Kinetic study for the oxidation of cyclohexanol and cyclohexanone with nitric acid to adipic acid
The adipic acid is an important intermediate in the production of nylon, polyurethane and polyester resins. The industrial approach for preparing adipic acid is through the liquid catalytic oxidation of KA oil with nitric acid. In this work, a comprehensive model is developed for this reaction based...
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| Published in | Chinese journal of chemical engineering Vol. 29; no. 1; pp. 183 - 189 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.2021
Department of Chemical Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1004-9541 2210-321X |
| DOI | 10.1016/j.cjche.2020.05.011 |
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| Abstract | The adipic acid is an important intermediate in the production of nylon, polyurethane and polyester resins. The industrial approach for preparing adipic acid is through the liquid catalytic oxidation of KA oil with nitric acid. In this work, a comprehensive model is developed for this reaction based on the kinetic study conducted in a continuous flow tubular reactor. The kinetic model fits well with the experimental results across the experimental conditions, and the average relative error between the calculated and experimental values is 5.7%. Results show that there was an induction period at the early stage of reaction. Moreover, it is found that at temperature range of 328–358 K, the formation rate of adipic acid strongly dependents on the temperature and nitric acid concentration. The developed model is used to predict the yield of adipic acid at 359–368 K. The work in this study could provide much knowledge for industrial tubular reactor design.
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| AbstractList | The adipic acid is an important intermediate in the production of nylon,polyurethane and polyester resins.The industrial approach for preparing adipic acid is through the liquid catalytic oxidation of KA oil with nitric acid.In this work,a comprehensive model is developed for this reaction based on the kinetic study conducted in a continuous flow tubular reactor.The kinetic model fits well with the experimental results across the experimental conditions,and the average relative error between the calculated and experimental values is 5.7％.Results show that there was an induction period at the early stage of reaction.Moreover,it is found that at temperature range of 328-358 K,the formation rate ofadipic acid strongly dependents on the temperature and nitric acid concentration.The developed model is used to predict the yield of adipic acid at 359-368 K.The work in this study could provide much knowledge for industrial tubular reactor design. The adipic acid is an important intermediate in the production of nylon, polyurethane and polyester resins. The industrial approach for preparing adipic acid is through the liquid catalytic oxidation of KA oil with nitric acid. In this work, a comprehensive model is developed for this reaction based on the kinetic study conducted in a continuous flow tubular reactor. The kinetic model fits well with the experimental results across the experimental conditions, and the average relative error between the calculated and experimental values is 5.7%. Results show that there was an induction period at the early stage of reaction. Moreover, it is found that at temperature range of 328–358 K, the formation rate of adipic acid strongly dependents on the temperature and nitric acid concentration. The developed model is used to predict the yield of adipic acid at 359–368 K. The work in this study could provide much knowledge for industrial tubular reactor design. [Display omitted] |
| Author | Su, Yuanhai Wei, Huilong Li, Guangxiao Luo, Zhenghong Pan, Detao |
| AuthorAffiliation | Department of Chemical Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China |
| AuthorAffiliation_xml | – name: Department of Chemical Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China |
| Author_xml | – sequence: 1 givenname: Detao surname: Pan fullname: Pan, Detao – sequence: 2 givenname: Guangxiao surname: Li fullname: Li, Guangxiao – sequence: 3 givenname: Yuanhai surname: Su fullname: Su, Yuanhai – sequence: 4 givenname: Huilong surname: Wei fullname: Wei, Huilong email: hui-longwei2019@sjtu.edu.cn – sequence: 5 givenname: Zhenghong surname: Luo fullname: Luo, Zhenghong email: luozh@sjtu.edu.cn |
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| Cites_doi | 10.1007/s10562-013-1025-3 10.1016/0926-860X(93)80144-F 10.1016/j.catcom.2011.03.026 10.1016/0920-5861(91)80052-B 10.1021/acs.iecr.6b00008 10.1016/0920-5861(91)80050-J 10.1039/C3CY20728E 10.1002/recl.19630820502 10.1016/0009-2509(63)85008-3 10.1016/S0009-2509(00)00350-X 10.1002/chem.201301498 10.1016/j.combustflame.2013.05.016 10.1002/recl.19630820503 10.1016/0926-860X(94)80104-5 10.1016/0009-2509(91)85105-7 10.1016/S0169-4332(97)00325-5 10.1021/acscatal.7b01753 10.1016/S0920-5861(98)00354-X 10.1016/j.cherd.2008.08.007 10.1126/science.281.5383.1646 10.1039/p29850001677 10.1021/jp067592d 10.1039/C7CP08576A 10.1021/ja01588a050 10.1016/S0920-5861(01)00502-8 10.1021/acs.iecr.5b04813 10.1016/0920-5861(91)80051-A 10.1039/p29920000605 10.1002/jctb.280360506 10.1002/recl.19630820107 10.1039/P29930002191 10.1007/s11144-014-0698-y |
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| Copyright | 2020 Chemical Industry and Engineering Society of China, and Chemical Industry Press Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
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| Keywords | Kinetic model Tubular reactor Adipic acid Nitric acid |
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| Title | Kinetic study for the oxidation of cyclohexanol and cyclohexanone with nitric acid to adipic acid |
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