently exfoliated into fewlayer BNNSs.The as-exfoliated BNNSs had a 2-6 nm thickness and approximately 7.91％ yield,exhibiting scalable,facile and environment-friendly features.Furthermore,the as-exfoliated BNNSs were applied as additive in oil for reducing friction ofoil.The COF of the BNNSs-based grease reduced by 20.10％ compared to grease,and the antiwear performance decreased by 55.8％ and 45.1％ relative to grease and h-BN-based grease. |
| Author | Liu, Zan Cheng, Zhilin Ma, Zhansheng |
| AuthorAffiliation | School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
| AuthorAffiliation_xml | – name: School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
| Author_xml | – sequence: 1 givenname: Zhansheng surname: Ma fullname: Ma, Zhansheng – sequence: 2 givenname: Zan surname: Liu fullname: Liu, Zan – sequence: 3 givenname: Zhilin surname: Cheng fullname: Cheng, Zhilin email: zlcheng224@126.com |
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| Snippet | The reliable exfoliation for BNNSs nanosheets was successfully achieved, which adopted the combination of microwave-assisted expansion and liquid nitrogen... The low cost and facile scalable exfoliation route for two-dimensional hexagonal boron nitride (h-BN)was still indispensable for potential applications.In this... |
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| SubjectTerms | BNNSs Exfoliation Friction Liquid nitrogen Microwave |
| Title | Scalable exfoliation for few-layered hexagonal boron nitride nanosheets (BNNSs) by microwave-assisted expansion and liquid nitrogen intercalation |
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