Detection of Chemical Warfare Agent Simulants by using Fluorescence Modulation of Rhodamine 6G/Ag Nanowires

Efficient detection of chemical warfare agents (CWAs) has become indispensable because of the constantly increasing widespread use of CWAs to inflict mass deaths. The commonly used mass spectrometry for CWA detection has a few drawbacks, such as the complexity of equipment and out-situ analysis; thu...

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Published inJournal of the Korean Physical Society Vol. 75; no. 10; pp. 827 - 831
Main Authors Jeong, Byeong Geun, Park, Dae Young, Yang, Kihyuk, An, Sung-Jin, Park, Chulho, Lee, Chanwoo, Yu, Hyang Mi, Jeong, Mun Seok, Lee, Seung Mi
Format Journal Article
LanguageEnglish
Published Seoul The Korean Physical Society 01.11.2019
Springer Nature B.V
한국물리학회
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ISSN0374-4884
1976-8524
DOI10.3938/jkps.75.827

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Abstract Efficient detection of chemical warfare agents (CWAs) has become indispensable because of the constantly increasing widespread use of CWAs to inflict mass deaths. The commonly used mass spectrometry for CWA detection has a few drawbacks, such as the complexity of equipment and out-situ analysis; thus, a simple and intuitive detection method is required to overcome these challenges. Accordingly, in this study, we fabricate Rhodamine 6G (R6G)/Ag nanowires (NWs) for CWA detection based on the sensitive fluorescence changes of R6G caused by the adsorption of different CWA derivatives. In addition, the localized surface plasmon of Ag NWs is applied to enhance the sensitivity of detection due to emission enhancement. The experimental results indicate that the simple CWA detection method proposed in this study can efficiently detect phosphate-type CWAs.
AbstractList Efficient detection of chemical warfare agents (CWAs) has become indispensable because of the constantly increasing widespread use of CWAs to inflict mass deaths. The commonly used mass spectrometry for CWA detection has a few drawbacks, such as the complexity of equipment and out-situ analysis; thus, a simple and intuitive detection method is required to overcome these challenges. Accordingly, in this study, we fabricate Rhodamine 6G (R6G)/Ag nanowires (NWs) for CWA detection based on the sensitive fluorescence changes of R6G caused by the adsorption of different CWA derivatives. In addition, the localized surface plasmon of Ag NWs is applied to enhance the sensitivity of detection due to emission enhancement. The experimental results indicate that the simple CWA detection method proposed in this study can efficiently detect phosphate-type CWAs.
Efficient detection of chemical warfare agents (CWAs) has become indispensable because of the constantly increasing widespread use of CWAs to inflict mass deaths. The commonly used mass spectrometry for CWA detection has a few drawbacks, such as the complexity of equipment and out-situ analysis; thus, a simple and intuitive detection method is required to overcome these challenges. Accordingly, in this study, we fabricate Rhodamine 6G (R6G)/Ag nanowires (NWs) for CWA detection based on the sensitive fluorescence changes of R6G caused by the adsorption of different CWA derivatives. In addition, the localized surface plasmon of Ag NWs is applied to enhance the sensitivity of detection due to emission enhancement. The experimental results indicate that the simple CWA detection method proposed in this study can efficiently detect phosphate-type CWAs. KCI Citation Count: 0
Author An, Sung-Jin
Park, Dae Young
Yang, Kihyuk
Park, Chulho
Lee, Chanwoo
Jeong, Byeong Geun
Yu, Hyang Mi
Jeong, Mun Seok
Lee, Seung Mi
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Keywords Chemical warfare agents
Localized surface plasmon
Silver nanowires
Rhodamine 6G
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Snippet Efficient detection of chemical warfare agents (CWAs) has become indispensable because of the constantly increasing widespread use of CWAs to inflict mass...
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SubjectTerms Chemical warfare
Fluorescence
Mass spectrometry
Mathematical and Computational Physics
Nanowires
Organic chemistry
Particle and Nuclear Physics
Physics
Physics and Astronomy
Rhodamine 6G
Sensitivity enhancement
Silver
Theoretical
물리학
Title Detection of Chemical Warfare Agent Simulants by using Fluorescence Modulation of Rhodamine 6G/Ag Nanowires
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