Tailoring polymer electrolytes with PVA for improved performance in electrical double layer capacitors

[Display omitted] In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinyl alcohol (PVA) as polymer hosts and sodium thiocyanate (NaSCN) for ion transport. Glycerol was incorporated to enhance ionic conduction. The conducted FTIR results establis...

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Published inJournal of industrial and engineering chemistry (Seoul, Korea) Vol. 146; pp. 506 - 521
Main Authors Hamsan, M.H., Hama, Peshawa O., Aziz, Shujahadeen B., Hadi, Jihad M., Ahmed, Mohammed B., Abdullah, Ranjdar M., Sadiq, Niyaz M., F. Z. Kadir, Mohd
Format Journal Article
LanguageEnglish
Published Elsevier B.V 25.06.2025
한국공업화학회
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Online AccessGet full text
ISSN1226-086X
1876-794X
DOI10.1016/j.jiec.2024.11.035

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Abstract [Display omitted] In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinyl alcohol (PVA) as polymer hosts and sodium thiocyanate (NaSCN) for ion transport. Glycerol was incorporated to enhance ionic conduction. The conducted FTIR results establish that glycerol can dissociate more salts. The band associated with SCN anion decreased in intensity and broadened. The ionic conductivity was determined through electrochemical impedance spectroscopy (EIS). The value of ε’ is about twice that of ε’’ value, which is the subject of enormous scientific debate. The AC conductivity spectrum reveals dissimilar regions endorsed to the contributions of electrode polarization and DC conductivity. The ion fraction and its contributions were determined using transference number measurement (TNM), with ion contributions reaching 0.93. The electrolyte exhibited electrochemical stability up to 2.67 V. Charge transfer via Faradaic processes was not observed at the electrode–electrolyte interface, as indicated by CV measurements. The triangular shape of the galvanostatic charge–discharge (GCD) diagram supports capacitive behavior rather than redox reactions, with a specific capacitance of 40F/g. The regular power and energy densities of the electric double-layer capacitors (EDLCs) were estimated as 1255.2 W/kg and 5.5 Wh/kg, respectively, over 1,500 cycles.
AbstractList [Display omitted] In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinyl alcohol (PVA) as polymer hosts and sodium thiocyanate (NaSCN) for ion transport. Glycerol was incorporated to enhance ionic conduction. The conducted FTIR results establish that glycerol can dissociate more salts. The band associated with SCN anion decreased in intensity and broadened. The ionic conductivity was determined through electrochemical impedance spectroscopy (EIS). The value of ε’ is about twice that of ε’’ value, which is the subject of enormous scientific debate. The AC conductivity spectrum reveals dissimilar regions endorsed to the contributions of electrode polarization and DC conductivity. The ion fraction and its contributions were determined using transference number measurement (TNM), with ion contributions reaching 0.93. The electrolyte exhibited electrochemical stability up to 2.67 V. Charge transfer via Faradaic processes was not observed at the electrode–electrolyte interface, as indicated by CV measurements. The triangular shape of the galvanostatic charge–discharge (GCD) diagram supports capacitive behavior rather than redox reactions, with a specific capacitance of 40F/g. The regular power and energy densities of the electric double-layer capacitors (EDLCs) were estimated as 1255.2 W/kg and 5.5 Wh/kg, respectively, over 1,500 cycles.
In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinylalcohol (PVA) as polymer hosts and sodium thiocyanate (NaSCN) for ion transport. Glycerol was incorporated toenhance ionic conduction. The conducted FTIR results establish that glycerol can dissociate more salts. The bandassociated with SCN anion decreased in intensity and broadened. The ionic conductivity was determined throughelectrochemical impedance spectroscopy (EIS). The value of ε’ is about twice that of ε’’ value, which is thesubject of enormous scientific debate. The AC conductivity spectrum reveals dissimilar regions endorsed to thecontributions of electrode polarization and DC conductivity. The ion fraction and its contributions were determinedusing transference number measurement (TNM), with ion contributions reaching 0.93. The electrolyteexhibited electrochemical stability up to 2.67 V. Charge transfer via Faradaic processes was not observed at theelectrode–electrolyte interface, as indicated by CV measurements. The triangular shape of the galvanostaticcharge–discharge (GCD) diagram supports capacitive behavior rather than redox reactions, with a specificcapacitance of 40F/g. The regular power and energy densities of the electric double-layer capacitors (EDLCs)were estimated as 1255.2 W/kg and 5.5 Wh/kg, respectively, over 1,500 cycles. KCI Citation Count: 0
Author Hadi, Jihad M.
Hama, Peshawa O.
Ahmed, Mohammed B.
Abdullah, Ranjdar M.
Aziz, Shujahadeen B.
Sadiq, Niyaz M.
F. Z. Kadir, Mohd
Hamsan, M.H.
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  surname: Hamsan
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  givenname: Peshawa O.
  surname: Hama
  fullname: Hama, Peshawa O.
  organization: Sulaimani Polytechnic University, Electrical Power Engineering, 46001 Sulaimani, Kurdistan, Iraq
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  givenname: Shujahadeen B.
  surname: Aziz
  fullname: Aziz, Shujahadeen B.
  email: shujahadeenaziz@gmail.com
  organization: Research and Development Center, University of Sulaimani, Qlyasan Street, Sulaymaniyah, Kurdistan Regional Government, 46001, Iraq
– sequence: 4
  givenname: Jihad M.
  surname: Hadi
  fullname: Hadi, Jihad M.
  organization: The Development Center for Research and Training (DCRT), University of Human Development, Sulaymaniyah, Kurdistan Region 46001, Iraq
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  givenname: Mohammed B.
  surname: Ahmed
  fullname: Ahmed, Mohammed B.
  organization: Research and Development Center, University of Sulaimani, Qlyasan Street, Sulaymaniyah, Kurdistan Regional Government, 46001, Iraq
– sequence: 6
  givenname: Ranjdar M.
  surname: Abdullah
  fullname: Abdullah, Ranjdar M.
  organization: Hameed Majid Advanced Polymeric Materials Research Lab., Physics Department, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani, Kurdistan Regional Government, 46001, Iraq
– sequence: 7
  givenname: Niyaz M.
  surname: Sadiq
  fullname: Sadiq, Niyaz M.
  organization: Department of Physics, College of Science, University of Halabja, Halabja 46006, Kurdistan Regional Government, Iraq
– sequence: 8
  givenname: Mohd
  surname: F. Z. Kadir
  fullname: F. Z. Kadir, Mohd
  organization: Department of Physics, Faculty of Science, Universiti Malaya, 50603 Kuala Lumpur, Malaysia
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Plasticized Polymer electrolyte
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Snippet [Display omitted] In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinyl alcohol (PVA) as polymer hosts...
In this work, solid polymer electrolytes (SPEs) were synthesized through solution casting, employing polyvinylalcohol (PVA) as polymer hosts and sodium...
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SubjectTerms Electrical properties
Energy storage EDLC device
Impedance study
Plasticized Polymer electrolyte
TNM & LSV
화학공학
Title Tailoring polymer electrolytes with PVA for improved performance in electrical double layer capacitors
URI https://dx.doi.org/10.1016/j.jiec.2024.11.035
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